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Etea Mdcat 2018 — Solved Past Paper with Answers

All 200 MCQs from Etea Mdcat 2018, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT KPK / ETEA past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all KPK / ETEA papers.

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Q1. I am afraid we have not got _ sugar for making tea.

  • A. Some
  • B. No
  • C. Any
  • D. Plenty

Explanation: The correct answer is 'any'. In English, 'any' is used in negative sentences and questions. The sentence 'I am afraid we have not got any sugar for making tea' is a negative sentence, hence 'any' fits perfectly. 'Some' is used for affirmative sentences, 'no' would create a double negative with 'not', and 'plenty' contradicts the negative context implied by 'afraid', thus none of these options are suitable.

Why the other options are wrong
  • A. 'Some' is generally used in affirmative sentences. Since the sentence is negative, 'some' is not suitable here.
  • B. 'No' cannot be used here because the sentence already contains 'not', which indicates negation.
  • D. 'Plenty' suggests an abundance, which contradicts the negative context implied by 'afraid'.

Q2. It’s raining cats and dogs. So there are _ cars on the road today.

  • A. Few
  • B. A few
  • C. A big number of
  • D. A great deal of

Explanation: The phrase 'It's raining cats and dogs' suggests heavy rain, which typically leads to fewer cars on the road. The correct word is 'few', which implies 'not many cars.' The phrase 'a few' would suggest some cars, which doesn't emphasize the reduction in number. 'A big number of' and 'a great deal of' imply a large quantity, which contradicts the expected decrease in car numbers due to the rain.

Why the other options are wrong
  • B. This is incorrect. 'A few' means 'some,' which implies a positive quantity, not suitable for emphasizing a reduced number due to rain.
  • C. This doesn't fit the sentence well. 'A big number of' suggests many cars, which contradicts the expectation of fewer cars on a rainy day.
  • D. This phrase typically refers to uncountable nouns and doesn't fit well with 'cars,' a countable noun.

Q3. I had an unexpected guest today. _ my old classmate.

  • A. It was
  • B. It is
  • C. He was
  • D. She was

Explanation: The sentence "I had an unexpected guest today. It was my old classmate." uses "It was" to correctly match the past tense context set by "had". The use of "it" is appropriate because the gender of the classmate is not specified, and "it" can refer to an unspecified or gender-neutral subject. "He was" and "She was" incorrectly assume a gender, and "It is" uses the wrong tense.

Why the other options are wrong
  • B. "It is" is incorrect because it uses present tense, whereas the context of the sentence is in the past tense.
  • C. "He was" is incorrect as it makes an assumption about gender, which is not specified in the sentence.
  • D. "She was" is incorrect for the same reason as "He was"; it assumes gender where none is specified.

Q4. Choose the correct indirect speech:She said, “What a lovely dress it is.”

  • A. She exclaimed that it is a lovely dress.
  • B. She exclaimed that it was a lovely dress.
  • C. She exclaimed that what a lovely dress it was.
  • D. She exclaimed what a lovely dress it is.

Explanation: In indirect speech, the tense of the verb usually shifts back to reflect the fact that the reporting is happening after the original speech. As a result, 'is' becomes 'was'. Additionally, exclamatory sentences are often reported by using verbs like 'exclaimed' and converting the sentence into a statement. The correct answer, Option B, successfully makes these adjustments. Option A fails to change the verb tense. Option C improperly retains the exclamatory form. Option D also fails to change the verb tense and retains the exclamatory structure.

Why the other options are wrong
  • A. This option is incorrect because the verb 'is' should be changed to the past tense 'was' to match the rules of indirect speech conversion.
  • C. This option is incorrect because it retains the exclamatory form 'what a lovely dress' which should be restructured in indirect speech.
  • D. This option is incorrect as it fails to convert the verb 'is' to the past tense 'was', and it also retains the exclamatory form.

Q5. Choose the correct indirect speech:The teacher said, “Amna, watch your steps.”

  • A. The teacher ordered Amna that she should watch her steps.
  • B. The teacher ordered Amna to watch your steps.
  • C. The teacher ordered Amna to watch her steps.
  • D. The teacher requested Amna to watch your steps.

Explanation: The correct answer is: 'The teacher ordered Amna to watch her steps.' In indirect speech, the verb 'said' is typically changed to match the speaker's intention—in this case, 'ordered' is appropriate as the teacher is giving an instruction. Additionally, the possessive adjective should match the subject (Amna), so 'her' is used instead of 'your'. Other options either use incorrect pronouns or verbs that do not accurately reflect the speaker's intention.

Why the other options are wrong
  • A. This option incorrectly uses 'that she should', which is not necessary in this context. The correct form is to use 'to' followed by the base form of the verb.
  • B. This option incorrectly uses 'your', which should be changed to 'her' to match Amna as the subject of the sentence.
  • D. This option incorrectly uses 'requested' instead of 'ordered'. The context suggests an order, not a request, and also uses 'your' instead of 'her'.

Q6. Saba was sick on the bus.The underlined prepositional phrase functions as a _ in this sentence.

  • A. Adjunct
  • B. Disjunct
  • C. Conjunct
  • D. Adverbial

Explanation: The underlined prepositional phrase 'on the bus' functions as an adjunct, which is a type of adverbial that provides additional information about the action or verb in the sentence. It tells us where the action of being 'sick' took place. Although all adjuncts are adverbials, not all adverbials are adjuncts. The other options are incorrect because:Disjunct: This option is incorrect as disjuncts express the writer's or speaker's attitude, which 'on the bus' does not do.Conjunct: This option is incorrect as conjuncts are used to connect clauses or sentences, which 'on the bus' does not do in this context.Adverbial: While technically correct, this option is too broad. 'On the bus' serves a more specific role as an adjunct.

Why the other options are wrong
  • B. Disjuncts are adverbials that comment on the entire sentence, often expressing the speaker's attitude or opinion, like 'frankly' or 'unfortunately.' The phrase 'on the bus' does not serve this function.
  • C. Conjuncts are used to connect clauses or sentences, such as 'however' or 'therefore.' The phrase 'on the bus' does not connect two parts of the sentence.
  • D. Adverbials modify verbs and provide context such as time, place, manner, etc. While 'on the bus' is indeed an adverbial, the specific role it plays here is as an adjunct.

Q7. Which way shall we go?The underlined word is:

  • A. Demonstrative adjective
  • B. Interrogative pronoun
  • C. Interrogative adjective
  • D. Exclamatory adjective

Explanation: The underlined word 'which' is an interrogative adjective because it modifies the noun 'way' and directly precedes it. Interrogative adjectives are used to ask questions about nouns. The other options are incorrect: a demonstrative adjective would indicate position or distance, which 'which' does not; an interrogative pronoun would stand alone and be followed by a verb, not a noun; and an exclamatory adjective is used to express strong feelings, which is not applicable in this question context.

Why the other options are wrong
  • A. Demonstrative adjectives specify the position or distance of a noun (e.g., this, that, these, those). The word 'which' is not indicating any position or distance.
  • B. Interrogative pronouns stand alone in a sentence and are typically followed by a verb (e.g., who, whom, what, which). In this case, 'which' is followed by a noun, not a verb, so it is not an interrogative pronoun.
  • D. Exclamatory adjectives express strong emotion and are not typically used in questions. The sentence in question is interrogative, not exclamatory, so 'which' does not function as an exclamatory adjective.

Q8. Choose the correct indirect speech:He said to me, “traitor”.

  • A. He said to me that I was a traitor.
  • B. He told me that I have been a traitor.
  • C. He called me a traitor.
  • D. He exclaimed with anger that I was a traitor.

Explanation: The correct answer is: He called me a traitor. In this case, the direct speech 'He said to me, "traitor"' involves the speaker directly addressing the listener with a specific term, 'traitor.' When converting such expressions to indirect speech, the verb 'called' is most appropriate as it conveys the act of naming or labeling someone. The other options either alter the tense, add unnecessary emotional context, or do not accurately reflect the original tone and intent of the direct speech.

Why the other options are wrong
  • A. This option is incorrect because it fails to capture the direct accusation or naming implied in the original speech. The verb 'called' is more appropriate for directly addressing someone as something.
  • B. This option is incorrect as it changes the tense and alters the meaning. 'Have been' suggests a completed action in the past, which does not match the tone or context of the direct speech.
  • D. This option is incorrect. Although it adds emotional context, it inaccurately reflects the original speech's simplicity. The term 'called' is more straightforward and precise for this context.

Q9. My mother offered me milk. But for my life, I could not drink it.[The underlined expression means:]

  • A. However hard I may try
  • B. Because of my life
  • C. For the sake of my life
  • D. During my life

Explanation: The phrase But for my life in the given context means However hard I may try, indicating an inability to perform the action regardless of effort. The correct answer reflects this meaning. The other options misinterpret the phrase: 'Because of my life' incorrectly suggests a life-threatening reason, 'For the sake of my life' implies a protective action, and 'During my life' is irrelevant to the context of effort and inability.

Why the other options are wrong
  • B. This interpretation is incorrect because it suggests a reason related to life-threatening consequences, which doesn't align with the context of the mother's offer.
  • C. This option implies doing something to preserve life, which is not the intended meaning of the phrase in this context.
  • D. This phrase suggests a time period, which does not fit the context of the difficulty in performing an action despite effort.

Q10. Out of the following indicate the matching item for PUPPIES.

  • A. School
  • B. Litter
  • C. Covey
  • D. Group

Explanation: Out of the following words that indicate ''puppies' is "Litter".

Why the other options are wrong
  • A. School is commonly used to describe a group of fish, not puppies.
  • C. Covey is typically used for small groups of birds, such as quails, not puppies.
  • D. Group is a general term that can refer to any collection of people or animals but doesn't specifically apply to puppies.

Q11. Choose the related word for Broom on the analogy of "Water : Splash".

  • A. Whisper
  • B. Gush
  • C. Swish
  • D. Screech

Explanation: The correct answer is Swish. When water moves rapidly, it creates a splash sound. Similarly, when a broom is used, it makes a swishing sound as it moves through the air.

Why the other options are wrong
  • A. Whisper refers to speaking softly, which is unrelated to the sound made by a broom.
  • B. Gush describes the forceful flow of water, producing a sound, but it does not relate to a broom.
  • D. Screech is a high-pitched noise, not typically associated with the action of sweeping with a broom.

Q12. Choose the related word for Rat on the analogy of "Elephant : Stride".

  • A. Scamper
  • B. Loiter
  • C. Whimper
  • D. Gallop

Explanation: Elephants take long steps while walking which is known as a stride. Similarly, a rat scampers which means it runs in quick, light movements.

Why the other options are wrong
  • B. Loiter refers to lingering or moving slowly without a purpose, which does not match the active movement style of a rat.
  • C. Whimper refers to a sound rather than a style of movement, making it unrelated to the analogy of movement styles.
  • D. Gallop is a fast-paced, bounding movement typical of horses, not small animals like rats.

Q13. Which of the following is correct in all respects?

  • A. I have done matric in 2010.
  • B. This is an utensil.
  • C. The population of the world rises.
  • D. This is the best peach-producing valley.

Explanation: This sentence is both grammatically correct and contextually appropriate. It uses the correct article and hyphenates the compound adjective "peach-producing."

Why the other options are wrong
  • A. Incorrect. The correct sentence should be "I did matric in 2010" because "have done" is present perfect tense, which is not appropriate when a specific time in the past is mentioned.
  • B. Incorrect. The correct article should be "a" instead of "an" because "utensil" starts with a consonant sound. The correct sentence should be "This is a utensil."
  • C. Incorrect. While grammatically correct, this statement is less common and may sound awkward. A more common phrasing would be "The population of the world is rising."

Q14. Which one of the following is opposite in meaning to the word SYMPATHY?

  • A. Apathy
  • B. Pathos
  • C. Empathy
  • D. Jealousy

Explanation: Apathy lack of interest, enthusiasm, or concern. While sympathy means feelings of pity and sorrow for someone else's misfortune.

Why the other options are wrong
  • B. Pathos refers to an appeal to emotion, often used in rhetoric to persuade an audience to feel a certain way, and is not the opposite of sympathy.
  • C. Empathy involves understanding and sharing the feelings of others, which is similar to sympathy but not its opposite.
  • D. Jealousy is the feeling of envy towards someone, which is unrelated to the concept of sympathy.

Q15. Choose the correct indirect speech:He said, "What is the matter"?

  • A. He said what the matter was.
  • B. He asked what the matter was
  • C. He enquired that what was the matter
  • D. He asked that what the matter had been

Explanation: Option (b), "He asked what the matter was," is the correct choice. This option correctly conveys the original question in indirect speech, changing "is" to "was" and properly using "asked" to indicate that it was a question.

Why the other options are wrong
  • A. Option (a) is incorrect because it uses "said" instead of "asked," which does not appropriately capture the questioning nature of the original statement.
  • C. Option (c) is incorrect because it awkwardly includes "that" and changes the structure unnecessarily, which is not standard for indirect speech
  • D. Option (d) is incorrect because it uses "had been," which is an unnecessary change to the past perfect tense and also misrepresents the time frame of the original question

Q16. Choose the correct voice:You are called names by him.

  • A. He is calling you names.
  • B. He calls you names.
  • C. He called you names.
  • D. You are being called names by him.

Explanation: The sentence 'You are called names by him.' is in passive voice and present simple tense. To convert it to active voice, rearrange the components so that 'he' is the subject performing the action: 'He calls you names.' This maintains the present simple tense. The other options either change the tense or maintain the passive structure, which is why they are incorrect.

Why the other options are wrong
  • A. This option is incorrect. It changes the tense from simple to continuous, which is not appropriate here.
  • C. This option is incorrect. It changes the tense to past simple, which does not match the passive sentence's present simple tense.
  • D. This option is incorrect. It is still in passive voice rather than active voice.

Q17. Fill in the blank with the most appropriate words.Don’t poke your nose _ my affairs

  • A. In
  • B. On
  • C. Into
  • D. By

Explanation: This is the most appropriate choice as "poke your nose into my affairs" is the standard expression meaning to interfere or meddle in someone else's business.

Why the other options are wrong
  • A. "Poke your nose in my affairs" is a common phrase, but it is slightly less formal than using "into." However, it's still acceptable in informal contexts.
  • B. "Poke your nose on my affairs" is incorrect because "on" does not fit with the expression.
  • D. "Poke your nose by my affairs" is grammatically incorrect and does not convey the intended meaning.

Q18. "Enlarge upon" means:

  • A. Explain in more detail
  • B. To make taller
  • C. To become large
  • D. To measure

Explanation: It means to speak or write about something in greater detail or much more emphasis.

Why the other options are wrong
  • B. "To make taller" refers to increasing height, which is a literal interpretation and not related to the meaning of the phrase ‘enlarge upon’.
  • C. "To become large" suggests physical growth in size, which does not align with the figurative meaning of "enlarge upon."
  • D. "To measure" involves determining the dimensions or quantity of something, unrelated to expanding on a topic.

Q19. ‘To the letter’ means:

  • A. Cursory
  • B. Enveloping a letter
  • C. Precisely
  • D. Reporting a problem

Explanation: "To the letter" means adherence to every detail or precision.

Why the other options are wrong
  • A. Cursory refers to something done quickly and without attention to detail, which is the opposite of what 'to the letter' implies.
  • B. This option is a literal interpretation involving a physical letter, which is unrelated to the metaphorical meaning of 'to the letter'.
  • D. Reporting a problem involves notifying someone about an issue, which does not match the meaning of 'to the letter'.

Q20. A person who leaves his country and settles in another country is called:

  • A. Emigrant
  • B. Immigrant
  • C. Migrant
  • D. Aborigine

Explanation: An emigrant is someone who leaves their country of origin to settle in another country, focusing on the movement away from the home country.In contrast, an immigrant is someone who moves into a new country to live permanently, emphasizing the arrival and settlement in a new location. A migrant can refer to both scenarios but is a broader term that includes temporary moves. An aborigine is unrelated to this context, as it describes native inhabitants of a land.

Why the other options are wrong
  • B. An immigrant is someone who arrives in a new country to live permanently. This term focuses on entering and settling in a different country.
  • C. A migrant is a more general term that refers to a person who moves from one place to another, which can be within or across national borders and may include both emigrants and immigrants.
  • D. An aborigine refers to the original inhabitants of a place, having lived there since the earliest times, not someone who moves from one country to another.

Q21. Alcoholic fermentation is the sole mean of respiration in:

  • A. Saccharomyces
  • B. Armillaria
  • C. Trichonympha
  • D. Balantidium

Explanation: Alcoholic fermentation occurs in yeast and plants. Alcoholic fermentation is the sole mean of respiration in Saccharomyces cerevisiae (yeast). Saccharomyces can ferment carbohydrates, breaking down glucose to form ethanol and carbon dioxide.

Why the other options are wrong
  • B. Armillaria is a genus of pathogenic fungi that predominantly rely on aerobic respiration for energy. They do not engage in alcoholic fermentation as their primary means of respiration.
  • C. Trichonympha are flagellate protists residing in the guts of termites. They aid in cellulose digestion, but do not perform alcoholic fermentation as a means of respiration.
  • D. Balantidium is a ciliated protozoan, primarily found in the intestinal tracts of certain animals. It does not rely on alcoholic fermentation for energy production.

Q22. The edible part of Morchella esculanta is:

  • A. Ascocarp
  • B. Basidiocarp
  • C. Zygocarp
  • D. Pseudocarp

Explanation: The fruiting body of ascomycetes is called ascocarp. As Morchella esculenta is an edible fungus from class Ascomycota, its ascocarp part is edible.

Why the other options are wrong
  • B. The basidiocarp is the fruiting body found in Basidiomycota fungi, not in Ascomycota fungi like Morchella esculenta.
  • C. Zygocarps are associated with fungi in the Zygomycota class and are not present in Morchella esculenta.
  • D. Pseudocarps are structures found in some plants but not associated with the fruiting body of Morchella esculenta.

Q23. XO in drosophila result in sterile:

  • A. Female
  • B. Male
  • C. Both (A) & (B)
  • D. No effect

Explanation: XO in drosophila results in a sterile male. As XO means the absence of the second chromosome. The male has only one X chromosome and one Y chromosome, while the female has two X chromosomes. So, when offspring of drosophila carry one X chromosome from a male and one X chromosome from a female it results in a normal female but when offspring of drosophila carry one X chromosome from a female and no chromosome from a male then it results in a sterile male.

Why the other options are wrong
  • A. This option is incorrect. In XO drosophila, the absence of a second sex chromosome results in a male, not a female.
  • C. This option is incorrect. XO results only in a sterile male, not both male and female.
  • D. This option is incorrect. The absence of the second sex chromosome (X or Y) in drosophila does have an effect, resulting in a sterile male.

Q24. Which of the following is not a fern?

  • A. Pteris
  • B. Tmesipteris
  • C. Dryopteris
  • D. Pteridium

Explanation: Tmesipteris is actually a genus of ferns belonging to the class Psilotopsida within the sub-division Psilophytina. Tmesipteris is a small genus of ferns that belongs to the class Psilotopsida. Psilotopsida is a class within the division Psilophyta, and this division includes ferns that are often considered primitive vascular plants. The class Psilotopsida includes not only Tmesipteris but also other genera like Psilotum. These ferns are unique because they lack true leaves and roots. Instead, they have small, scale-like appendages on their stems. Tmesipteris, like other members of Psilotopsida, exhibits simple vascular tissues and has a relatively simple overall structure compared to more advanced ferns.

Why the other options are wrong
  • A. Pteris is a large and diverse genus of true ferns within the family Pteridaceae. This group is known for its characteristic fronds and is commonly referred to as brake ferns or maidenhair ferns. They are found in various environments across the globe, making them a well-known member of the fern family.
  • C. Dryopteris is a genus of true ferns, commonly referred to as wood ferns. They belong to the family Dryopteridaceae and are widely distributed, inhabiting a range of environments. These ferns are known for their large, divided fronds and are a typical example of true ferns.
  • D. Pteridium, commonly known as bracken ferns, is another genus of true ferns. They are part of the family Dennstaedtiaceae and are known for their extensive rhizomatous growth and large, compound fronds. Bracken ferns are particularly adaptable and widespread, thriving in various habitats.

Q25. Umbel of umbels is present in:

  • A. Hydrocotyl
  • B. Carrot
  • C. Iberis
  • D. Grapes

Explanation: The term "umbel of umbels" refers to an inflorescence arrangement where multiple smaller umbels are arranged in an overall larger, compound umbel. This structure is commonly found in plants belonging to the Apiaceae (or Umbelliferae) family. The Apiaceae family is known for its characteristic inflorescence called an umbel. One of the well-known examples of an umbel of umbels is seen in plants of the genus Daucus. The common carrot, Daucus carota, is a member of this genus and exhibits an umbel of umbels in its inflorescence.

Why the other options are wrong
  • A. Hydrocotyle is a genus within the family Araliaceae. While some species produce simple umbels, they do not typically form the compound umbel structure described as an 'umbel of umbels'.
  • C. Iberis, or candytuft, belongs to the Brassicaceae family and typically has a corymb inflorescence, not an umbel. A corymb is different in structure from an umbel of umbels.
  • D. Grapes (Vitis vinifera) exhibit a panicle inflorescence, a compound raceme, which is structurally different from an umbel of umbels.

Q26. Male having Down's syndrome have sex chromosomes:

  • A. XXY
  • B. XY
  • C. XYY
  • D. XYYY

Explanation: In Down’s syndrome, the affected person contains an extra autosomal chromosome number 21 (trisomy 2n+1). Males having this syndrome have XY sex chromosomes. They have 3 21st chromosomes.

Why the other options are wrong
  • A. XXY represents Klinefelter's syndrome, where males have an extra X chromosome, but it is unrelated to Down's syndrome, which involves an autosomal chromosome.
  • C. XYY syndrome is a separate chromosomal disorder affecting males, characterized by an additional Y chromosome, not associated with Down's syndrome.
  • D. XYYY syndrome is an exceedingly rare chromosomal disorder involving multiple extra Y chromosomes and does not relate to Down's syndrome.

Q27. Darwins finches are found in:

  • A. New Zealand
  • B. New Guinea
  • C. Galapagos Islands
  • D. Australia

Explanation: Darwin finches (13 types) are found in the Galapagos islands, west of Ecuador.

Why the other options are wrong
  • A. This option is incorrect. While New Zealand is known for its unique bird species, it is not the location where Darwin's finches are found.
  • B. This option is incorrect. New Guinea is home to diverse bird species, but not Darwin's finches.
  • D. This option is incorrect. Australia has many unique animals, but Darwin's finches are not among them.

Q28. Which of the following is the most economically important plant family?

  • A. Poaceae
  • B. Asteraceae
  • C. Rosaceae
  • D. Fabaceae

Explanation: Poaceae, commonly known as the grass family, is one of the largest and most economically important families of flowering plants. The Poaceae family includes a wide variety of grasses, ranging from small, herbaceous plants to large, woody bamboos. Many grasses in the Poaceae family are of great economic importance for humans and animals. They are used as staple food crops, for forage, as ornamental plants, and for the production of materials such as paper and thatch. This family includes major cereal crops that serve as staples worldwide, such as rice (Oryza sativa), wheat (Triticum aestivum), maize (corn, Zea mays), barley (Hordeum vulgare), and oats (Avena sativa).

Why the other options are wrong
  • B. Asteraceae, or the daisy family, is one of the largest families of flowering plants and includes many ornamental plants and some food crops like lettuce and sunflower, but it does not match the economic impact of Poaceae.
  • C. Rosaceae, the rose family, includes some economically important fruits like apples, cherries, and strawberries, but overall, its economic importance is less compared to Poaceae.
  • D. Fabaceae, or the legume family, is economically important due to its role in nitrogen fixation and inclusion of crops like beans and peas. However, its economic impact is smaller than that of Poaceae.

Q29. The living phloem, cork and cork cambium is collectively called:

  • A. Periderm
  • B. Protoderm
  • C. Periblem
  • D. Bark

Explanation: The living phloem, cork and cork cambium is collectively called Bark.

Why the other options are wrong
  • A. Periderm consists of cork, cork cambium, and phelloderm, which are parts of the protective outer layer but do not include phloem.
  • B. Protoderm is a type of primary meristem that differentiates into the epidermis, not related to phloem or cork.
  • C. Periblem is involved in forming the cortex in roots and stems, not the outer protective structures like bark.

Q30. All of the following acts as cloning vector except:

  • A. BAC
  • B. YAC
  • C. Cosmids
  • D. EcoRI

Explanation: Cloning: It is a technique for developing a large number of genes, identical cells, tissues, or organisms.Vector: Vectors are required to make rDNA molecules for gene cloning. Ecor1 does not act as a cloning vector. As it is a restriction enzyme, which cut double-stranded DNA into single-stranded complementary strands.

Why the other options are wrong
  • A. BAC (Bacterial Artificial Chromosome) is a common type of cloning vector used to clone large fragments of DNA.
  • B. YAC (Yeast Artificial Chromosome) serves as a cloning vector particularly useful for cloning very large DNA fragments.
  • C. Cosmids are hybrid plasmid vectors that contain a small portion of lambda phage DNA, making them useful cloning vectors for DNA fragments of intermediate size.

Q31. How many sperms are produced from fifty secondary spermatocyte?

  • A. 200
  • B. 100
  • C. 50
  • D. 150

Explanation: The secondary spermatocyte continues into meiosis II and each spermatocyte forms two sperm. So, 2x50=100.

Why the other options are wrong
  • A. This option is incorrect. Each secondary spermatocyte undergoes meiosis II to produce two sperms, resulting in a total of 100 sperms from 50 secondary spermatocytes.
  • C. This option is incorrect. Each secondary spermatocyte produces two sperms, not one. Thus, 50 secondary spermatocytes yield 100 sperms.
  • D. This option is incorrect. The calculation should be 2 sperms per secondary spermatocyte, resulting in 100 sperms, not 150.

Q32. Which one of the following is a shrub?

  • A. Parmelia
  • B. Aster
  • C. Rhus
  • D. Banana

Explanation: Rhus are shrubs.

Why the other options are wrong
  • A. Parmelia refers to a type of foliose lichen, which is not a shrub. Lichens are symbiotic associations between a fungus and an alga or cyanobacterium, typically found on rocks and tree trunks.
  • B. Aster plants are flowering herbs often cultivated for ornamental purposes. They are not classified as shrubs because they do not have the woody stems characteristic of shrubs.
  • D. Banana plants are large herbaceous plants, not shrubs. They have a pseudostem formed by leaf bases and produce fruit in clusters, making them easily distinguishable from shrubs.

Q33. In nitrogen-fixing bacteria, the nitrogenase complex is sensitive to:

  • A. O2
  • B. CO2
  • C. NO2
  • D. NO3

Explanation: Nitrogen fixing bacteria contain an enzyme complex known as Nitrogenase which catalyses the conversion of nitrogen gas to ammonia. The nitrogenase complex is sensitive to oxygen. Oxygen will make the enzyme irreversibly inactive. So, the nitrogen-fixing bacteria needs to protect the nitrogenase enzyme from oxygen.

Why the other options are wrong
  • B. Incorrect. Carbon dioxide does not inactivate the nitrogenase enzyme. It is not a threat to the nitrogenase complex in nitrogen-fixing bacteria.
  • C. Incorrect. Nitrite (NO2) does not directly affect the nitrogenase enzyme's activity in nitrogen-fixing bacteria.
  • D. Incorrect. Nitrate (NO3) does not affect the activity of the nitrogenase enzyme in the same way oxygen does.

Q34. Over eating psychological disorder is called:

  • A. Dyspepsia
  • B. Septicemia
  • C. Anorexia
  • D. Bulimia

Explanation: Bulimia nervosa is an eating disorder in which a person may eat a lot of food at once and then try to get rid of the food by vomiting, using laxatives, or sometimes over-exercising.

Why the other options are wrong
  • A. Dyspepsia refers to indigestion, characterized by discomfort or pain in the upper abdomen. It is related to digestion problems, not a psychological eating disorder.
  • B. Septicemia is a serious bloodstream infection caused by bacteria. It is unrelated to eating behaviors or psychological disorders.
  • C. Anorexia nervosa is an eating disorder characterized by an intense fear of gaining weight and a distorted body image, leading to self-starvation. It involves under-eating rather than overeating.

Q35. The first successful surgery of heart was performed by Dr. Ludwig by repairing a wound on which part:

  • A. Right auricle
  • B. Right ventricle
  • C. Left auricle
  • D. Left ventricle

Explanation: The first successful surgery of the heart was performed by Dr. Ludwig by repairing a wound on the Right ventricle.

Why the other options are wrong
  • A. This option is incorrect. The first successful surgery of the heart was performed by Dr.Ludwig by repairing a stab wound to the right ventricle on September 7, 1896.
  • C. This option is incorrect. The first successful surgery of the heart was performed by Dr.Ludwig by repairing a stab wound to the right ventricle on September 7, 1896.
  • D. This option is incorrect. The first successful surgery of the heart was performed by Dr.Ludwig by repairing a stab wound to the right ventricle on September 7, 1896.

Q36. Lignin could not be expected in which part of the plant cell wall:

  • A. Secondary cell wall
  • B. Middle lamella
  • C. Primary cell wall
  • D. Both "B" and "C"

Explanation: The primary cell wall of the plant is composed of cellulose, pectic compounds mostly polysaccharides, and hemicellulose. It lacks lignin. Middle lamella also lacks lignin.

Why the other options are wrong
  • A. The secondary cell wall is rich in lignin, which provides structural support and rigidity to the plant.
  • B. The middle lamella is primarily composed of pectin and acts as a glue between plant cells. It does not contain lignin.
  • C. The primary cell wall is mainly composed of cellulose and other polysaccharides. It is flexible and does not contain lignin.

Q37. The following statement is true for the absorption spectra of photosynthesis:

  • A. Chlorophyll a and b have the same absorption spectra.
  • B. Chlorophyll a and b have different absorption spectra.
  • C. Chlorophyll a and carotenoids have the same absorption spectra.
  • D. Carotenoids and chlorophyll b have the same absorption spectra.

Explanation: Yes, chlorophyll-a and chlorophyll-b, the two main types of chlorophyll found in photosynthetic organisms, have slightly different absorption spectra. Chlorophyll-a and chlorophyll-b absorb light most efficiently in the blue and red regions of the electromagnetic spectrum, but they have different absorption peaks. While chlorophyll-a is directly involved in the conversion of light energy to chemical energy in the photosystems, chlorophyll-b expands the range of light that can be captured and utilized for photosynthesis.

Why the other options are wrong
  • A. No, this is incorrect. Chlorophyll-a and chlorophyll-b have different absorption spectra. They absorb light most efficiently in the blue and red regions of the electromagnetic spectrum, but their absorption peaks are distinct.
  • C. This is incorrect. Chlorophyll-a and carotenoids have different absorption spectra. Carotenoids absorb light primarily in the blue and green regions of the spectrum, complementing the absorption of chlorophyll.
  • D. This is incorrect. Carotenoids and chlorophyll-b have different absorption spectra. Carotenoids absorb light mainly in the blue and green regions, while chlorophyll-b absorbs more in the blue and red regions.

Q38. An autoimmune disorders in which stiffness and inflammation of vertebrae occurs is called as:

  • A. Lupus
  • B. Scleroderma
  • C. Ankylosing spondylitis
  • D. Juvenile dermatomyositis

Explanation: An autoimmune disorder in which stiffness and inflammation of vertebrae occur is called Ankylosis spondylitis.

Why the other options are wrong
  • A. Lupus is an autoimmune disease that can cause joint pain and inflammation, but it primarily affects the skin, kidneys, and other organs rather than specifically targeting the spine.
  • B. Scleroderma involves hardening and tightening of the skin and connective tissues, but it does not primarily target the vertebrae or cause spinal inflammation.
  • D. Juvenile dermatomyositis is an inflammatory condition affecting the skin and muscles, particularly in children, and does not typically involve the vertebrae.

Q39. The study of fishes is:

  • A. Ornithology
  • B. Ichthyology
  • C. Herpetology
  • D. Serpetology

Explanation: The correct answer is Ichthyology, which is the scientific study of fishes, including their biology, classification, and conservation. Ornithology refers to the study of birds, Herpetology covers amphibians and reptiles, and 'Serpetology' is not an established scientific term.

Why the other options are wrong
  • A. Ornithology is the study of birds, not fishes. This term is unrelated to aquatic life.
  • C. Herpetology involves the study of amphibians and reptiles, such as frogs, snakes, and lizards, not fishes.
  • D. Serpetology is a misspelling and does not refer to any recognized scientific field. The correct term for the study of reptiles is Herpetology.

Q40. Which of the following is absent in C4 Plants:

  • A. Calvin Cycle
  • B. Bundle Sheath Cells
  • C. PEP Carboxylase
  • D. CO2 Fixation in Mesophyll Cells

Explanation: In C4 plants, CO2 fixation occurs in the mesophyll cells, but it follows a unique pathway compared to C3 plants. C4 plants are adapted to minimize photorespiration by initially fixing CO2 in the mesophyll cells using the enzyme PEP Carboxylase, forming a four-carbon compound (oxaloacetate). This compound is then transported to the bundle sheath cells, where the Calvin cycle occurs. Therefore, the statement that CO2 fixation is absent in mesophyll cells is incorrect.The Calvin cycle is indeed present in C4 plants, but it occurs in the bundle sheath cells, not the mesophyll cells. Bundle sheath cells are essential for the Calvin cycle in C4 plants, and PEP Carboxylase is vital for the initial CO2 fixation. Thus, options A, B, and C are incorrect.

Why the other options are wrong
  • A. The Calvin cycle is present in C4 plants. It takes place in the bundle sheath cells, where CO2 is eventually fixed into sugar.
  • B. Bundle sheath cells are present in C4 plants. They play a crucial role in the Calvin cycle by receiving four-carbon compounds from mesophyll cells.
  • C. PEP Carboxylase is an enzyme present in C4 plants. It facilitates the initial fixation of CO2 in mesophyll cells, forming a four-carbon compound.

Q41. The stage of plasmodium life cycle not related to human body is:

  • A. Merozoite
  • B. Ookinetes
  • C. Trophozoites
  • D. Gametozoites

Explanation: Ookinetes are formed in the mosquito gut after fertilization of the female gametocyte by the male gametocyte. This stage is part of the Plasmodium's life cycle within the mosquito and does not occur in the human body.

Why the other options are wrong
  • A. This option is incorrect. Merozoites are a stage of the Plasmodium life cycle that occurs after the liver phase and involves invading red blood cells within the human body.
  • C. This option is incorrect. Trophozoites are a developmental stage of Plasmodium that occurs inside human red blood cells during the asexual replication phase.
  • D. This option is incorrect. Gametozoites are the sexual stages of the Plasmodium that develop in the human bloodstream and can be taken up by mosquitoes during a blood meal.

Q42. In protein synthesis the initiator tRNA carrying amino acid methionine land on which site of ribosome:

  • A. E site
  • B. P site
  • C. A site
  • D. C site

Explanation: In protein synthesis, the initiator tRNA molecule carrying chemically modified initial amino acid, methionine (known as N-formyl methionine) binds to a small ribosomal subunit at P-site (peptidyl site) where a peptide bond will form. This binding is controlled by an enzyme called initiation factors (IF1 and IF2).

Why the other options are wrong
  • A. The E site, or exit site, is where empty tRNAs leave the ribosome during the elongation phase of protein synthesis, not where the initiator tRNA binds.
  • C. The A site, or aminoacyl site, is where subsequent tRNAs carrying new amino acids bind during the elongation phase of protein synthesis, not where the initiator tRNA first binds.
  • D. There is no C site in the ribosome involved in protein synthesis. This is not a valid option.

Q43. Goblet cells are:

  • A. Unicellular exocrine gland
  • B. Unicellular endocrine glands
  • C. Multicellular exocrine gland
  • D. Multicellular endocrine glands

Explanation: The goblet cells are unicellular exocrine gland. Goblet cells are scattered in the epithelial linings of the intestinal and respiratory tracts. They secrete mucin and create a protective mucus layer.

Why the other options are wrong
  • B. This is incorrect. Endocrine glands secrete hormones directly into the bloodstream, and goblet cells do not produce hormones or possess endocrine functions.
  • C. This is incorrect because goblet cells are unicellular, meaning they consist of a single cell, unlike multicellular glands that are composed of multiple cells.
  • D. This option is incorrect for two reasons: goblet cells are unicellular, not multicellular, and they do not secrete hormones like endocrine glands do.

Q44. Which process of cell division is involved in gametes formation in Funaria:

  • A. Mitosis
  • B. Meiosis
  • C. Amitosis
  • D. Binary Fission

Explanation: In the life cycle of mosses such as Funaria, the process of cell division involved in gamete formation is known as mitosis. The life cycle of mosses involves alternation of generations between a haploid gametophyte phase and a diploid sporophyte phase.

Why the other options are wrong
  • B. Meiosis occurs in the sporophyte generation of Funaria, which is diploid, and it results in the formation of spores, not gametes. Meiosis reduces the chromosome number by half, preparing for the gametophyte phase.
  • C. Amitosis is a form of direct cell division without the typical mitotic spindle. It is more common in prokaryotes and not applicable to bryophytes like Funaria, which are eukaryotic organisms.
  • D. Binary fission is a method of asexual reproduction seen in prokaryotes. Funaria, being a bryophyte, reproduces sexually and vegetatively, not through binary fission.

Q45. Closed vascular system is the characteristic of:

  • A. Lycopsida
  • B. Sphenopsida
  • C. Dicot
  • D. Monocot

Explanation: Monocots (monocotyledons) typically have a scattered vascular bundle and they are collateral and closed. The vascular bundles in monocots are distributed throughout the stem without a clearly defined ring pattern. This is in contrast to dicots, which often have a ring-shaped arrangement of vascular bundles in their stems.

Why the other options are wrong
  • A. Lycopsida, also known as club mosses, have a vascular system, but it is seedless and does not have a closed structure due to the absence of cambium.
  • B. Sphenopsida, or horsetails, possess a vascular system that is also seedless and lacks a closed configuration because they do not have cambium.
  • C. Dicots typically have an open vascular system due to the presence of cambium, which allows for secondary growth and a ring-like arrangement of vascular bundles.

Q46. Common name of the Loligo pealeii is:

  • A. Squid
  • B. Laligo
  • C. Slug
  • D. Oyster

Explanation: The correct answer is Squid. Loligo pealeii is a species of squid, which are marine cephalopods known for their elongated bodies and tentacles. They are distinct from other mollusks such as slugs and oysters. Slugs are terrestrial and belong to a different class (Gastropoda), while oysters are bivalve mollusks, not cephalopods. 'Laligo' is not a valid common name for any known species.

Why the other options are wrong
  • B. Laligo is not a recognized common name for any organism. It appears to be a misspelling or variation of Loligo.
  • C. Slug is the common name for various terrestrial gastropod mollusks, such as Limax maximus, which is not related to the marine Loligo pealeii.
  • D. Oyster is the common name for bivalve mollusks like Ostrea lurida, which are distinct from cephalopods like Loligo pealeii.

Q47. Tornaria larva resembles with:

  • A. Bipinnaria larva
  • B. Trochophore larva
  • C. Glochidium larva
  • D. Instar larva

Explanation: Tornaria larva resembles with Bipinnaria larva. Because Tornaria larva of hemichordates and Bipinnaria of Echinodermata are very similar in shape and structure. The pattern of cleavage of a fertilised egg, formation of mesoderm, anus, mouth, and coelom in echinoderms and hemichordates is similar. So, most resemblance is with Bipinnaria larva.

Why the other options are wrong
  • B. The Trochophore larva, found in annelids and some mollusks, differs significantly in morphology and developmental pathways from the Tornaria larva.
  • C. Glochidium larvae are unique to certain bivalve mollusks and do not share the developmental or morphological characteristics seen in Tornaria larvae.
  • D. Instar larvae are a stage in the development of arthropods and are not similar to Tornaria larvae, as they belong to a different phylum with distinct developmental stages.

Q48. Taxus baccata is the botanical name of:

  • A. Fever tree
  • B. Deadly nightshade
  • C. English Yew
  • D. Daffodils

Explanation: Taxus baccata is the botanical name for the European yew, a species of coniferous tree. The European yew belongs to the family Taxaceae. The plant is known for its dark green needles, red berries, and its association with various cultural and historical contexts. It contains compounds called taxanes, which have been of interest for their potential medicinal properties, particularly in the development of certain cancer treatments such as paclitaxel (Taxol).

Why the other options are wrong
  • A. The botanical name Vachellia xanthophloea refers to the Fever tree, known for its yellow-green bark and use in traditional medicine.
  • B. Atropa belladonna is the botanical name of Deadly Nightshade, a plant known for its toxic properties and historical use in poisons.
  • D. Narcissus is the botanical name of Daffodils, popular ornamental flowers known for their bright yellow blooms.

Q49. Venous flower basket belong to which group of organisms:

  • A. Angiosperms
  • B. Sponges
  • C. Marine Algae
  • D. Fungus-like protists

Explanation: Venous flower basket belong to sponges (Phylum porifera).The Venus' flower basket is a species of glass sponge found in the deep waters of the Pacific Ocean, usually at depths below 500 m. Like other glass sponges, they build their skeletons out of silica, which forms a unique lattice structure consisting of spicules

Why the other options are wrong
  • A. Angiosperms are a group of flowering plants. The Venus' flower basket, however, is not a plant but an animal from the marine environment.
  • C. While marine algae are found in ocean environments, they are plants or plant-like organisms, unlike the animal nature of the Venus' flower basket.
  • D. These are eukaryotic organisms that resemble fungi. The Venus' flower basket is not a protist but a marine animal, specifically a sponge.

Q50. The main difference between catalysts and enzymes is:

  • A. Enzymes are more specific in action than catalysts
  • B. Catalysts are required in larger quantities than enzymes
  • C. Catalysts are generally inorganic while enzymes are organic and protein-based
  • D. Enzymes require specific pH conditions, whereas catalysts do not

Explanation: Enzymes are organic molecules, primarily proteins, whereas most catalysts are inorganic substances.

Why the other options are wrong
  • A. This option highlights the specificity of enzymes, which is true; however, it does not address the primary difference in their composition or nature.
  • B. This statement is incorrect as both enzymes and catalysts can operate effectively in small amounts. Thus, this does not represent a key difference.
  • D. This statement is misleading. While enzymes often function best at specific pH levels, some catalysts can also be affected by pH, making this not a definitive difference.

Q51. The first hormone to be discovered was:

  • A. Secretin
  • B. Testosterone
  • C. Insulin
  • D. Thyroxin

Explanation: Wm. M. Bayliss and Ernest H. Starling discovered secretin, the first hormone, in 1902. They discovered this hormone when they were studying pancreatic secretion. Secretin hormone stimulates the pancreas to secrete digestive fluid.

Why the other options are wrong
  • B. Incorrect. Testosterone, a key male sex hormone, was not discovered until the 1930s, making it much later than secretin.
  • C. Incorrect. Insulin, crucial for glucose regulation, was discovered in 1921 by Frederick Banting and Charles Best, which is after secretin's discovery.
  • D. Incorrect. Thyroxin, involved in regulating metabolism, was identified in the early 20th century but after the discovery of secretin.

Q52. For defense against a virus attack, the body produces:

  • A. Antibodies
  • B. Histamines
  • C. Antigens
  • D. Interferons

Explanation: The correct answer is Interferons. Interferons are proteins produced by host cells in response to viral infections. They play a crucial role in the immune response by inhibiting viral replication within host cells and activating immune cells. While antibodies are essential for neutralizing viruses outside cells, they are not the primary defense against viruses that have already entered cells. Histamines are related to allergic responses, and antigens are not produced by the body but are targets for the immune system.

Why the other options are wrong
  • A. Antibodies are crucial proteins of the immune system that specifically target and neutralize foreign objects like bacteria and viruses. However, they are more involved in targeting bacteria and extracellular viruses rather than directly combating viruses within cells.
  • B. Histamines are involved in allergic reactions and regulating physiological functions such as gastric acid secretion. They do not directly combat viral infections.
  • C. Antigens are foreign molecules that trigger an immune response. They are not produced by the body; instead, they are recognized by antibodies and immune cells.

Q53. Short life cycle is a plant adaptation to survive in:

  • A. High temperature
  • B. Low temperature
  • C. High soil pH
  • D. Low soil pH

Explanation: Plants growing in low temperatures may suffer from ill effects. To manage low temperatures, they possess well-developed bark for protection and short life cycles. Such plants bring changes in the composition of solutes in the cell to prevent ice crystal formation. The leaves and stems are hardy to withstand low temperatures. Most of them possess scale leaves, and the rate of transpiration is low to retard cooling.

Why the other options are wrong
  • A. At high temperatures, plants face challenges such as water loss and protein denaturation. Adaptations include deep root systems for water uptake and reflective surfaces to minimize heat absorption. However, a short life cycle is not a typical adaptation for high temperatures.
  • C. High soil pH affects nutrient availability, but plants themselves do not adapt their life cycle in response. Instead, soil amendments like elemental sulfur are used to lower soil pH.
  • D. Low soil pH can lead to nutrient deficiencies or toxicities. Adjustments to pH are typically managed through the addition of lime, rather than through changes in plant life cycles.

Q54. Baroceptors are the sensors in body responsible for determination of:

  • A. Blood Glucose
  • B. Blood Ammonia
  • C. Blood 𝑝H
  • D. Blood Pressure

Explanation: Baroreceptors are mechanoreceptors located in blood vessels near the heart that provide the brain with information about blood volume and pressure by detecting the level of stretch on vascular walls.

Why the other options are wrong
  • A. Blood glucose is monitored by chemoreceptors, not baroreceptors. Baroreceptors are not involved in detecting chemical levels like glucose.
  • B. Baroreceptors do not detect blood ammonia. Ammonia levels are measured through chemical testing, not sensory receptors like baroreceptors.
  • C. Blood pH is sensed by chemoreceptors, which detect chemical changes. Baroreceptors, being mechanoreceptors, do not sense pH levels.

Q55. Which one of the following is not a draught animal?

  • A. Buffalo
  • B. Mule
  • C. Elephant
  • D. Yak

Explanation: Elephants, although used for heavy lifting in industries such as logging, are not traditional draught animals in agriculture. Draught animals like buffaloes, mules, and yaks are specifically bred and trained for agricultural tasks such as plowing and transporting goods across fields. These animals are chosen for their ability to work efficiently in these environments, unlike elephants, which are not typically utilized in such roles.

Why the other options are wrong
  • A. Buffaloes are commonly used as draught animals, especially in agriculture, due to their strength and endurance.
  • B. Mules are highly valued as draught animals because they are strong and hardy, often used for carrying loads and plowing fields.
  • D. Yaks are used as draught animals in mountainous regions, where they are essential for carrying loads and plowing.

Q56. Which of the following is not isotonic to sea water?

  • A. Myxine (Hagfish)
  • B. Skates
  • C. Sharks
  • D. Teleost (Bony Fishes)

Explanation: Marine teleosts are hypoosmotic to seawater, so they face osmotic loss of water and diffusional gain of NaCl across the gill.

Why the other options are wrong
  • A. Myxine, or hagfish, are isotonic to seawater, meaning their internal osmotic pressure matches the external environment, so they do not need to actively regulate their osmotic balance.
  • B. Skates maintain an isotonic condition with seawater through the retention of urea, which balances osmotic pressures without needing significant regulatory mechanisms.
  • C. Sharks are isotonic to seawater due to the presence of urea and trimethylamine N-oxide in their blood, aligning their internal osmotic conditions with the surrounding environment.

Q57. Which of the following is not part of the first line of defense?

  • A. Sebum
  • B. Perspiration
  • C. Interferon
  • D. Epidermis

Explanation: The first line of defense includes physical and chemical barriers like the skin (including the epidermis), sebum, and perspiration, which help prevent pathogens from entering the body. Sebum and perspiration are secretions that support these barriers. Interferon, however, is part of the second line of defense. It is a protein that aids in the immune response by inhibiting viral replication and activating immune cells. This distinction makes interferon not a component of the first line of defense.

Why the other options are wrong
  • A. Sebum is an oily substance secreted by sebaceous glands in the skin, forming part of the physical barrier in the first line of defense.
  • B. Perspiration, or sweat, helps to flush out pathogens from the skin surface, making it a component of the first line of defense.
  • D. The epidermis is the outermost layer of the skin, serving as a physical barrier against pathogens, thus part of the first line of defense.

Q58. Which one of the following is not an insect?

  • A. Ticks
  • B. Honey bee
  • C. Beetle
  • D. Wasp

Explanation: Ticks are not insects because they are arachnids.Ticks are parasitic arachnids of the order Ixodida. They are part of the mite superorder Parasitiformes. Adult ticks are approximately 3 to 5 mm in length depending on age, sex, and species, but can become larger when engorged.

Why the other options are wrong
  • B. Honey bees are insects that belong to the class Insecta, characterized by having six legs and three main body segments.
  • C. Beetles are classified as insects within the class Insecta, known for their hard exoskeleton and wings covered by elytra.
  • D. Wasps are insects that belong to the class Insecta, with distinct features such as a narrow waist and six legs.

Q59. A condition called Goose pimples, are caused by:

  • A. Overcooled body
  • B. Bacteria
  • C. Environmental changes
  • D. Pollution

Explanation: Option A is correct.The hairs in mammals act as insulating organs and reduce heat loss. Thus the heat is retained in the body to a certain extent. To increase the effect of insulation, the hairs are erected. This occurs involuntarily when the body is over-cooled. In humans, it produces Goose pimples.

Why the other options are wrong
  • B. Bacteria do not cause Goose pimples. This physiological reaction is unrelated to bacterial activity.
  • C. While environmental changes can include temperature shifts, Goose pimples specifically result from a cold environment, making this option too broad and nonspecific.
  • D. Pollution does not directly cause Goose pimples. This condition is a physiological response to cold temperatures, not environmental pollutants.

Q60. Piriformis syndrome is associated with which of the following disorder:

  • A. Arthritis
  • B. Sciatica
  • C. Spondylosis
  • D. Disc slip

Explanation: Piriformis syndrome is a condition where the piriformis muscle in the buttocks compresses the sciatic nerve, leading to sciatica symptoms such as pain, numbness, and tingling in the lower limbs. While a slipped disc can also cause sciatica, piriformis syndrome is specifically related to muscle compression rather than disc issues. Arthritis and spondylosis, on the other hand, are primarily joint and spinal disorders that do not typically involve the piriformis muscle or cause sciatica directly.

Why the other options are wrong
  • A. Arthritis is primarily a joint disorder characterized by inflammation, pain, and stiffness. It does not typically involve the sciatic nerve or piriformis muscle.
  • C. Spondylosis is a degenerative condition affecting the spine, mainly due to aging. It does not specifically involve the piriformis muscle or cause sciatica directly.
  • D. A slipped disc can cause sciatica, but it is not directly linked to piriformis syndrome, which specifically involves the piriformis muscle compressing the sciatic nerve.

Q61. Which one of the following is not an exclusive trait of arthropoda?

  • A. Presence of wings
  • B. Jointed appendages
  • C. Haemocoel
  • D. Chitinous exoskeleton

Explanation: Phylum Arthropoda doesn’t possess wings.Yes, some arthropods have wings, but not all of them do; only members of the class Insecta within the subphylum Hexapoda have wings. These wings are attached to the thorax, along with the three pairs of legs that are characteristic of insects. Many other arthropods, such as spiders, scorpions, and crustaceans, lack wings entirely.

Why the other options are wrong
  • B. Jointed appendages are a distinctive feature of arthropods, allowing for complex movement and interaction with their environment.
  • C. A hemocoel is a primary body cavity in arthropods, functioning as part of their open circulatory system.
  • D. A chitinous exoskeleton is a defining characteristic of arthropods, providing protection and structural support.

Q62. Locomotary organ in leech is called?

  • A. Setae
  • B. Chatae
  • C. Parapodia
  • D. None of the above

Explanation: Leech has no locomotory organs.

Why the other options are wrong
  • A. Setae are bristle-like structures used for locomotion in earthworms, not leeches.
  • B. Chaetae, also known as setae, serve as locomotory structures in earthworms, but are absent in leeches.
  • C. Parapodia are paired appendages found in some polychaete annelids, not in leeches.

Q63. The number of Hyoid bone in human skull region is:

  • A. 1
  • B. 6
  • C. 22
  • D. 206

Explanation: There are overall 29 bones in the skull region, but there is only 1 hyoid bone in the human skull region.

Why the other options are wrong
  • B. This is incorrect. The number 6 does not correspond to any specific grouping of bones in the skull region related to the hyoid bone.
  • C. This is incorrect. The human skull comprises 22 bones, but this count does not include the hyoid bone, which is separate from the skull itself.
  • D. This is incorrect. 206 is the total number of bones in the adult human body, not the number of hyoid bones.

Q64. Which factor is not involved in release of Oxytocin in females:

  • A. Stretching of uterus
  • B. Stretching of Cervix
  • C. Low level of testosterone
  • D. Low level of progesterone

Explanation: The correct answer is Option C: Low level of testosterone. Testosterone is a male sex hormone and does not influence the release of oxytocin in females. Oxytocin is primarily involved in childbirth and breastfeeding, and its release is stimulated by the stretching of the uterus and cervix (Options A and B) as well as hormonal changes such as a decrease in progesterone levels (Option D). Therefore, low testosterone levels do not play a role in this process.

Why the other options are wrong
  • A. The stretching of the uterus during childbirth is a significant trigger for the release of oxytocin, which facilitates labor contractions.
  • B. Stretching of the cervix during labor is a major stimulus for oxytocin release, promoting uterine contractions.
  • D. A low level of progesterone towards the end of pregnancy helps in preparing the body for childbirth and can stimulate oxytocin release.

Q65. Chymotrypsin acts upon:

  • A. Starch in duodenum
  • B. Proteins in stomach
  • C. Proteins in duodenum in acidic medium
  • D. Proteins in duodenum in alkaline medium

Explanation: Chymotrypsin acts in the duodenum, the first part of the small intestine, where it helps break down proteins into smaller peptides. It is a digestive enzyme secreted by the pancreas as an inactive precursor, chymotrypsinogen, which is then activated in the small intestine by another enzyme called trypsin.

Why the other options are wrong
  • A. Starch is broken down by pancreatic amylase, not chymotrypsin, in the duodenum.
  • B. Pepsin, not chymotrypsin, breaks down proteins in the stomach, where the environment is acidic.
  • C. Chymotrypsin functions in the duodenum but requires an alkaline medium, unlike the acidic conditions of the stomach.

Q66. In E.C.G QRS complex represent:

  • A. Atrial systole
  • B. Atrial diastole
  • C. Ventricle systole
  • D. Ventricle diastole

Explanation: The second part of ECG is the QRS complex which features a small drop in voltage (Q) a large voltage peak ( R ) and another small drop in voltage (S). The QRS complex corresponds to the depolarization of the ventricle during ventricle systole.

Why the other options are wrong
  • A. The atrial systole is represented by the P wave, not the QRS complex. The P wave corresponds to the depolarization of the atria, leading to atrial contraction.
  • B. Atrial diastole is the relaxation phase of the atria, which is not represented by the QRS complex. The atria repolarize during the QRS complex, but this is not visible in the ECG due to the dominance of the ventricular signal.
  • D. The T wave follows the QRS complex and represents ventricular repolarization, corresponding to ventricular diastole (relaxation), not the QRS complex.

Q67. The common name of rubella is:

  • A. Whooping cough
  • B. German measles
  • C. African sleeping sickness
  • D. Tay Sach’s Disease

Explanation: It is also called German measles, but it is caused by a different virus than measles.

Why the other options are wrong
  • A. Whooping cough is the common name for pertussis, a bacterial infection that affects the respiratory system.
  • C. African sleeping sickness is the common name for African Trypanosomiasis, a parasitic disease transmitted by the tsetse fly.
  • D. Tay-Sach’s disease is a genetic disorder also known as GM2 gangliosidosis, not related to rubella.

Q68. A heterozygote fruit fly has more florescent pigments in their eyes than a wild homozygote fruit fly, this is an example of:

  • A. Co-dominance
  • B. Incomplete dominance
  • C. Over dominance
  • D. Complete dominance

Explanation: When the phenotypic expression of heterozygotes becomes more intense than the homozygous state of the dominant allele, is called over-dominance. So, the above example is an example of Over dominance.

Why the other options are wrong
  • A. In co-dominance, both alleles of a gene are equally expressed in the heterozygote, resulting in a phenotype that shows both traits simultaneously, such as the AB blood type where both A and B antigens are expressed.
  • B. Incomplete dominance occurs when neither allele is completely dominant over the other, leading to a blended phenotype in heterozygotes, such as pink flowers resulting from a cross between red and white four o'clock plants.
  • D. Complete dominance happens when one allele completely masks the effect of the other in a heterozygous condition, as seen in Mendelian inheritance where dominant traits are fully expressed.

Q69. A vein differs from an artery in having:

  • A. Strong muscular walls
  • B. Narrow lumen
  • C. Valves control direction of blood flow opposite to heart
  • D. Valves control direction of blood flow towards heart

Explanation: All the veins transport blood to the heart.

Why the other options are wrong
  • A. Both arteries and veins have muscular walls, but arteries have thicker walls due to higher blood pressure.
  • B. Arteries generally have a narrower lumen compared to veins, which have a wider lumen to accommodate slower blood flow.
  • C. This describes arteries, which carry blood away from the heart. Not all veins have valves to prevent backflow, but those that do ensure blood flows towards the heart.

Q70. Expiratory centre in medulla is:

  • A. Dorsal
  • B. Ventral
  • C. Lower part
  • D. All of the above

Explanation: The dorsal and lateral regions contain the expiratory centre, they stimulate expiration and inhibit inspiration.

Why the other options are wrong
  • B. The ventral respiratory group (VRG) in the medulla contains the inspiratory centre. It is not responsible for expiration and it increases the depth and rate of inspiration.
  • C. The lower part of the medulla is not specifically involved in respiratory control. It serves as a transition to the spinal cord and manages other neural functions.
  • D. This option is incorrect because the expiratory center is specifically located in the ventral region of the medulla, not in the dorsal or lower parts.

Q71. Polyploidy is more common in:

  • A. Animals
  • B. Plants
  • C. Both equally
  • D. Viruses

Explanation: Polyploidy (extra sets of chromosomes) is rare in animals but common in plants, where it often leads to larger size and hybrid vigor (e.g, wheat, cotton).

Why the other options are wrong
  • A. While some animals can exhibit polyploidy, it is generally rare due to the complexities involved in their development and reproduction. Most animals are diploid, meaning they have two sets of chromosomes, and polyploidy can often lead to complications in their viability.
  • C. This statement is incorrect because polyploidy is predominantly found in plants. While some organisms can exhibit polyploidy, it is not equally common across both groups.
  • D. Viruses do not have a cellular structure and do not possess chromosomes like cellular organisms. Instead, they rely on host cells for replication, making polyploidy an irrelevant concept for viruses.

Q72. The first stage in development of Xerosere is appearance of:

  • A. Foliose lichens
  • B. Crustose lichens
  • C. Fruticose lichens
  • D. Climax stage

Explanation: Due to great exposure to the sun and extreme deficiency of water, the first pioneers in the bare rock area are a few simple organisms. The most successful of such organisms is crustose lichens.

Why the other options are wrong
  • A. Foliose lichens are typically found in later stages, as they require more nutrients than crustose lichens.
  • C. Fruticose lichens appear in later stages, after crustose and foliose lichens have altered the environment.
  • D. The climax stage is the final stage of succession, characterized by a stable and mature ecosystem.

Q73. Mg++ and Ca++ are excreted in fishes through:

  • A. Kidney
  • B. Gills
  • C. Skin
  • D. All of the above

Explanation: Option A is correct.The kidneys in fishes play a vital role in osmoregulation, helping maintain the balance of water and salts in their bodies despite different aquatic environments. In addition to filtering nitrogenous wastes, they are especially important in the excretion of divalent ions such as magnesium (Mg²⁺) and calcium (Ca²⁺), which, if accumulated, can disturb cellular and physiological processes. Marine fishes actively excrete these excess salts through their kidneys and gills, while freshwater fishes conserve essential ions and excrete large amounts of dilute urine to maintain osmotic balance. Thus, fish kidneys are central to both waste removal and the regulation of ionic composition of body fluids.

Why the other options are wrong
  • B. The gills primarily handle the exchange of gases and the excretion of monovalent ions such as Na+ and Cl-. They are less involved in the excretion of divalent ions.
  • C. Fish skin primarily serves as a barrier and is not directly involved in the excretion of ions like Mg++ and Ca++. It mainly deals with water permeability.
  • D. This option is incorrect because each organ has specific roles. Kidneys are responsible for excreting divalent ions, while gills and skin have different functions.

Q74. Vomit centre is located in:

  • A. Pons
  • B. Midbrain
  • C. Cerebellum
  • D. Medulla

Explanation: The medulla oblongata is the posterior part of the brainstem and plays a key role in controlling autonomic functions and reflexes, such as vomiting. This is why the vomit center is located here. In contrast, the pons is more involved with sleep and respiratory rhythms, the midbrain with sensory information processing, and the cerebellum with motor control and balance. None of these has a direct role in the vomiting reflex.

Why the other options are wrong
  • A. The pons is primarily involved in functions such as sleep and breathing regulation. It acts as a bridge between various parts of the brain but does not control vomiting.
  • B. The midbrain is involved in processes related to vision, hearing, motor control, and alertness. It does not manage vomiting reflexes.
  • C. The cerebellum is responsible for coordination and balance, ensuring smooth and precise movements. It is not associated with the vomiting reflex.

Q75. Which of the following is a summer variety?

  • A. Figs
  • B. Cabbages
  • C. Oranges
  • D. Pears

Explanation: Figs (Ficus carica) are generally known for their sweet and succulent fruits, and they are indeed associated with the summer season in many regions. The timing of the fig fruiting season can vary based on factors such as the fig variety, climate, and local conditions. However, in many places, figs tend to ripen and are harvested during the summer months.

Why the other options are wrong
  • B. Cabbage is a cool-season vegetable that thrives in spring and autumn. It is not considered a summer variety as it prefers cooler temperatures found in early spring or fall.
  • C. Oranges are typically associated with warm and tropical climates, but many varieties are harvested in winter, especially in colder regions where cold-tolerant citrus varieties are grown. Therefore, they are not considered a summer variety.
  • D. Pears are generally harvested in late summer to early autumn, but they are often associated with being a winter fruit due to their storage capabilities. As such, they are not classified as a summer variety.

Q76. Depolarization of neuron is characterized by:

  • A. Na+ into the axon and K+ out of the axon
  • B. K+ into the axon and Na+ out of the axon
  • C. Na+ and K+ within the axon toward the axon terminal
  • D. Increased Na+ permeability leading to an influx of Na+

Explanation: When a neuron fiber is stimulated by a stimulus of adequate strength (threshold stimulus), the stimulated area of the fiber becomes several times more permeable to Na+ than to K+ due to the opening of voltage-regulating Na+ gates. As a result, Na gates permit the influx of Na+ ions by diffusion. Since more Na+ ions are entering than leaving, the electrical potential of the membrane changes from -70 mV towards zero and then reaches 50 mV. This reversal of polarity across two sides of the membrane is called depolarization. This electropositive inside and electronegative outside last for about one millisecond till the Na+ gates are closed. Note that K+ is not involved in the depolarization of neurons. It is involved in repolarization and hyperpolarization.

Why the other options are wrong
  • A. This option is incorrect. While Na+ does move into the axon during depolarization, K+ does not move out until repolarization.
  • B. This option is incorrect. During depolarization, Na+ ions move into the axon, not K+.
  • C. This option is incorrect. Depolarization involves the influx of Na+ from outside the neuron, not movement within the axon.

Q77. The center of porphyrin in the head region of hemoglobin is occupied by:

  • A. Potassium
  • B. Sodium
  • C. Magnesium
  • D. Iron

Explanation: Haemoglobin consists of four polypeptide chains. Each chain is associated with a haem group. Haeme group is an iron-containing group, which consists of porphyrin with a central atom of ferrous (iron) between four pyrrole rings.

Why the other options are wrong
  • A. This option is incorrect. Potassium is not involved in the structure of the heme group in hemoglobin. It is primarily an electrolyte important for cellular function.
  • B. This option is incorrect. Sodium plays a role in nerve impulse transmission and fluid balance, but not in the structure of hemoglobin's heme group.
  • C. This option is incorrect. Magnesium is a central component in chlorophyll, not in the heme group of hemoglobin.

Q78. Syphilis is caused by:

  • A. Spirochete
  • B. Nostoc
  • C. Water blooms
  • D. Cyanobacteria

Explanation: Syphilis is caused by the bacterium Treponema pallidum, which belongs to the spirochete group. Spirochetes are notable for their spiral shapes and unique motility mechanisms. This bacterial group includes pathogens known for causing various diseases, with Treponema pallidum specifically linked to syphilis. In contrast, the other options are related to cyanobacteria, which are photosynthetic bacteria not associated with sexually transmitted infections. Nostoc and cyanobacteria are both non-pathogenic in the context of syphilis, and water blooms are an environmental concern rather than a bacterial classification.

Why the other options are wrong
  • B. This option is incorrect as Nostoc is a genus of cyanobacteria known for forming colonies in aquatic environments and soil. They have no connection to sexually transmitted infections like syphilis.
  • C. This option is incorrect because water blooms are phenomena caused by the rapid growth of algae in water bodies, often due to high nutrient levels. They are unrelated to any bacterium that causes syphilis.
  • D. This option is incorrect because cyanobacteria, also known as blue-green algae, are photosynthetic bacteria that do not cause infections like syphilis. They are more commonly associated with ecological and environmental impacts.

Q79. The organism developed with two heads and one trunk is called:

  • A. Identical twins
  • B. Dizygotic twins
  • C. Fraternal twins
  • D. Siamese twins

Explanation: Siamese twins or also known as Conjoined twins. It is a very rare condition in which twins are joined side to side at the pelvis and part or all of the belly (abdomen) and chest but with separate heads. Such twins develop when an early embryo only partially separates to form two individuals.

Why the other options are wrong
  • A. Identical twins, also known as monozygotic twins, result from a single fertilized egg that splits to form two separate embryos. They do not develop with two heads and one trunk.
  • B. Dizygotic twins, or fraternal twins, result from two separate eggs fertilized by two separate sperm. They are two distinct individuals and do not share body structures.
  • C. Fraternal twins are another term for dizygotic twins, meaning they are not identical and do not share physical structures such as a trunk.

Q80. This is used as a substrate during the formation of alcohol:

  • A. Sucrose
  • B. Glucose
  • C. Galactose
  • D. Mannose

Explanation: Sucrose or cane sugar is widely distributed among higher plants. Its commercial source is solely sugarcane and beet. It is used as a substrate for the formation of alcohol. Glucose is a widely distributed sugar.

Why the other options are wrong
  • B. Although glucose is directly used in fermentation, it is not the initial substrate for many industrial alcohol fermentations where sucrose is preferred due to its availability and cost-effectiveness.
  • C. Galactose is not typically used as a substrate in conventional alcohol production processes, as it is less common and not as economically viable as sucrose.
  • D. Mannose is rarely used as a substrate in alcohol fermentation because it is not as readily available or as efficient in fermentation processes compared to other sugars like sucrose.

Q81. If the required excitation voltage is given, for which element the x − rays spectrum consists of three spectral lines i.e. Kα Kβ Lα :

  • A. Na
  • B. B
  • C. K
  • D. Ca

Explanation: A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from the emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. A spectral line may be observed either as an emission line or an absorption line.Option A: The electronic configuration of Na is = 1s2,2s2,2p6,3s1 There are 2 electrons in 1st shell, 8 in 2nd and 1 in 3rd. The difference between the highest and lowest shells is 3-1=2. The spectral lines are (2,1). The two are K(alpha), and K(beta) and one is K(gamma).

Why the other options are wrong
  • B. Boron (B) has an electronic configuration of 1s2 2s2 2p1. It doesn't have enough electrons in higher energy levels to produce the Kα, Kβ, and Lα lines simultaneously. Therefore, it cannot exhibit the specified three spectral lines.
  • C. Potassium (K) has an electronic configuration of 1s2 2s2 2p6 3s2 3p6 4s1. It can produce Kα and Kβ lines but its higher energy levels result in transitions that do not match the Lα line requirement for this specific question.
  • D. Calcium (Ca) has an electronic configuration of 1s2 2s2 2p6 3s2 3p6 4s2. While it can produce some spectral lines, it also does not align with the requirement for Kα, Kβ, and Lα lines due to its electron configuration and the transitions involved.

Q82. SiO2 is the only oxide that reacts with:

  • A. HClaq
  • B. KOHaq
  • C. Steam
  • D. SO3

Explanation: SiO2 is an acidic oxide and reacts with strong bases. Among the given options, it will react with hot, concentrated KOH(aq) due to the need for strong conditions to overcome its extensive covalent bonding. It does not react with HCl(aq) because it is not a base. It doesn't react with steam as the strong covalent network structure of SiO2 is too stable to break under such conditions. Lastly, SO3 is also an acidic oxide, and thus, does not react with another acidic oxide like SiO2.

Why the other options are wrong
  • A. SiO2 is not basic and does not react with acids like HCl, as it lacks oxide ions.
  • C. SiO2 does not react with steam because its covalent network structure does not break easily.
  • D. Both SiO2 and SO3 are acidic, hence they do not react with each other.

Q83. The cation that distort the electron cloud of NO3− ion more and facilitates its decomposition is:

  • A. Li+
  • B. Mg2+
  • C. Cs+
  • D. Be2+

Explanation: Polarizability refers to the ability of a cation to distort the electron cloud of an anion in an ionic compound and the anionic cloud is pulled towards the cation when it gets distorted. According to Fajan’s rule, the greater charge density(charge/size) on a cation leads to greater distortion. Due to higher charge and smaller size, the charge density of Be++ is and so it will distort the electron cloud of NO3- more facilitating its decomposition.

Why the other options are wrong
  • A. Li+ has a small size but a single positive charge. This results in relatively low charge density compared to doubly charged cations, limiting its ability to significantly polarize the NO3− ion.
  • B. Mg2+ has a larger ionic radius, resulting in a lower charge density compared to smaller cations with the same charge. This makes it less effective at polarizing the NO3− ion.
  • C. Cs+ has a very large ionic size and a single positive charge, leading to very low charge density, making it the least effective at polarizing NO3−.

Q84. The energy of electron in the first excited state of Hydrogen atom in J/atom is:

  • A. 2.8 × 10−18 J/atom
  • B. 0.545 × 10−18 J/atom
  • C. −2.18 × 10−18 J/atom
  • D. −1312.36 J/atom

Explanation: By using the formula for the energy of an electron in the nth orbitEn=-{me-4Z2/8 ε2 h2 n2}For hydrogen Z=1 and by putting values of constants also first excited state of hydrogen means, n=2 which is the second shell to which the ground state hydrogen electron has excited to. En= (-2.178×10-18)×1/n2

Why the other options are wrong
  • A. This option is incorrect. This value does not correspond to the energy of an electron in the first excited state.
  • C. This option is incorrect because it represents the energy of the electron in the ground state, not the first excited state.
  • D. This option is incorrect as it does not reflect the energy levels associated with electron transitions in hydrogen atoms and uses incorrect units.

Q85. Unhybrid "p" orbitals on linear overlap:

  • A. Always form Pi(π) bond
  • B. Always form Sigma(σ) bond
  • C. Neither form σ nor π bond
  • D. Form more reactive and more unstable π bond

Explanation: Unhybridized orbitals can only form π bonds upon sideways or parallel overlap and cannot form sigma bonds.

Why the other options are wrong
  • B. Sigma bonds are formed by the linear or end-to-end overlap of orbitals, typically involving hybridized orbitals, not unhybridized p orbitals.
  • C. This is incorrect as unhybridized p orbitals are specifically capable of forming π bonds through their sideways overlap.
  • D. While π bonds formed by unhybridized p orbitals can be reactive due to their weaker overlap compared to σ bonds, the term 'more unstable' is misleading without context. The key aspect is the type of overlap, not stability.

Q86. Amino acid leucine is coded by how many codons:

  • A. 1
  • B. 2
  • C. 4
  • D. 6

Explanation: Amino acid leucine is coded by 6 codons UUA, UUG, CUU, CUC, CUA, and CUG.

Why the other options are wrong
  • A. This option is incorrect. No amino acid is coded by only one codon.
  • B. This option is incorrect. While some amino acids are encoded by two codons, leucine is not one of them.
  • C. This option is incorrect. Leucine is encoded by more than four codons.

Q87. Whenever Pb shows inert pair effect it always form:

  • A. Ionic bond
  • B. Covalent bond
  • C. Co-ordinate covalent bond
  • D. Metallic bond

Explanation: The inert pair effect is the effect of the s-orbitals in which they do not participate to make bonds with other molecules because the electrons are held tightly due to the strong attraction of the nucleus towards the electrons. The reason for this effect is that the elements having the f-orbital show poor shielding effect due to their diffused shapes. As a result, the nuclear charge on their s orbitals increases due to this poor shielding effect. This results in more attraction and binding of the electrons in the s-orbitals which stops them from getting out and prevents the metal to acquire a +4 oxidation state. The electronic configuration of lead isPb (82) = (Xe) 4f14 5d10 6s2 6p2Due to the inert pair effect, the +2 oxidation state of Pb is more stable than its +4 oxidation state. Further on moving down the group, the ionization enthalpy decreases. As a result, the sum of the first two ionization enthalpies of Pb is quite low and hence Pb can easily lose two electrons to form Pb2+ ions. Consequently, Pb forms ionic compounds.

Why the other options are wrong
  • B. This option is incorrect. Although lead can form covalent bonds, the inert pair effect makes it more likely to form ionic bonds because the +2 oxidation state is more stable than +4.
  • C. This option is incorrect. Co-ordinate covalent bonds involve a shared pair of electrons where both electrons come from the same atom. Lead's tendency to form Pb2+ ions doesn't favor this type of bonding in the context of the inert pair effect.
  • D. This option is incorrect. Metallic bonds involve a sea of delocalized electrons, which is not characteristic of the ionic nature that lead exhibits due to the inert pair effect.

Q88. In the compound CO2 and H2O the hybridization in oxygen is respectively:

  • A. sp2 and sp2
  • B. sp2 and sp3
  • C. sp3 and sp3
  • D. sp3 and sp2

Explanation: In the carbon dioxide molecule, oxygen hybridizes its orbitals to produce three sp2 hybrid orbitals. The Unhybridized p orbital in the oxygen atom remains unchanged and is primarily used to form a pi bond. However, out of these three sp hybrid orbitals, only one will be used to produce a bond with the carbon atom.The central atom, which is hybridized, is oxygen. In the formation of the water molecule, there are three 2p orbitals and one 2s orbital. They are combined to generate the sp3 hybrid orbitals. Furthermore, each hydrogen atom forms covalent connections with two hybrid orbitals, and two hybrid orbitals are occupied by lone pairs during the process.

Why the other options are wrong
  • A. In both carbon dioxide and water, the oxygen atom's hybridization is different due to the differing molecular geometries and number of electron pairs. This option suggests identical hybridization, which is incorrect.
  • C. This option incorrectly assumes that both oxygen atoms in CO2 and H2O have the same hybridization. In reality, CO2 involves sp2 hybridization for the oxygen atom.
  • D. In CO2, the oxygen atom is sp2 hybridized due to the linear structure, while in H2O, it is sp3 hybridized. This option reverses the correct hybridizations.

Q89. According to M.O theory the number of molecular orbitals in O2 are:

  • A. 10
  • B. 7
  • C. 8
  • D. 9

Explanation: Oxygen atoms contribute ground-state molecular orbitals from 1s, 2s, and 2p electrons. The 1s orbitals form σ1s and σ*1s filled Mos. The 2s orbitals form σ2s and σ*2s filled MOs. The σ2p and π2p MOs are also filled, while the antibonding π*2p orbitals are partially filled in triplet oxygen (the ground state), or only one is filled in singlet oxygen. But the antibonding σ*the 2p orbital is ordinarily empty in the ground state, and higher orbitals are not filled unless the oxygen molecule absorbs light energy which is capable of exciting the electrons to higher orbitals.

Why the other options are wrong
  • B. This option is incorrect. The molecular orbital configuration for O2 includes more orbitals than just 7.
  • C. This option is incorrect. The molecular orbitals for O2 are formed from a combination of more atomic orbitals than 8.
  • D. This option is incorrect. The molecular orbitals for O2 involve a total of 10 orbitals, not 9.

Q90. Specie with dipole moment equal to zero is:

  • A. AlCl3
  • B. CH4
  • C. 1,4 − Dibromobenzene
  • D. All of the above

Explanation: Specie with dipole moment equal to zero is: 𝐴𝑙𝐶𝑙3 𝐶𝐻4 1,4 − 𝐷𝑖𝑏𝑟𝑜𝑚𝑜𝑏𝑒𝑛𝑧𝑒𝑛𝑒 because their structures allow for their charges to be 'canceled' out.

Why the other options are wrong
  • A. Aluminum chloride does not have a dipole moment, which is a measurement of the overall polarity of a molecule. The individual aluminum and chlorine bonds are polar, but the shape of the molecule, with the bonds at 120-degree angles from each other, cancels this out. This makes the molecule non-polar
  • B. Due to the tetrahedral structure of CH4, each bond pair is at an equal distance, indicating that they are symmetrically arranged. As a result, in CH4 each bond dipole moment cancels out one another, resulting in zero net dipole moment.
  • C. In 1,4-bromobenzene, the 2 dipole moments are directly opposite one another and face in exactly opposite directions with exactly equal magnitudes. They thus nullify each other and result in zero net dipole moment.

Q91. Aqueous KOH causes SN-reaction in alkylhalide. On which of the following alkylhalides KOHaq would like to attack easily.

  • A. CH3 − CH2 − Cl
  • B. CH3 − CH2 − Br
  • C. CH3 − CH2 − F
  • D. CH3 − CH2 − I

Explanation: Iodide ion is a very good leaving group due to low bond energy so the attack of KOH(aq) to proceed SN reaction and hence it can be easily substituted.

Why the other options are wrong
  • A. Chloride ion is a fair leaving group, but it is not as good as bromide or iodide. Therefore, the attack of KOH(aq) is less effective on CH3-CH2-Cl compared to iodide or bromide derivatives.
  • B. Bromide ion is a good leaving group, better than chloride but not as good as iodide. KOH(aq) attacks this substrate more easily than chlorides but less so than iodides.
  • C. Fluoride ion is a poor leaving group due to its high bond strength and low polarizability, making KOH(aq) attack very ineffective on CH3-CH2-F.

Q92. Three reactions are giveni. H2SO4 + 2HF ⟶ F2 + SO2 + 2H2Oii. H2SO4 + 2HBr ⟶ Br2 + SO2 + 2H2Oiii. H2SO4 + 8HI ⟶ 4I2 + H2S + 4H2OThe strongest reducing agent in these reactions is:

  • A. HI
  • B. HF
  • C. HBr
  • D. All of the above

Explanation: HI is the strongest reducing agent. The compounds having low dissociation energy are a stronger reducing agent than the others having high dissociation energy. The HI has low thermal stability as compared to HF, HCI, and HBr. HI can release H atoms easily as compared to HF, HCI, and HBr to reduce the other compound. The decreasing order of the reducing character is HI>HBr>HCl>HF

Why the other options are wrong
  • B. HF is not a strong reducing agent due to the high bond dissociation energy of the H-F bond. The fluoride ion is small, and its electrons are tightly held, making it difficult to oxidize. Therefore, HF is a poor reducing agent.
  • C. HBr is a reducing agent, but it is not as strong as HI. While it can act as a reducing agent, the bond dissociation energy of HBr is higher than that of HI, making it less effective at releasing hydrogen atoms.
  • D. This option is incorrect because not all substances listed are strong reducing agents. Specifically, HF is a poor reducing agent, while HI is the strongest among them.

Q93. An unknown gas diffuses 5 times slower than that of H2. The molecular mass of the unknown gas is:

  • A. 50
  • B. 10
  • C. 15
  • D. 25

Explanation: According to Graham’s law of diffusion of gases, the rate of diffusion is inversely proportional to the square root of molar masses of gases. Using the formular1/r2 =√M1/M2(5rH2/r2)2 =(√M2/2)225×2=M2M2=50

Why the other options are wrong
  • B. This is incorrect. A molecular mass of 10 would mean the gas diffuses faster, not slower, than H2.
  • C. This is incorrect. A molecular mass of 15 is too low for a gas that diffuses 5 times slower than H2.
  • D. This is incorrect. A molecular mass of 25 would not result in the gas diffusing 5 times slower than H2.

Q94. Hydrogen bonding in H − F is stronger than H2O and NH3. The highest boiling point among the three is of:

  • A. HF
  • B. NH3
  • C. H2O
  • D. All have equal boiling points

Explanation: Each water molecule has two hydrogen atoms. Whereas, each HF molecule has only one hydrogen atom. And hence, water molecule takes part in extensive and more hydrogen bonding than Hydrofluoric acid. Water molecule through their extensive hydrogen bonding forms bulky molecule and it is very difficult to break their bonds. A large amount of energy is required to break all its bonds. Thus H2O has a higher boiling point than HF.

Why the other options are wrong
  • A. Although HF has strong hydrogen bonding due to the high electronegativity of Fluorine (F), it can only form one hydrogen bond per molecule. Consequently, its boiling point (19.5°C) is lower than that of water, which can form more hydrogen bonds per molecule.
  • B. In Ammonia (NH3), the presence of one lone pair on nitrogen limits hydrogen bonding. As a result, NH3 has a boiling point of about -33.3°C, which is lower than that of both HF and H2O.
  • D. This option is incorrect as the boiling points of HF, NH3, and H2O are different due to variations in their hydrogen bonding capabilities.

Q95. We have three test tubes having aqueous solutions of Ca(NO3)2, Ba(NO3)2 and K2CO3 respectively. On addition of dil H2SO4. Which test tube solution turns milky?

  • A. Ca(NO3)2 solution
  • B. Ba(NO3)2 solution
  • C. K2CO3 solution
  • D. All turned milky

Explanation: When sulfuric acid is added to calcium nitrate, calcium sulfate is produced, which is slightly soluble and often forms a fine precipitate that appears milky. This contrasts with barium nitrate, which forms a dense white precipitate of barium sulfate, and potassium carbonate, which releases carbon dioxide gas causing bubbling but no precipitate. Thus, only the calcium nitrate solution turns milky due to the formation of a fine calcium sulfate precipitate.

Why the other options are wrong
  • B. When sulfuric acid is added to barium nitrate, barium sulfate and nitric acid are formed: Ba(NO3)2(aq) + H2SO4(aq) → BaSO4(s) + 2 HNO3(aq). Barium sulfate is highly insoluble and forms a heavy white precipitate rather than a milky solution.
  • C. Adding sulfuric acid to potassium carbonate produces potassium sulfate, carbon dioxide, and water: H2SO4 + K2CO3 → K2SO4 + CO2 + H2O. The reaction releases carbon dioxide gas, causing effervescence but not a milky appearance.
  • D. This option is incorrect because each reaction behaves differently: calcium and barium form different types of precipitates, and potassium carbonate releases gas.

Q96. The chelating ligand out of the following is:

  • A. CH3COO−
  • B. (CH2)2(NH2)2
  • C. SCN−
  • D. NO2−

Explanation: A chelating ligand is a ligand that is mostly attached to a central metal ion by bonds that are from two or more donor atoms. In other words, these are a type of ligands where the molecules can form several bonds to a single metal ion or they are ligands with more than one donor site.The chelating ligand here Is (𝐶𝐻2)2(𝑁𝐻2)2

Why the other options are wrong
  • A. The acetate ion (CH3COO−) is a monodentate ligand, meaning it can donate only one pair of electrons to a metal ion. It does not have the ability to form multiple bonds to a single metal center like a chelating ligand.
  • C. Thiocyanate (SCN−) is an ambidentate ligand, meaning it can bind to a metal center through either the sulfur or nitrogen atom. However, it does not form multiple bonds simultaneously to a single metal ion like chelating ligands do.
  • D. The nitrite ion (NO2−) can act as a monodentate ligand, binding through either nitrogen or oxygen. Although it can potentially bind in two different ways, it does not simultaneously form multiple bonds to a single metal center to act as a chelating ligand.

Q97. Evaporation depends upon:

  • A. Surface area
  • B. Temperature
  • C. Both (A) & (B)
  • D. None of the above

Explanation: The correct answer is that evaporation depends on both surface area and temperature. Evaporation is a surface phenomenon, meaning that more molecules can escape to the air when the surface area is larger. Additionally, increasing the temperature provides more energy to the molecules, allowing them to overcome intermolecular forces more easily and escape into the vapor phase. Therefore, both factors are crucial in determining the rate of evaporation. Options that consider only one factor or neither are incomplete explanations of the process.

Why the other options are wrong
  • A. Evaporation is a surface phenomenon. Increasing the surface area allows more molecules to escape into the air, speeding up evaporation. This is why spreading clothes out to dry makes them dry faster.
  • B. Higher temperatures provide more energy to molecules, enabling them to overcome intermolecular forces and escape into the vapor phase more readily, thus increasing the rate of evaporation.
  • D. This option is incorrect because both surface area and temperature are known factors that influence the rate of evaporation.

Q98. Students were heating CaCO3 in an open container to produce CO2 gas,CaCO3(s) ⟶ CaO(s) + CO2(g)If we increase pressure on this system the:

  • A. Equilibrium will shift towards right
  • B. Equilibrium will shift towards left
  • C. Equilibrium will not be disturbed
  • D. System does not obey equilibrium rules

Explanation: The correct answer is that the system does not obey equilibrium rules. Chemical equilibrium can only be established in a closed system where reactants and products are contained. In this scenario, the CaCO3 is heated in an open container, allowing the CO2 gas to escape. As a result, the system cannot reach equilibrium, as the continuous loss of CO2 gas prevents the establishment of a dynamic balance between reactants and products.All other options are incorrect because they assume that equilibrium can be achieved or disturbed in an open system, which is not possible. The nature of an open system prevents the maintenance of chemical equilibrium as it allows mass to be lost to the surroundings.

Why the other options are wrong
  • A. This option is incorrect because the system is open, and equilibrium cannot be established. In an open system, the gas produced leaves the system, preventing the establishment of equilibrium.
  • B. This option is incorrect because the system is open, and equilibrium cannot be established. Changes in pressure do not affect an open system in the same way as a closed system.
  • C. This option is incorrect because in an open system, equilibrium cannot be reached in the first place. Since the system is open, any product formed escapes, and equilibrium cannot be maintained.

Q99. The oxidation state of platinum in [Pt(NH3)4(NO2)Cl]SO4 is:

  • A. III
  • B. II
  • C. 0
  • D. IV

Explanation: Explained in image below:

Why the other options are wrong
  • A. If the oxidation state of platinum is III, the charge balance equation would not be satisfied considering the charges of other ligands and the sulfate ion.
  • B. An oxidation state of II for platinum would not result in a neutral charge balance when taking into account the charges of the ligands and the counter ion.
  • C. Assuming platinum has an oxidation state of 0 would ignore the balancing needed with the negatively charged ligands and the sulfate ion, leading to an incorrect charge balance.

Q100. The outer electronic configuration of Cu+ ion is 4S03d10 with this configuration the aqueous solution of copper (I) compound is:

  • A. Blue
  • B. Greenish blue
  • C. Bluish green
  • D. Colourless

Explanation: Transition elements exhibit color due to d-d transition. d-d transition is possible only when the d subshell has unpaired electrons. Cu+ has filled the orbital: 4s0 3d10. Due to a lack of unpaired d- electrons Cu+ is colorless.

Why the other options are wrong
  • A. This option is incorrect. Blue color arises when there are unpaired d electrons that can undergo d-d transitions, which is not the case for Cu+.
  • B. This option is incorrect. A greenish blue color would indicate the presence of unpaired d electrons, which are absent in Cu+.
  • C. This option is incorrect. The appearance of a bluish green color would require unpaired d electrons, which Cu+ does not have.

Q101. For the reaction,CO(g) + (1/2)O2(g) ⟶ CO2(g)

  • A. Kp > Kc
  • B. Kp < Kc
  • C. Kp = Kc
  • D. Kp ≥ Kc

Explanation: For the reaction. CO(g)+1/2O2(g) = CO2(g) Kp<Kc

Why the other options are wrong
  • A. This option is incorrect. In gaseous reactions, Kp is related to Kc by the expression Kp = Kc(RT)^(Δn), where Δn is the change in moles of gas. Since Δn = -0.5 for this reaction, Kp < Kc.
  • C. This option is incorrect. Kp equals Kc only when Δn = 0, which is not the case here. For this reaction, Δn = -0.5, leading to Kp < Kc.
  • D. This option is incorrect. Given that Δn = -0.5 for the reaction, Kp is less than Kc; thus, Kp cannot be greater than or equal to Kc.

Q102. Initially one mole each N2 and O2 were made to react as,If at equilibrium 0 ∙ 25 moles of O2 is present the equilibrium concentration of NO will be:

  • A. 0.50 moles
  • B. 0.125 moles
  • C. 1.50 moles
  • D. 1.75 moles

Explanation: N2(g) + O2(g) 2NO(g) As from the balance chemical equation it is clear that 1 mole O2 gives 2 mole NO so as 0.25 mole O2 left so 0.75 mole consumed so it will give 1.50 mole NO.2x0.75-1=1.50

Why the other options are wrong
  • A. This option is incorrect. According to the balanced chemical equation N2(g) + O2(g) → 2NO(g), each mole of O2 consumed yields 2 moles of NO. If 0.75 moles of O2 are consumed, 1.50 moles of NO should form, not 0.50 moles.
  • B. This option is incorrect. The stoichiometry of the reaction implies that 0.75 moles of O2 consumption would yield 1.50 moles of NO. 0.125 moles is too low.
  • D. This option is incorrect. The reaction stoichiometry dictates that 0.75 moles of O2 consumed would produce exactly 1.50 moles of NO, not 1.75 moles.

Q103. The compound of manganese with zero reducing power is:

  • A. KMnO4
  • B. MnO2
  • C. MnCl2
  • D. Mn2(SO4)3

Explanation: The reducing power is the ability to give electrons and reduce others. The compound having maximum oxidation number will have the zero reducing power as it doesn’t have any remaining electrons to give other compounds.

Why the other options are wrong
  • B. In MnO2, manganese is in the +4 oxidation state. It can still donate electrons to reach its highest oxidation state of +7, so it has reducing power.
  • C. In MnCl2, manganese has an oxidation state of +2. It can further oxidize by losing more electrons, indicating some reducing power.
  • D. In Mn2(SO4)3, manganese has an oxidation state of +3. It can reach a higher oxidation state by donating more electrons, thus it possesses reducing power.

Q104. Chemical reactions associated with hydro-carbons is/are:

  • A. Electrophilic addition
  • B. Electrophilic substitutions
  • C. Free radical substitutions
  • D. All are possible

Explanation: Chemical reactions associated with hydrocarbons are:Electrophilic addition, Electrophilic substitutions, Free radical substitutions.

Why the other options are wrong
  • A. Electrophilic addition involves the breakage of double or triple bonds, characteristic of unsaturated hydrocarbons such as alkenes and alkynes.
  • B. Electrophilic substitution reactions occur primarily in aromatic hydrocarbons, where an electrophile replaces a hydrogen atom on the aromatic ring.
  • C. Free radical substitution is typical in saturated hydrocarbons like alkanes, where a hydrogen atom is replaced by a halogen atom through a radical mechanism.

Q105. Henderson-Hasselbalch equation is used to calculate the pH of a buffer solutions. The correct representation of the equation is:

  • A. pH = pKa + log([Acid]/[Salt])
  • B. pH = pKa - log([Salt]/[Acid])
  • C. pH = pKa + log([Salt]/[Acid])
  • D. pH = pKa - log([Acid]/[Salt])

Explanation: Henderson-Hasselbalch equation to calculate the pH of a buffer solution ispH=pka+log[salt]/[Acid]

Why the other options are wrong
  • A. This option is incorrect. The formula should have the concentration of salt over the concentration of acid.
  • B. This option is incorrect. The formula should have a plus sign, not a minus sign.
  • D. This option is incorrect. The formula should have the concentration of salt over the concentration of acid, and use a plus sign.

Q106. If the pH of the solution is 9 its OH− ions concentration is:

  • A. 10−5
  • B. 5
  • C. 10−9
  • D. 9

Explanation: As we know that,pH+pOH=14pOH=14-9=5Also, pOH=log[OH-][OH-]=antilog(pOH)[OH]=antilog (5)[OH]=10-5

Why the other options are wrong
  • B. This option is incorrect because it represents a miscalculation. The concentration of OH− ions is not expressed in direct numerical values but in powers of 10.
  • C. This option is incorrect. It seems to confuse the concentration of H+ ions with OH− ions. Remember, pH refers to H+, and pOH refers to OH−.
  • D. This option is incorrect as it mistakenly treats the numerical value of pH as the concentration of OH− ions, which is not the case.

Q107. During the formation of addition polymers, which smaller molecules you think are eliminated:

  • A. H2O
  • B. HCl
  • C. NH3
  • D. No molecules are eliminated

Explanation: In polymer chemistry, an additional polymer is a polymer that forms by simple linking of monomers without the co-generation of other products. Addition polymerization differs from condensation polymerization, which does co-generate a product, usually water.In addition, polymerization monomers simply react to form polymers without the formation of by products.

Why the other options are wrong
  • A. This option is incorrect. Water is typically eliminated in condensation polymerization, not in addition polymerization.
  • B. This option is incorrect. HCl is not a by-product of addition polymerization; it may be eliminated in certain condensation polymerizations.
  • C. This option is incorrect. Ammonia is not eliminated during addition polymerization processes.

Q108. If the overlap of sp3 hybrid orbitals in carbon atoms is smaller, the bond so formed is:

  • A. Weak
  • B. Strong
  • C. Less energetic
  • D. More stable

Explanation: According to the quantum mechanical approach, a covalent bond is formed when half-filled orbitals in the outer or valence shells of two atoms overlap, so as a result of this overlap, the electrons with opposite spins become paired to stabilize themselves. Larger the overlap, the stronger the bond is formed.

Why the other options are wrong
  • B. This option is incorrect because a strong bond requires a larger overlap between orbitals, allowing for more effective electron sharing.
  • C. This option is not directly relevant to the overlap concept. The energy of a bond relates more to its stability and strength.
  • D. A more stable bond typically results from stronger overlap, not smaller overlap. Thus, this option is incorrect in this context.

Q109. The minimum energy below which no reaction occur in reactant molecules is:

  • A. Average Kinetic Energy of the molecules
  • B. Potential Energy of the molecules
  • C. Free Energy of the molecules
  • D. Activation Energy of the molecules

Explanation: Activation energy is the minimum energy that the reactants must have to be converted into products. It can also be described in terms of energy which activate reactants to start a chemical reaction.

Why the other options are wrong
  • A. The average kinetic energy of molecules is related to their motion and temperature. It does not determine if a reaction will occur, but rather the speed of molecular movement.
  • B. Potential energy relates to the energy stored due to molecular interactions and positions. While it plays a role in reactions, it is not the threshold energy required to start a reaction.
  • C. Free energy, specifically Gibbs free energy, determines the spontaneity of a reaction. It is not the minimum energy needed to initiate a reaction.

Q110. Reactants in a transition state:

  • A. Always change to product
  • B. Return back to reactants
  • C. May return to reactants or proceed to form products
  • D. Are of low energy

Explanation: The transition state is a high-energy state, and some amount of energy – the activation energy – must be added for the molecule to reach it. Because the transition state is unstable, reactant molecules don't stay there long but quickly proceed to the next step of the chemical reaction.If the molecules in the reactants collide with enough kinetic energy and this energy is higher than the transition state energy, then the reaction occurs, and products form. But if the k.E of colliding molecules is not enough and so transition state then the colliding molecules just bounce back unchanged.

Why the other options are wrong
  • A. This option is incorrect because it suggests that reaching the transition state guarantees the formation of products. In reality, the transition state is an unstable point, and the reaction can revert to reactants or proceed to products based on various factors such as energy and conditions.
  • B. This option partially describes what can happen in a transition state, but it is not the complete picture. While it is possible for reactants to revert back from the transition state, it’s also possible for them to proceed to form products if the conditions are right.
  • D. This option is incorrect because the transition state is characterized by a high-energy peak, not a low-energy state. It is an activated complex that requires additional energy to reach, differentiating it from both reactants and products.

Q111. Compound in which addition takes place through Markovnikov’s rule is:

  • A. CH3 − CH = CH − CH3
  • B. CH3 − C(CH3) = CH − CH3
  • C. C2H5 − CH = CH − CH3
  • D. CH3 − CH = CH − C3H7

Explanation: Markovnikov Rule predicts the regiochemistry of HX addition to unsymmetrically substituted alkenes. The halide component of HX bonds preferentially at the more highly substituted carbon, whereas the hydrogen prefers the carbon which already contains more hydrogens.

Why the other options are wrong
  • A. This is a symmetrical alkene, meaning both carbons involved in the double bond have the same environment. Markovnikov’s rule is not applicable because there is no difference in substitution between the carbons.
  • C. Although this compound is unsymmetrical, both carbons in the double bond have a similar environment in terms of hydrogen atoms. Thus, Markovnikov's rule cannot distinctly predict the addition outcome.
  • D. While this compound appears asymmetrical, the lack of significant variance in substitution between the carbons in the double bond means Markovnikov's rule does not clearly determine the addition pattern.

Q112. The type of isomerism present in the compound given, is:

  • A. Structural
  • B. Optical
  • C. Stereo
  • D. None of the above

Explanation: Stereoisomers are isomers that have the same composition (that is, the same parts) but that differ in the orientation of those parts in space. There are two kinds of stereoisomers: enantiomers and diastereomers. The two conditions must be met for compounds to show Stereoisomerism(geometric isomerism) 1- There should be a C-C double bond to restrict the free rotation of attached groups.2- The two groups attached to the same C must be different.

Why the other options are wrong
  • A. Structural isomers, also known as constitutional isomers, have the same molecular formula but differ in the connectivity of atoms within the molecules.
  • B. Optical isomerism occurs when isomers have the same molecular formula and structural formula but differ in their effect on plane-polarized light, typically due to chiral centers.
  • D. This option implies that none of the given types of isomerism are correct, which is not true in this context as stereoisomerism is applicable.

Q113. During the formation of aqueous solution of any electrolyte:

  • A. Heat is evolved
  • B. Heat is absorbed
  • C. Heat may be evolved or absorbed
  • D. Electrolyte does not dissolve in water

Explanation: A solution is a homogeneous mixture of two or more substances and can either be in the gas phase, the liquid phase, or the solid phase. The enthalpy change of solution refers to the amount of heat that is released or absorbed during the dissolving process (at constant pressure). This enthalpy of solution can either be positive (endothermic) or negative (exothermic). The heat may be evolved or absorbed during the formation of aqueous solution of electrolytes and it completely depends upon their behaviour and properties of electrolytes being used.

Why the other options are wrong
  • A. Heat is evolved when an exothermic reaction occurs, such as when Na+ ions are formed in water. However, not all electrolytes behave this way.
  • B. Heat is absorbed in endothermic processes, like the dissolution of ammonium chloride, where the heat of solution is positive. Yet, this is not the case for all electrolytes.
  • D. This statement is incorrect as electrolytes are characterized by their ability to dissolve in water and dissociate into ions.

Q114. The compound with more than 10% solubility in pure water is:

  • A. M𝑔𝐶𝑂3
  • B. A𝑙2(𝐶𝑂3)3
  • C. K2𝐶𝑂3
  • D. 𝑍𝑛𝐶𝑂3

Explanation: The solubility of ionic compounds in water is largely determined by the balance between lattice energy and hydration energy. Lattice energy is the energy required to separate the ions in a compound, and it increases with greater charge and smaller ionic size. Hydration energy is the energy released when ions are solvated by water molecules. For K2CO3, the K+ ions have a relatively large size and a +1 charge, resulting in lower lattice energy and higher solubility. In contrast, MgCO3, Al2(CO3)3, and ZnCO3 all have higher lattice energies due to their higher charges and smaller ionic sizes, making them less soluble in water.

Why the other options are wrong
  • A. MgCO3 has high lattice energy due to the +2 charge and smaller ionic size of Mg2+. This results in lower solubility in water.
  • B. Al2(CO3)3 has even higher lattice energy due to the +3 charge and small size of Al3+, making it very insoluble in water.
  • D. ZnCO3 has high lattice energy due to the +2 charge and smaller size of Zn2+, resulting in low solubility in water.

Q115. The mass of 𝑁𝑎𝑂𝐻 needed to prepare 0.2 molal solution in 500𝑔 pure water at 4℃ is:

  • A. 0.4𝑔
  • B. 4.0𝑔
  • C. 1.5𝑔
  • D. 1.0𝑔

Explanation: As for 0.2 molal solution 0.2 mole of NaOH is needed to dissolve in 1000 grams of water. For 500 grams0.2÷1000×500=0.1 mole of NaOHThe mass for 0.1 mole of NaOH is 40 g/mol×0.1mol = 4 grams.

Why the other options are wrong
  • A. This is incorrect. The calculation misinterprets the relationship between molality and mass, as it incorrectly divides or multiplies the values involved.
  • C. This is incorrect. The calculation underestimates the amount of NaOH by using incorrect molar mass or molality values.
  • D. This is incorrect. The calculation significantly underestimates the mass of NaOH needed by using incorrect proportions or molar mass.

Q116. The Fridel crafts catalyst “𝐴𝑙𝐶𝑙3” used in the substitution reactions of Benzene is good:

  • A. Electrophile
  • B. Lewis acid
  • C. Electron deficient species
  • D. Bear all properties

Explanation: The function of AlCl3(anhydrous), in the Friedel-Craft reaction, is to produce electrophile, which later adds to the benzene nucleus. This electrophilic aromatic substitution allows the synthesis of monoacetylated products from the reaction between arenes and acyl chlorides or anhydrides. The products are deactivated and do not undergo a second substitution. Normally, a stoichiometric amount of the Lewis acid catalyst is required for both the substrate and the product form complexes.

Why the other options are wrong
  • A. While AlCl3 helps in forming an electrophile during the reaction, it itself is not an electrophile. Instead, it acts to make other species more electrophilic.
  • C. AlCl3 is electron-deficient, which is why it acts as a Lewis acid. However, simply being electron-deficient does not fully describe its role in the reaction.
  • D. While AlCl3 has multiple roles, including acting as a Lewis acid and facilitating electrophile formation, it does not 'bear all properties' in a general sense, as this is too broad and vague.

Q117. The most reactive compound out of the following is:

  • A. Ortho hydroxy toluene
  • B. Ortho chloro ethyl benzene
  • C. Phenol
  • D. Para ethyl benzoic acid

Explanation: Substituents: -OH and -CH₃Effect: Both are activating groups. -OH is strongly activating; -CH₃ is weakly activating. Being ortho to each other increases electron density in the ring even more.This is even more activated than phenol, due to combined activating effects.

Why the other options are wrong
  • B. This option is incorrect because the chlorine atom has an electron-withdrawing effect, reducing the reactivity of the compound.
  • C. Substituent: -OHEffect: Strongly activating due to resonance donation of the lone pair on oxygen into the ring. Makes the ring highly reactive toward EAS, especially at ortho and para positions.
  • D. This option is incorrect because the carboxylic acid group is an electron-withdrawing group, which decreases the reactivity of the compound.

Q118. Addition of soluble impurities into a liquid and solid respectively causes:

  • A. Increase in boiling point of liquid and decrease in melting point of solid
  • B. Increase in both boiling and melting points
  • C. Decrease in boiling point of liquid and increase in melting point of solid
  • D. Decrease in both boiling and melting points

Explanation: Whenever a soluble, non-volatile impurity is added to a liquid, some of the solute particles tend to migrate toward the surface of the liquid, and some will remain in the bulk liquid. Due to this, an obstruction is caused by the volatile nature of the liquid. In other words, it becomes harder for the liquid molecules to vaporize due to the obstruction caused by the molecules of the added impurity. The result is that the net vapor pressure of the mixture becomes lower than that of the pure liquid, as fewer liquid molecules can go into the vapor phase. We know that the boiling point of a substance is the temperature at which the vapor pressure of the substance equals the external pressure. What happens during boiling is that we raise the temperature of the liquid, thereby raising its vapor pressure, until it becomes equal to the atmospheric pressure and starts to boil. So, when the impurity is added, vapor pressure is reduced, and thus, more heat needs to be supplied to raise it to the external pressure and make the mixture boil. Hence, the presence of soluble impurities increases the boiling point of liquids. The higher the concentration of impurity, the higher will be the elevation in boiling point. When we add impurities to the pure substance, the melting point of the solid is decreased because impurities weaken the lattice structure of solids due to which it becomes less stable and melts before its original melting point. This is called melting point depression.

Why the other options are wrong
  • B. While impurities increase the boiling point of a liquid, they actually decrease the melting point of a solid. This option is incorrect.
  • C. Impurities increase the boiling point of a liquid and decrease the melting point of a solid, contrary to what this option suggests.
  • D. Soluble impurities increase the boiling point of liquids and decrease the melting point of solids, making this option incorrect.

Q119. The elevation in boiling point ∆𝑇𝑏 is equal to ebullioscopic constant 𝐾𝑏 when the Molarity (𝑀) of the solution is:

  • A. 0.1m
  • B. 1.0m
  • C. 10.0m
  • D. Statement is wrong

Explanation: According to the formula for the elevation of boiling point∆Tb=kb×m Where kb is the ebullioscopic constant and m is the molality of the solution. ∆Tb will be equal to kb only if molality is 1.0m and it has no relation with the molarity of solution so the given statement is wrong.

Why the other options are wrong
  • A. According to the formula for the elevation of boiling point, ∆Tb = Kb × m, where m is the molality. The elevation is equal to Kb only when molality is 1.0m. Thus, 0.1m is incorrect.
  • B. This option mentions molality (1.0m) which would make ∆Tb equal to Kb, but the question incorrectly refers to molarity. Hence, it is not applicable.
  • C. With a molality of 10.0m, ∆Tb would be ten times the ebullioscopic constant, not equal to it. Therefore, this option is incorrect.

Q120. 𝑂𝐻− + 𝐶2𝐻5 − 𝐼 ⟶ 𝐶2𝐻5 − 𝑂𝐻 + 𝐼− One of the species in the above reaction is a substrate. It is:

  • A. 𝑂𝐻−
  • B. 𝐶𝐻3 − 𝐶𝐻2 − 𝑂𝐻
  • C. 𝐼−
  • D. C𝐻3 − 𝐶𝐻2 − I

Explanation: The molecule which contains the electrophile and the leaving functional group is called a substrate. It is the molecule on which nucleophiles attack to form a product.

Why the other options are wrong
  • A. OH- is a nucleophile because it donates an electron pair to form a bond with the electrophilic carbon, rather than acting as a substrate.
  • B. CH3-CH2-OH is the product formed in the reaction, not the substrate.
  • C. Iodide ion, I−, acts as a leaving group in the reaction and not as a substrate.

Q121. Cyclic alkanes with greater angle strain are always:

  • A. More stable
  • B. Less energetic
  • C. More reactive
  • D. Obey the general formula of normal alkanes

Explanation: Angle strain occurs when bond angles deviate from the ideal bond angles to achieve maximum bond strength in a specific chemical conformation. Angle strain typically affects cyclic molecules, which lack the flexibility of acyclic molecules.It occurs in cycloalkanes because the carbons in cycloalkanes are sp3 hybridized, which means that they do not have the expected ideal bond angle of 109.5°; this causes an increase in the potential energy because of the desire for the carbons to be at an ideal 109.5°. Bond angle strain causes a ring to have a poor overlap between the atoms, resulting in weak and reactive C-C bonds. An eclipsed spatial arrangement of the atoms on the cycloalkanes results in high energy and hence less stability and more reactivity.

Why the other options are wrong
  • A. No, increased angle strain leads to higher energy and instability.
  • B. Incorrect, angle strain increases potential energy, making them more energetic.
  • D. Incorrect, cyclic alkanes do not follow the general formula of normal alkanes due to their ring structure.

Q122. Students were decomposing 𝐶𝑎𝐶𝑂3 placed in a China dish by heating using burner in the laboratory. The “system” in this experiment is:

  • A. China dish
  • B. Burner
  • C. Laboratory
  • D. 𝐶𝑎𝐶𝑂3

Explanation: The system is the collective substances in the reaction such as the reactants and products. The surroundings are everything around the reaction such as the reaction flask and the room. During a reaction, energy is transferred between the system and its surroundings. The system and surrounding together make up the universe.

Why the other options are wrong
  • A. The China dish acts as a container and does not participate in the reaction. It is part of the surroundings.
  • B. The burner provides heat and is part of the surroundings that affect the system, but it is not the system itself.
  • C. The laboratory encompasses the entire environment where the experiment takes place, and it serves as the surroundings.

Q123. The process that can be both endothermic and exothermic out of the following is:

  • A. Dissolution
  • B. Crystallization
  • C. Bond breaking
  • D. Condensation

Explanation: The process of dissolving can be endothermic (temperature goes down) or exothermic (temperature goes up). When water dissolves a substance, the water molecules attract and “bond” to the particles (molecules or ions) of the substance causing the particles to separate from each other.The process of dissolving can be endothermic (temperature goes down) or exothermic (temperature goes up).Ammonium nitrate dissolving in solution is an endothermic reaction. As the ammonium nitrate dissolves, heat energy is absorbed from the environment causing the surrounding environment to feel cold. The dissolution of calcium chloride in water is an example of an exothermic reaction.

Why the other options are wrong
  • B. Crystallization is typically an exothermic process as it involves the release of energy when a substance transitions from a solution to a solid form.
  • C. Bond breaking is always an endothermic process because it requires energy input to overcome the forces holding the atoms together.
  • D. Condensation is an exothermic process as it involves the release of energy when gas molecules lose energy and transition to a liquid state.

Q124. The amine which is more reactive towards 𝐻𝐼 is:

  • A. Methyl amine
  • B. Dimethyl amine
  • C. Methyl propyl amine
  • D. Butyl amine

Explanation: The greater the basicity of amines the higher its reactivity. Order of basicity if the −R group is −CH3 group:Secondary amine > primary amine > tertiary amine > Ammonia > Aryl compounds. Dimethyl amine, a secondary amine, is the most reactive amine towards HI.

Why the other options are wrong
  • A. Methyl amine is a primary amine. While it is more reactive than ammonia, it is less reactive than secondary amines like dimethyl amine because it has fewer alkyl groups to donate electron density.
  • C. Methyl propyl amine is a primary amine. Although it has more alkyl groups than methyl amine, it is still less reactive than secondary amines like dimethyl amine.
  • D. Butyl amine is also a primary amine. Despite having a longer carbon chain, it lacks the additional alkyl group that would increase its basicity and reactivity compared to secondary amines.

Q125. The alcohol given 𝐶𝐻3 − 𝐶𝐻2 − 𝐶(𝐶𝐻3)2 −𝑂𝐻. If oxidized with a strong oxidizing agent given:

  • A. Aldehyde
  • B. Ketone
  • C. Ether
  • D. None of the above

Explanation: A tertiary alcohol can't form this carbonyl group: the tertiary custom has three single bonds to other C- atoms and one single bond to the oxygen of the hydroxyl-group. To form a carbonyl group, you need a double bond. Carbon can only form 4 bonds and the C-C- bonds are relatively stable, so it can't form the carbonyl group. With enough energy, it is possible to oxidise even tertiary alcohols, but your product will be only carbon dioxide and water (that's what you get by the complete oxidation of every alcohol).

Why the other options are wrong
  • A. Primary alcohols can be oxidized to form aldehydes. However, the structure given is not a primary alcohol.
  • B. Secondary alcohols are oxidized to ketones. The given structure is not a secondary alcohol, so this is incorrect.
  • C. Ethers are formed by dehydration of alcohols, not by oxidation. Thus, this option is incorrect.

Q126. The aqueous solution of which of the following electrolyte will conduct electric current to large extent:

  • A. 𝑀𝑔(𝑂𝐻)2
  • B. 𝐻2𝐶𝑂3
  • C. N𝐻4𝐶𝑙
  • D. N𝐻4𝑂H

Explanation: The correct answer is NH4Cl because it is a strong electrolyte that completely dissociates in water, producing a large number of ions (NH4+ and Cl-), which facilitates high electrical conductivity.Mg(OH)2 is not correct as it is sparingly soluble and does not produce a significant amount of ions in solution.H2CO3 is a weak acid that partially dissociates, offering limited conductivity.NH4OH is a weak base and also partially dissociates, thus offering lower conductivity compared to strong electrolytes.

Why the other options are wrong
  • A. Mg(OH)2 is a sparingly soluble compound and does not dissociate completely in water, resulting in limited ion production and thus lower conductivity compared to other strong electrolytes.
  • B. H2CO3 is a weak acid and only partially dissociates in water, leading to limited conductivity.
  • D. NH4OH is a weak base and does not fully dissociate in water, yielding fewer ions and reduced conductivity compared to strong electrolytes.

Q127. Read the statement and choose the option correctly.

  • A. Option A
  • B. Option B
  • C. Option C
  • D. Option D

Explanation: The general form of a rate law is: Rate =k[A]x[B]y1. Find the effect of changing [A] (Order with respect to A):Compare Experiment 1 and Experiment 2.In Experiment 1: [A]=0.1, [B]=0.1, Rate =2×10−5In Experiment 2: [A]=0.2, [B]=0.1, Rate =4×10−5Notice that [B] stays the same (0.1).When [A] doubles (from 0.1 to 0.2), the Rate also doubles (from 2×10−5 to 4×10−5).If doubling the concentration doubles the rate, the reaction is first order with respect to A. So, x=1.2. Find the effect of changing [B] (Order with respect to B):Compare Experiment 1 and Experiment 3.In Experiment 1: [A]=0.1, [B]=0.1, Rate =2×10−5In Experiment 3: [A]=0.1, [B]=0.2, Rate =4×10−5Notice that [A] stays the same (0.1).When [B] doubles (from 0.1 to 0.2), the Rate also doubles (from 2×10−5 to 4×10−5).If doubling the concentration doubles the rate, the reaction is first order with respect to B. So, y=1.3. Combine to find the Rate Law: Since x=1 and y=1, the rate law is: Rate =k[A]1[B]1 Which simplifies to: Rate =k[A][B]

Why the other options are wrong
  • B. This option suggests the reaction is second order with respect to A and first order with respect to B. Our analysis showed it's first order with respect to A. If it were second order with respect to A, doubling [A] would quadruple the rate (2^2 = 4), but the rate only doubled.
  • C. This option suggests the reaction is zero order with respect to A (meaning the rate does not depend on [A]) and second order with respect to B. Our analysis showed it's first order with respect to A and first order with respect to B. If it were zero order with respect to A, changing [A] would not change the rate, but it did. If it were second order with respect to B, doubling [B] would quadruple the rate, but it only doubled.
  • D. This option suggests the reaction is first order with respect to A and second order with respect to B. Our analysis showed it's first order with respect to A and first order with respect to B. If it were second order with respect to B, doubling [B] would quadruple the rate, but it only doubled.

Q128. The compound which you think is not the derivative of acetic acid is:

  • A. Acetyl chloride (CH3COCl)
  • B. Acetic anhydride ((CH3CO)2O)
  • C. Acetamide (CH3CONH2)
  • D. None of these

Explanation: All the listed compounds are derivatives of acetic acid based on their structural transformations.

Why the other options are wrong
  • A. Acetyl chloride is a derivative of acetic acid formed by replacing the hydroxyl (-OH) group with a chlorine atom. This transformation typically utilizes thionyl chloride (SOCl2), which facilitates the conversion of the acid into an acyl chloride.
  • B. Acetic anhydride is created by the dehydration of two acetic acid molecules, often achieved using phosphorus pentoxide (P2O5). This process removes water, resulting in a compound that retains the acetic acid structure, confirming it as a derivative.
  • C. Acetamide is synthesized from acetic acid through a reaction with ammonia (NH3). The process involves forming an ammonium salt, which is then heated to expel water and form the amide. Thus, it is classified as a derivative of acetic acid.

Q129. The reducing agent in the reaction given, 𝐾𝑀𝑛𝑂4 + 𝐾𝐼 + 𝐻2𝑆𝑂4 ⟶ 𝑀𝑛𝑆𝑂4 + 𝐾2𝑆𝑂4 +𝐼2 + 𝐻2𝑂 is:

  • A. 𝐾𝑀𝑛𝑂4
  • B. 𝐾𝐼
  • C. 𝐻2𝑆𝑂4
  • D. 𝐾𝐼 and 𝐻2𝑆𝑂4 both

Explanation: Reducing agent is the one which has the ability to give its unshared pair of electrons to other species to reduce them.

Why the other options are wrong
  • A. KMnO4 acts as an oxidizing agent because the manganese ion in KMnO4 is reduced from an oxidation state of +7 to +2 in MnSO4, facilitating the oxidation of another species.
  • C. H2SO4 is not a reducing agent in this reaction. It is used as an acidic medium to facilitate the reaction but does not undergo any change in oxidation state.
  • D. Only KI acts as the reducing agent in this reaction because it is the species that undergoes oxidation. H2SO4 is not involved in the oxidation-reduction process.

Q130. Students calculated the cell voltage for the reaction, 𝐵𝑟2 + 2𝑁𝑎𝐶𝑙 ⟶ 2𝑁𝑎𝐵𝑟 + 𝐶𝑙2 through the formula 𝐸°𝑐𝑒𝑙𝑙= 𝐸°𝑟𝑒𝑑+ 𝐸°𝑜𝑥𝑑 the answer was negative. It means that:

  • A. The reaction is non-spontaneous and feasible
  • B. The reaction is non-spontaneous and not feasible
  • C. The reaction is spontaneous and feasible
  • D. The reaction is spontaneous and not feasible

Explanation: The energy associated with the separation/transfer of charge is the property of potential, E. A cell potential's arithmetic sign determines the spontaneity of the cell reaction, with positive values indicating spontaneous and feasible reactions and zero or negative values indicating nonspontaneous and non-feasible reactions (spontaneous in the reverse direction). If the value is positive, the oxidation-reduction reaction is spontaneous. Only spontaneous reactions are feasible. That is, without the assistance of a third party. The cathode undergoes reduction, while the anode undergoes oxidation. If the value is negative, it signifies that only the opposite reaction is spontaneous. It refers to the cathode's oxidation and the anode's reduction. The change in Gibbs free energy in a galvanic cell, where a spontaneous redox reaction drives the cell to produce an electric potential, must be negative. The cell potential, which is positive when electrons flow freely through the electrochemical cell, is the polar opposite of this.

Why the other options are wrong
  • A. This option is incorrect because a negative cell potential indicates that the reaction cannot occur spontaneously under standard conditions, and thus it is not feasible without external intervention.
  • C. This option is incorrect because a negative cell potential signifies that the reaction is not spontaneous and therefore not feasible under standard conditions.
  • D. This option is incorrect because a spontaneous reaction is always feasible under the given conditions, so these two terms cannot be contradictory.

Q131. The non-carbonyl compound out of the following is:

  • A. Option A: CH3-CO-CH3
  • B. Option B: C2H5-CH(OH)-CH3
  • C. Option C: CH3-C(NH2)=O
  • D. Option D: CH3-C(OR)=O

Explanation: Carbonyl groups have a carbonyl functional group (C=O) which may be either aldehyde or ketone.

Why the other options are wrong
  • A. This compound is known as propanone or acetone, which is a ketone. Ketones are characterized by the presence of a carbonyl group (C=O) bonded to two carbon atoms.
  • C. This compound is an amide, containing a carbonyl group (C=O) bonded to a nitrogen atom. Amides are classified as carbonyl compounds.
  • D. This compound is an ester, which includes a carbonyl group (C=O) bonded to an oxygen atom. Esters are also carbonyl compounds.

Q132. The empirical formula of the compound was found to be 𝐶𝐻2𝑂. If the molar mass of the compound is 150𝑔/𝑚𝑜𝑙. The molecular formula of the compound is:

  • A. C6H12O6
  • B. C4H8O2
  • C. C5H10O4
  • D. C5H10O5

Explanation: The molecular formula is given byMolecular formula = n x empirical formulaWhere n= molecular formula mass/empirical formula massThe empirical formula mass of CH2O is =12+2+16=30g/mol.n = 150/30=5. So Molecular formula is Molecular formula = 5×CH2O = C5H10O5

Why the other options are wrong
  • A. This option assumes a different scaling factor, which doesn't match the given molar mass of 150 g/mol. The scaling factor based on the molar mass should be 5, not 6.
  • B. This molecular formula results from an incorrect scaling factor of 4. The calculation should yield a scaling factor of 5 based on the molar mass.
  • C. This option is incorrect because the scaling factor should be applied equally to all elements in the empirical formula, resulting in an incorrect formula.

Q133. The volume of 𝐶𝑂2 produced by heating 33.5𝑔 𝐿𝑖2𝐶𝑂3 at room temperature and pressure is (𝑀𝑟 𝐿𝑖2𝐶𝑂3 = 67𝑔/𝑚𝑜𝑙):

  • A. 22.4 𝑑𝑚3
  • B. 12.0 𝑑𝑚3
  • C. 11.2 𝑑𝑚3
  • D. 24.0 𝑑𝑚3

Explanation: moles of Li2CO3= mass/Mr =33.5/67 = 0.5 Moles of CO2: moles of Li2CO3 1 : 1Hence moles of CO2 =0.5 0.5 × 24= 12dm3 Molar volume at ROOM temperature and pressure is 12 dm³ while molar volume at STANDARD temperature and pressure is 22.4 dm³.

Why the other options are wrong
  • A. This option assumes the use of standard temperature and pressure (STP) conditions, where the molar volume is 22.4 dm³. However, the problem specifies room temperature and pressure, where the molar volume is 24 dm³.
  • C. This option incorrectly assumes a molar volume different from room temperature conditions or an incorrect mole calculation.
  • D. This option assumes that 1 mole of CO2 is produced, but only 0.5 moles of Li2CO3 are heated, producing only 0.5 moles of CO2.

Q134. The equation used to describe the behavior of ideal gases under standard conditions is:

  • A. P𝑉 = 𝑛𝑅T
  • B. 𝑃𝑀 = 𝑑𝑅T
  • C. 𝑃𝑉𝑀 = 𝑚𝑅T
  • D. All of the above

Explanation: The correct equation to describe the behavior of ideal gases under standard conditions is PV = nRT. This equation is fundamental in chemistry and physics, relating the pressure (P), volume (V), temperature (T), and moles of gas (n) with the universal gas constant (R). The other options represent derived forms of the ideal gas equation under specific conditions, such as when considering density (Option B) or involving mass (Option C), but they are not the primary form of the ideal gas law.

Why the other options are wrong
  • B. This equation is derived from the ideal gas law when considering the density of a gas. It expresses the pressure in terms of density, molar mass, and temperature, but it is not the basic form of the ideal gas law.
  • C. This form is another derivation involving the mass of the gas, molar mass, and volume, but it is not the standard ideal gas law equation.
  • D. This option is incorrect because not all the equations are correct forms of the ideal gas law under standard conditions.

Q135. The nuclei you think is invisible in NMR spectroscopy is:

  • A. N14
  • B. P31
  • C. Cl35
  • D. C13

Explanation: NMR spectroscopy requires nuclei with non-zero spin to be detected. Cl³⁵ has a quadrupolar nucleus with spin 3/2 and often gives broad, weak, or undetectable signals, making it practically "invisible" in routine NMR. Nuclei like C¹³, H¹, N¹⁴, and P³¹ are commonly detectable.

Why the other options are wrong
  • B. P31 has a non-zero nuclear spin and is commonly used in NMR spectroscopy to study phosphorus-containing compounds due to its sensitivity.
  • C. Cl35 has a non-zero nuclear spin and can be observed in NMR, although the signals are often broad due to quadrupole interactions.
  • D. C13 is NMR-active with a 1/2 spin, making it a valuable isotope for studying carbon-containing compounds in NMR spectroscopy.

Q136. The amount of methane in biogas is approximately:

  • A. 10-30%
  • B. 50-90%
  • C. 50-75%
  • D. 60-75%

Explanation: Biogas is predominantly composed of methane (CH4) and carbon dioxide (CO2). The methane content typically ranges from 50% to 75% by volume. Option C accurately reflects this range. Option A suggests a much lower methane content than is typical, Option B overestimates the possible upper limit, and Option D does not encompass the full typical range, omitting the lower end.

Why the other options are wrong
  • A. This option is incorrect. Methane content in biogas is generally higher than 30%.
  • B. This option is incorrect. Although methane can be a major component, the upper limit is generally around 75%.
  • D. This option is incorrect. While this range is partially accurate, it does not account for the lower end of the typical range.

Q137. By the absorption of visible light, which of the following compounds gives smogy air and has brown tint?

  • A. NO
  • B. 𝑆𝑂3
  • C. 𝑁𝑂−3
  • D. 𝑁𝑂2

Explanation: Nitrogen dioxide absorbs radiation in the ultraviolet (UV) and visible (vis) regions due to the electron transitions within the nitrogen dioxide molecule. It is a pungent gas that, along with fine airborne particulate matter, contributes to the reddish-brown haze characteristic of smoggy air.

Why the other options are wrong
  • A. Nitric oxide (NO) is a colorless gas that reacts with oxygen to form nitrogen dioxide (NO2), which contributes to smog but does not itself have a brown tint.
  • B. Sulfur trioxide (SO3) is a colorless gas that does not absorb visible light to create a brown tint. It contributes to acid rain when it reacts with water.
  • C. Nitrate ions (NO3-) are not gaseous and do not absorb visible light. They are typically found in particulate form and are a result of various chemical reactions in the atmosphere.

Q138. Regarding reactivity of the compounds having carbonyl group. The most reactive compound out of the following is:

  • A. CH3CH2COCH3
  • B. C2H5COOH
  • C. CH3COH
  • D. CH3COOH

Explanation: Compound C is the most reactive because it has a simple carbonyl group with minimal electron donating influence, enhancing its electrophilic nature.

Why the other options are wrong
  • A. Compound A contains two electron-donating alkyl groups, which reduce the electrophilic character of the carbonyl carbon. This makes it less reactive compared to other compounds with less electron donation.
  • B. Compound B is a carboxylic acid, which features resonance stabilization. The electron donation from the hydroxyl group decreases the reactivity of the carbonyl carbon compared to simple carbonyl compounds.
  • D. Like Compound B, Compound D is a carboxylic acid. The resonance stabilization and electron-donating nature of the carboxyl group lowers its reactivity compared to compounds with simple carbonyl groups.

Q139. Whenever nitrile group is hydrolysed (𝑑𝑖𝑙 𝐻𝐶𝑙) with water it always produces:

  • A. Alcohol
  • B. Carboxylic acid
  • C. Amines
  • D. Amides

Explanation: Nitrile gets hydrolyzed in two steps; amides are formed first. While in the second step, an ammonium salt of a carboxylic acid is formed. For example, Ethanenitrile on getting hydrolyzed gives ethanamide in the first step, while ammonium ethanoate in the second step.

Why the other options are wrong
  • A. This option is incorrect. Hydrolysis of nitriles does not produce alcohols. Alcohols are typically formed from the reduction of carboxylic acids or esters, not from nitriles.
  • C. This option is incorrect. Amines are typically formed through the reduction of nitriles, not by hydrolysis.
  • D. This option is partially correct but incomplete. Amides are indeed an intermediate product in the hydrolysis of nitriles, but further hydrolysis leads to the formation of carboxylic acids.

Q140. Elements of which block of the periodic table shows variable oxidation state?

  • A. The s-block elements
  • B. The p-block elements
  • C. The d and f block elements
  • D. None of the blocks

Explanation: In the case of d-block elements due to the presence of electrons at d orbitals, is closer to the outermost shell of the metal. They show variable oxidation states. With increasing the number of electrons of the d orbitals (up to 5 electrons), the number of oxidation states increases. In the case of d electrons due to a lower effective nuclear charge of attraction, the electrons can be removed to form different oxidation states.Actinides are F-block elements(atomic number 89 to103) with the general electronic configuration of the outermost shell being [Rn]5f1,146d0,17s2. Where the last electron enters the inner 5f-orbital of the actinides. Actinides are also known as rare earth metals. Now according to the Aufbau principle(L+S value), the energy order of the orbitals should be 5f<6d<7s but due to the more diffuse orbitals, their energy becomes more or less the same. As a result, electrons can be excited easily. Due to this reason, actinides show a greater range of oxidation states. But if we consider lanthanides due to their comparatively small size of 4f orbital they have a limited number of oxidation states.

Why the other options are wrong
  • A. The s-block elements typically exhibit a fixed oxidation state of +1 or +2 due to their valence shell configurations, which do not allow for variability.
  • B. While p-block elements can show a variety of oxidation states, this variability is not as common or extensive as in the d- and f-block elements.
  • D. This is incorrect because both d and f block elements are known for their variable oxidation states due to their electron configurations.

Q141. What is the strain energy per unit volume of a rod made from this metal when the strain of the rod is 0.010?

  • A. 10 kJ m−3
  • B. 100 kJ m−3
  • C. 1.0 MJ m−3
  • D. 10 MJ m−3

Explanation: To calculate the strain energy per unit volume (also known as strain energy density), you use the formula: strain energy per unit volume = (1/2) × stress × strain.Given that the strain is 0.010, and assuming the stress is calculated using Young's modulus of the material (for example, 2 × 109 Pa), the calculation would be:strain energy per unit volume = (1/2) × (2 × 109 Pa) × 0.010 = 10 × 106 J m−3 = 10 MJ m−3Thus, the correct answer is 10 MJ m−3. All other options are incorrect because they either underestimate or overestimate the strain energy density based on improper calculations or incorrect assumptions.

Why the other options are wrong
  • A. This value is incorrect because it is orders of magnitude lower than the calculated strain energy density, which is in MJ m−3.
  • B. This option is incorrect as it underestimates the strain energy density by a factor of 100. The correct calculation should be in MJ m−3.
  • C. This option is incorrect because the calculated strain energy density is 10 times higher. Double-check your calculation of stress and the use of the formula.

Q142. A diffraction grating is used to measure the wavelength of monochromatic light, as shown in the diagram. The spacing of the slits in the grating is 1.00 × 10−6m. The angle between the first-order diffraction maxima is 60.0°. What is the wavelength of the light?

  • A. 287 nm
  • B. 470 nm
  • C. 574 nm
  • D. 940 nm

Explanation: The explanation is given below:

Why the other options are wrong
  • A. This option is incorrect. It assumes an incorrect calculation of the sine function or misapplies the diffraction formula.
  • B. This option is incorrect. It might result from using an incorrect angle or misplacing the diffraction order in the formula.
  • D. This option is incorrect. It could result from a miscalculation of the order of maxima or an incorrect application of the formula.

Q143. A filament lamp has a resistance of 180 Ω when the current in it is 500mA. What is the power dissipated in the lamp?

  • A. 45 W
  • B. 90 W
  • C. 290 W
  • D. 360 W

Explanation: The power dissipated in an electrical component can be calculated using the formula P = I2R, where P is the power, I is the current, and R is the resistance. Given that the current (I) is 500 mA (or 0.5 A) and the resistance (R) is 180 Ω, we can calculate the power as follows: P = (0.5)2 × 180 = 0.25 × 180 = 45 W Therefore, the correct answer is 45 W. Other options are incorrect as they result from either using wrong calculation methods or misinterpretation of the question.

Why the other options are wrong
  • B. This option is incorrect. Using the formula P = I2R and substituting the given values results in a power of 45 W, not 90 W.
  • C. This option is incorrect. The calculation using P = I2R yields 45 W, which is significantly lower than 290 W.
  • D. This option is incorrect. The correct calculation with the given values results in 45 W, not 360 W.

Q144. Orange light in a vacuum has a wavelength of 600 nm. What is the frequency of this light?

  • A. 180 Hz
  • B. 5.0 × 105 Hz
  • C. 1.8 × 1011 Hz
  • D. 5.0 × 1014 Hz

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option is incorrect. The frequency is too low for visible light, which typically falls in the range of 1014 Hz.
  • B. This option is incorrect. Such a low frequency is typical for radio waves, not visible light.
  • C. This option is incorrect. This frequency is much lower than expected for visible light, which is in the terahertz range.

Q145. A stationary sound wave has a series of nodes. The distance between the first and the sixth node is 30.0 cm. What is the wavelength of the sound wave?

  • A. 5.0 cm
  • B. 6.0 cm
  • C. 10.0 cm
  • D. 12.0 cm

Explanation: The following is the solution:

Why the other options are wrong
  • A. Incorrect. Remember to consider the number of nodes and their distances.
  • B. Incorrect. Make sure to apply the correct formula for calculating wavelength.
  • C. Incorrect. Take into account the relationship between nodes and wavelength.

Q146. In Simple Harmonic Motion the acceleration of the particle is zero when its:

  • A. Velocity is zero
  • B. Displacement is zero
  • C. Both velocity and displacement are zero
  • D. Both velocity and displacement are maximum

Explanation: As we know; a ∝-x Where a=acceleration x=displacement As long as the pendulum in harmonic motion is moving, it covers a displacement and thus has an acceleration. But as soon as it stops and comes to rest, the velocity and change in velocity are zero thus the acceleration is also zero and the displacement covered by it is also zero. Acceleration depends upon the change in velocity, if either final or initial velocity is zero it doesn't mean that acceleration is zero.The velocity is maximum at the mean position and displacement is maximum at the extreme so this option can't be justified to be correct.

Why the other options are wrong
  • A. In SHM, the acceleration is directly proportional to the displacement and is in the opposite direction. At the extremum positions, where the displacement is maximum, the acceleration is also maximum. The velocity, on the other hand, is zero at the extremum positions.
  • C. In SHM, the acceleration is directly proportional to the displacement and is in the opposite direction. At the extremum positions, where the displacement is maximum, the acceleration is also maximum. The velocity, on the other hand, is zero at the extremum positions.
  • D. In SHM, the acceleration is directly proportional to the displacement and is in the opposite direction. At the extremum positions, where the displacement is maximum, the acceleration is also maximum. The velocity, on the other hand, is zero at the extremum positions.

Q147. A typical mobile phone battery has an e.m.f. of 5.0 V and an internal resistance of 200 mΩ.What is the terminal P.D. of the battery when it supplies a current of 500 mA?

  • A. 4.8 V
  • B. 4.9 V
  • C. 5.0 V
  • D. 5.1 V

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option is incorrect. It assumes a greater voltage drop across the internal resistance than what actually occurs.
  • C. This option is incorrect. It represents the e.m.f. of the battery, not accounting for the voltage drop due to internal resistance.
  • D. This option is incorrect. It suggests an increase in voltage, which is not possible when considering the internal resistance causes a voltage drop.

Q148. Which combination of up (u) and down (d) quarks forms a neutron?

  • A. u u u
  • B. u u d
  • C. u d d
  • D. d d

Explanation: Quarks are fundamental and elementary particles, there are six flavors of quarks =up, down, top, bottom, charm, and strange.Down, bottom, and strange are the antiparticles of up, top, and charm respectively.Three of these are combined to make any particle such as the proton, neutron, etc.A neutron consists of two down quarks and one up quark.A proton consists of two up quarks and one down quark.Both protons and neutrons are baryons. Baryons are heavy subatomic particles made up of three quarks.

Why the other options are wrong
  • A. All up quarks would not allow for a neutral charge, which is required for a neutron. Instead, this combination doesn't form a neutron.
  • B. This combination forms a proton, not a neutron. A proton is composed of two up quarks and one down quark.
  • D. This combination is incomplete and cannot form a neutron, as a neutron requires three quarks in total.

Q149. How many cubic nanometres, nm3, are in a cubic micrometer, μm3?

  • A. 103
  • B. 106
  • C. 109
  • D. 1012

Explanation: The following is the solution:

Why the other options are wrong
  • A. This would be the conversion factor for linear nanometers to micrometers, not cubic.
  • B. This is the square of the linear conversion factor, not cubic.
  • D. This would be the conversion factor if we were considering the volume in terms of picometers, not nanometers.

Q150. A man stands in a lift that is accelerating vertically downwards. Which statement describes the force exerted by the man on the floor?

  • A. It is equal to the weight of the man.
  • B. It is greater than the force exerted by the floor on the man.
  • C. It is less than the force exerted by the floor on the man.
  • D. It is less than the weight of the man.

Explanation: As the lift is accelerating vertically downward so (g-a). The apparent weight of a man would become less than the actual weight. F=W-Rma=mg-RR=mg-maR= m(g-a)If the lift would be moving upward then (g+a), both g and acceleration would be parallel F=R-Wma=R-mgma+mg=RR=m(a+g)In the case of acceleration, the weight and the exerted force can't be equal. The weight of man and exerted force will be equal if the lift is at rest or moving with constant speed. The floor would apply a force on a man equal to the weight of a man.

Why the other options are wrong
  • A. This option is incorrect as the force exerted by the man is affected by the lift's acceleration.
  • B. This option is incorrect as the force exerted by the man is not greater than the force exerted by the floor in this scenario.
  • C. This option is incorrect as the force exerted by the man is not less than the force exerted by the floor in this scenario.

Q151. The efficiency of a heat engine working between the freezing point and the boiling point of water is near to:

  • A. 50%
  • B. 25%
  • C. 12.5%
  • D. 6.25%

Explanation: Boiling point of water= 100° =373K Freezing point of water=0° = 273K The formula for efficiency; =1-TCold/Thotx100 = 1- 273/373x100 =26.80% ≈25% NOTE: make sure the temperature values being used in the formula are in Kelvin. In the numerator, we always take the cold body's temperature. In the denominator, we always take the hot body's temperature.

Why the other options are wrong
  • A. This option is incorrect.
  • C. This option is incorrect.
  • D. This option is incorrect.

Q152. Two railway trucks of masses m and 3m move towards each other in opposite directions with speeds 2v and v respectively. These trucks collide and stick together. What is the speed of the trucks after the collision?

  • A. v/4
  • B. v/2
  • C. v
  • D. 5v/4

Explanation: This problem involves an inelastic collision where two railway trucks stick together after colliding. The principle of conservation of momentum is used to solve for the final speed of the combined mass. Initially, the momentum of the system is calculated by considering the direction and magnitude of each truck's momentum:The momentum of the truck with mass 'm' moving at '2v' is 2mv, while the truck with mass '3m' moving at '-v' (opposite direction) has a momentum of -3mv. The total initial momentum therefore is 2mv - 3mv = -mv.After the collision, the trucks stick together, forming a combined mass of 4m. Let the final velocity of this combined mass be 'v_final'. According to conservation of momentum, the total momentum before the collision equals the total momentum after the collision:-mv = 4m × v_finalSolving for v_final gives v_final = -v/4. The negative sign indicates the direction is opposite to the initial direction of the truck with mass 'm', and the magnitude of the speed is v/4.Incorrect options:v/2: This assumes a different distribution of momentum that does not align with the conservation principle.v: This implies no change in velocity, which contradicts the nature of inelastic collisions.5v/4: This results from a miscalculation of momentum distribution, leading to an incorrect final speed.

Why the other options are wrong
  • B. This option assumes an incorrect calculation of the combined system's speed, leading to an incorrect final velocity.
  • C. This option incorrectly suggests no change in velocity, which is not possible in an inelastic collision where the objects stick together.
  • D. This option misapplies the conservation of momentum, resulting in an incorrect calculation of the final speed.

Q153. A thin horizontal plate of area 0.036 m2 is beneath the surface of a liquid of density 930 kg m−3. The force on one side of the plate due to the pressure of the liquid is 290 N. What is the depth of the plate beneath the surface of the liquid?

  • A. 0.88 m
  • B. 1.1 m
  • C. 1.8 m
  • D. 8.7 m

Explanation: Pressure P = hρgwhere h is the depth, ρ is the density of the liquid and g is the acceleration of free fall.But,Pressure P = Force / Area = F / ATherefore,Depth h = P / ρg = F / (Aρg) = 290 / [0.036 (930) (9.81)] = 0.88m

Why the other options are wrong
  • B. This depth is incorrect. It results from miscalculating the formula or substituting incorrect values in the equation.
  • C. This depth is too large. It indicates an error in using the formula or misapplying the values given for force, area, or density.
  • D. This depth is excessively large, showing a significant miscalculation in the use of the formula or values.

Q154. An electron and a proton enter a magnetic field with equal velocities which one of them experiences more force:

  • A. Electron
  • B. Proton
  • C. Both experience same force
  • D. Cannot be predicted

Explanation: F=q(V×B) F=qvBsin The formula infers that F∝v As both proton and electron have the same velocity they will experience the same value of force. As both have opposite charges, therefore the force being applied would be the same in magnitude but opposite in direction. In simple words both particles are deflected with the same force but in the direction opposite to each other.

Why the other options are wrong
  • A. As both proton and electron have the same velocity they will experience the same value of force.
  • B. As both proton and electron have the same velocity they will experience the same value of force.
  • D. As both proton and electron have the same velocity they will experience the same value of force.

Q155. An electromagnetic wave travels in a straight line through a vacuum. The wave has a frequency of 6.0 THz. What is the number of wavelengths in a distance of 1.0 m along the wave?

  • A. 5.0 × 10–5
  • B. 2.0 × 101
  • C. 2.0 × 104
  • D. 5.0 × 107

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option is incorrect. It appears to be a misunderstanding of the relationship between frequency and wavelength.
  • B. This option is incorrect. It results from an error in calculating the number of wavelengths over the given distance.
  • D. This option is incorrect. It reflects a significant overestimation of the number of wavelengths.

Q156. What is the magnitude of a point charge which produces an electric field of 2 N/C at a distance of 60 cm?

  • A. 8 × 10−11C
  • B. 2 × 10−12C
  • C. 3 × 10−11C
  • D. 6 × 10−10C

Explanation: The electric field (E) due to a point charge (q) at a distance (r) is given by the formula E = k * |q| / r2, where k is the electrostatic constant (approximately 8.99 × 109 N m2/C2). Here, E = 2 N/C and r = 60 cm = 0.6 m. Rearranging the formula to solve for |q|, we have |q| = E * r2 / k. Substituting the values, |q| = (2 N/C) * (0.6 m)2 / (8.99 × 109 N m2/C2) = 8 × 10−11C. Therefore, the correct answer is 8 × 10−11C. The other options fail to provide the correct magnitude as they either miscalculate or misinterpret the formula and given values.

Why the other options are wrong
  • B. This option incorrectly suggests the magnitude of the charge as 2 × 10−12C. Recalculate using the formula to see the correct result.
  • C. This option incorrectly suggests the magnitude of the charge as 3 × 10−11C. The correct calculation yields a different result.
  • D. This option overestimates the charge magnitude as 6 × 10−10C. Follow the correct formula to find the accurate value.

Q157. The speed v of a liquid leaving a tube depends on the change in pressure ΔP and the density ρ of the liquid. The speed is given by the equation. where k is a constant that has no units. What is the value of n?

  • A. 1/2
  • B. 1
  • C. 3/2
  • D. 2

Explanation: Explanation is given in image.

Why the other options are wrong
  • B. This option is incorrect because it assumes a direct proportionality, which is not consistent with Bernoulli's equation where the speed is proportional to the square root of the pressure change divided by density.
  • C. This option is incorrect as it overestimates the relationship between speed and the physical parameters. The speed does not increase at this rate according to Bernoulli's principle.
  • D. This option is incorrect because it suggests a quadratic relationship, which is not supported by the principles of fluid dynamics where speed is proportional to the square root of the pressure change divided by density.

Q158. A uniform horizontal footbridge is 12 m long and weighs 4000 N. It rests on two supports X and Y as shown. A man of weight 600 N is at a distance of 4 m from support X. What is the upward force on the footbridge from support X?

  • A. 2200 N
  • B. 2300 N
  • C. 2400 N
  • D. 2600 N

Explanation: As the total length of the bridge is 12m and a man of 600N weight is standing at a distance of 4 m from X. The torque acting at a 4m distance is τ1 =12F Nm. The distance of Y from the center of the bridge is 6m. The weight of the bridge acting from its center is 4000N.So, the torque acting at a 6m distance is 6(4000).=24000Nm Since the weight of the bridge is acting downward and the torque is clockwise and negative so τ2 = -24000NmThe distance of man from Y is 8m.So the torque acting at 8m distance is 8(600)= 4800NmSince the force due to man is acting downward and torque is clockwise and negative so τ3 =-4800 NmApplying 2nd condition of equilibrium;∑τ = 0τ1 + τ2 + τ3 =012F -24000 - 4800 =012F = 24000 + 480012 F = 28800F = 28800/12F = 2400N

Why the other options are wrong
  • A. This calculation underestimates the force. Check the distances and torques involved.
  • B. This is close but incorrect. Review the equilibrium conditions and ensure all forces are accounted for.
  • D. This overestimates the force. Double-check the distances used in your torque calculations.

Q159. A diameter 'd' and length 'l' wire hangs vertically from a fixed point. The wire is extended by hanging a mass 'M' on its end. The Young modulus of the wire is 'E'. The acceleration of free fall is 'g'. Which equation is used to determine the extension 'x' of the wire?

  • A. Option A
  • B. Option B
  • C. Option C
  • D. Option D

Explanation: Use the formula given:𝑥 =4𝑀𝑔𝑙 / 𝐸𝜋𝑑2

Why the other options are wrong
  • A. This option uses an incorrect factor and does not correctly apply the formula for extension using Young's Modulus.𝑥 = 2𝑀𝑔𝑙 / 𝐸𝜋𝑑2
  • B. This option incorrectly assumes a different proportionality constant and does not match the standard formula used in elasticity.𝑥 = 𝑀𝑔𝑙 / 2𝐸𝜋𝑑2
  • C. This option uses an incorrect formula structure that does not consider the correct relationship between the variables.𝑥 = 2𝑀𝑔𝑙 / 𝐸𝜋𝑑3

Q160. A sound wave has a frequency of 2500 Hz and a speed of 1500 m s−1. What is the shortest distance from a point of maximum pressure in the wave to a point of minimum pressure?

  • A. 0.15 m
  • B. 0.30 m
  • C. 0.60 m
  • D. 1.20 m

Explanation: Frequency=2500 hzWave speed=1500m/sNow wave speed = wave length*FrequencySo wavelength=Wave speed/FrequencyWavelength=1500/2500 =3/5 =0.6 mA sound wave is also known as a pressure wave. The wavelength can be said to be the distance between 2 consecutive maximum pressure points or the distance between 2 consecutive minimum pressure points.In the middle of 2 consecutive maximum pressure points, there is a minimum pressure point.So the wavelength between the point of maximum pressure in the wave to the point of minimum pressure is=0.6/2=0.3m. Hence the shortest distance between the point of maximum pressure in the wave to the point of minimum pressure is 0.3m.

Why the other options are wrong
  • A. This is incorrect. This value does not align with the calculated wavelength and the principles of wave motion.
  • C. Incorrect. 0.6 m represents the full wavelength, which is the distance between two consecutive maximum pressure points, not the shortest distance to a minimum pressure point.
  • D. Incorrect. This value is twice the wavelength, which doesn't apply to the distance from maximum to minimum pressure points within a single cycle.

Q161. The instantaneous current in a circuit is given by I = √2 sin(ωt + ∅) ampere what is the rms value of the current?

  • A. 2 A
  • B. √2 A
  • C. 1 A
  • D. (1/√2)A

Explanation: The RMS (Root Mean Square) value of a sinusoidal alternating current is given by dividing the peak current by √2. For the given current I = √2 sin(ωt + ∅) A, the peak current I0 is √2 A. Thus, the RMS current is IRMS = I0/√2 = √2/√2 = 1 A. Therefore, the correct answer is 1 A. The other options are incorrect because they either represent the peak current or a miscalculated RMS value.

Why the other options are wrong
  • A. This option is incorrect. The RMS value is not directly equal to the peak value of the current.
  • B. This option is incorrect. The value given is the peak current, not the RMS current.
  • D. This option is incorrect. This value would represent the RMS of a peak current of 1 A, not √2 A.

Q162. Which list shows electromagnetic waves in order of increasing frequency?

  • A. Radio waves → gamma rays → ultraviolet → infra-red
  • B. Radio waves → infra-red → ultraviolet → gamma rays
  • C. Ultraviolet → gamma rays → radio waves → infra-red
  • D. Ultraviolet → infra-red → radio waves → gamma rays

Explanation: Electromagnetic waves don't require a medium to travel. They are 7 types, each of them having the same kind of vibrations but different frequencies and wavelengths and hence energies. Cosmic waves are not electromagnetic waves.

Why the other options are wrong
  • A. This order is incorrect because gamma rays have a much higher frequency than ultraviolet and infra-red.
  • C. This order is incorrect because radio waves have the lowest frequency, not higher than gamma rays and ultraviolet.
  • D. This order is incorrect because infra-red and radio waves have lower frequencies than ultraviolet and gamma rays.

Q163. What is the momentum of X −rays having wavelength 0.001nm?

  • A. 6.63 × 10−22 kg m s−1
  • B. 6.63 × 10−27 kg m s−1
  • C. 6.63 × 10−31 kg m s−1
  • D. 6.63 × 10−34 kg m s−1

Explanation: We know that,λ= h / pp=6.26×10 −22 kgm/s

Why the other options are wrong
  • B. This value is incorrect. It might result from a miscalculation or incorrect understanding of the conversion between nanometers and meters. Ensure you convert the wavelength correctly and use the right formula.
  • C. This value is too small. It could arise from misunderstanding the relationship between wavelength and momentum. Remember that a smaller wavelength corresponds to a larger momentum.
  • D. This value is Planck's constant itself, not the momentum. The momentum calculation should use Planck's constant divided by the wavelength, not the constant alone.

Q164. The maximum energy of the electrons released in photocell is independent of:

  • A. Frequency of incident light
  • B. Intensity of incident light
  • C. Nature of cathode surface
  • D. Wavelength of light

Explanation: The working of a photocell can be explained by the photoelectric effect.•The photoelectrons which are released when a beam of light falls on the cathode are independent of the intensity of light. •It does depend upon the frequency of incident light, the effect will only be observed if the incident light has the frequency of a specific value known as threshold frequency.•And should have a specific wavelength known as cutoff wavelength.• As long as the incident wave doesn't have the frequency and wavelength equal or greater than the required values no effect will be observed.• Different metals have different values of threshold frequencies so the nature of the cathode is also taken into consideration. •consider the following equationK.Emax= hv-work functionThis shows that the max kinetic energy of electrons depends upon frequency, wavelength, and work function and work function depends upon the nature of the metal being used as a cathode.So it's independent of the intensity of light.

Why the other options are wrong
  • A. The maximum energy of the electrons released in the photocell is directly proportional to the frequency of the incident light. Higher frequencies result in higher energy electrons.
  • C. The maximum energy of the electrons released in the photocell depends on the work function of the cathode material, which varies with different cathode surfaces.
  • D. The maximum energy of the electrons is influenced by the wavelength of light since wavelength and frequency are inversely related. Lower wavelength (higher frequency) means higher energy electrons.

Q165. A mass m is suspended from a spring of spring constant k. The angular frequency of oscillations of the spring is:

  • A. k/m
  • B. √[k/m]
  • C. m/k
  • D. √[m/k]

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option incorrectly implies that the angular frequency (ω) is directly proportional to the spring constant divided by the mass. The correct relationship is that ω is proportional to the square root of the ratio of k to m. Therefore, option A is incorrect.
  • C. This option suggests that the angular frequency (ω) is inversely proportional to the mass divided by the spring constant. This is incorrect because the frequency is actually determined by the square root of the spring constant to mass ratio. Therefore, option C is incorrect.
  • D. This option incorrectly states that the angular frequency (ω) is the square root of the mass (m) divided by the spring constant (k). The correct formula is the square root of the spring constant to mass ratio, making option D incorrect.

Q166. Which expression using SI base units is equivalent to the volt?

  • A. kg m2s−1A−1
  • B. kg m s−2 A
  • C. kg m2s−1A
  • D. kg m2s−3A−1

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option is incorrect. It represents the unit for momentum per current, which doesn't relate to voltage.
  • B. This option is incorrect. It resembles the unit for force times current, not voltage.
  • C. This option is incorrect. It is related to power times current, which doesn't correspond to voltage.

Q167. On a planet, a vertically-launched projectile takes 12.5 s to return to its starting position. The projectile gains a maximum height of 170 m. The planet does not have an atmosphere. What is the acceleration of free fall on this planet?

  • A. 2.2 m s−2
  • B. 8.7 m s−2
  • C. 27 m s−2
  • D. 54 m s−2

Explanation: Explanation is given below:

Why the other options are wrong
  • A. This value is too low. Re-evaluate using the time of flight and maximum height.
  • C. This value is too high. Check the calculations and consider the symmetry of the motion.
  • D. This is incorrect. This value is not consistent with the given time and height.

Q168. The ionization potential of a hydrogen atom is 13.6V what will be the energy of the electron in the second orbit?

  • A. −10.2 eV
  • B. −3.40 eV
  • C. +3.40 eV
  • D. −1.51 eV

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option is incorrect. This value does not correspond to the energy of an electron in the second orbit of a hydrogen atom.
  • C. This option is incorrect. Energy levels for bound electrons are negative, indicating that energy must be added to free the electron.
  • D. This option is incorrect. This value corresponds to a higher orbit, not the second orbit of a hydrogen atom.

Q169. A man has a mass of 80 kg. He ties himself to one end of a rope which passes over a single fixed pulley. He pulls on the other end of the rope to lift himself up at an average speed of 50 cm s−1. What is the average useful power at which he is working?

  • A. 40 W
  • B. 0.39 kW
  • C. 4.0 kW
  • D. 39 kW

Explanation: Explanation is given in image.

Why the other options are wrong
  • A. This option is incorrect. It underestimates the power required to lift the man.
  • C. This option is incorrect. It overestimates the power required to lift the man.
  • D. This option is incorrect. It significantly overestimates the power needed.

Q170. A transverse wave travels along a rope. The graph shows the variation of the displacement of the particles in the rope with distance along it at a particular instant. At which distance along the rope do the particles have maximum upwards velocity?

  • A. 0.5 m
  • B. 1.0 m
  • C. 1.5 m
  • D. 2.0 m

Explanation: Since the wave is moving to the right, we can draw the position of the wave at the next instant by simply replicating the wave, but shifted to the right.In this way, we can know how each point has moved in the next instant. It can be seen that particles at both 0.5 m and 1.0 m will move upward at the next instant but the largest upward change in displacement occurs at a distance of 0.5 m.

Why the other options are wrong
  • B. At 1.0 m, the slope is less steep compared to 0.5 m, resulting in a lower upward velocity.
  • C. This point is on a downward slope, indicating a downward velocity rather than an upward one.
  • D. At 2.0 m, the slope is also downward, which means particles are moving downwards.

Q171. Which of the following will be a better shield against 𝛾-rays?

  • A. Ordinary water
  • B. Heavy water
  • C. Lead
  • D. Aluminum

Explanation: Gamma rays are known to have maximum penetration they can penetrate several metals. The best shielding against them is elements with high atomic numbers and high density, such as lead. The atomic number of Lead is 82.Gamma rays travel at the speed of light, and they can travel thousands of meters in the air before spending their energy. They can be shielded by water but a huge amount would be required: 13.8 feet of water, about 6.6 feet of concrete, or about 1.3 feet of Lead is required to shield against gamma rays. Aluminium is less dense and gamma rays can penetrate through them completely.

Why the other options are wrong
  • A. This option is incorrect. While water can attenuate gamma rays, a very large thickness is required to provide effective shielding.
  • B. This option is incorrect. Although heavy water has a slightly higher density than ordinary water, it is still not as effective as lead in shielding gamma rays.
  • D. This option is incorrect. Aluminum has a lower density compared to Lead, making it less effective in shielding against gamma rays.

Q172. In a uniform electric field, which statement is correct?

  • A. All charged particles experience the same force
  • B. All charged particles move with the same velocity
  • C. All electric field lines are directed towards positive charges
  • D. All electric field lines are parallel

Explanation: In case of the uniform electric field, the two electric field lines are1. straight2. parallel3. equidistantA uniform electric field is a field in which the value of the field strength remains the same

Why the other options are wrong
  • A. In a uniform electric field, the force experienced by a charged particle depends on the charge of the particle (q) and the electric field strength (E). The force (F) is calculated using F = qE, meaning particles with different charges experience different forces. Thus, this option is incorrect.
  • B. Charged particles in a uniform electric field experience acceleration proportional to their charge-to-mass ratio (q/m), but this does not guarantee the same velocity. Initial velocity, exposure time, and other forces affect their actual velocities. Therefore, this option is incorrect.
  • C. Electric field lines originate from positive charges and terminate at negative charges. In a uniform field, lines are straight and parallel, not necessarily directed towards positive charges. Therefore, this option is incorrect.

Q173. A metal cube with sides of length “𝑎” has electrical resistance 𝑅 between opposite faces. What is the resistance between the opposite faces of a cube of the same metal with sides of length 3𝑎?

  • A. 9𝑅
  • B. 3𝑅
  • C. R/3
  • D. 𝑅/9

Explanation: the resistance can be found by the relation R=pL/A p(resistivity) In this case L=a and A=a2 soR=p 1/aWhen L=3a then A=9a2So R=p 1/3a Hence 1/3 times

Why the other options are wrong
  • A. This would be the resistance if both the length and cross-sectional area increased proportionally, which is not the case here.
  • B. This assumes the resistance is directly proportional to the change in side length without considering the change in cross-sectional area.
  • D. This would be the resistance if the increase in cross-sectional area was the only factor considered without accounting for the increased length.

Q174. Which particle is a fundamental particle?

  • A. Electron
  • B. Hadron
  • C. Neutron
  • D. Proton

Explanation: •An electron is a kind of lepton which is considered a fundamental or elementary particle because they are not further divisible.•Hadrons are the heaviest particles; they are further composed of 2 quarks.•Protons and neutrons are baryons which are further composed of 3 quarks

Why the other options are wrong
  • B. Hadrons are composite particles made up of quarks. Examples include protons and neutrons, which are not fundamental particles.
  • C. Neutrons are baryons, a type of hadron, composed of three quarks. They are not fundamental particles.
  • D. Protons are baryons, a type of hadron, composed of three quarks. They are not fundamental particles.

Q175. The nuclear equation shown has a term missing. What is represented by the missing term?

  • A. An antineutrino
  • B. An electron
  • C. A neutrino
  • D. A positron

Explanation: Antineutrinos are produced in nuclear beta decay together with a beta particle (in beta decay a neutron decays into a proton, electron, and antineutrino).

Why the other options are wrong
  • B. An electron is indeed emitted in beta decay, but it is not the missing term in the nuclear equation if the question specifically asks for the antineutrino.
  • C. Neutrinos are particles associated with beta-plus decay (positron emission). In beta-minus decay, which involves neutron to proton conversion, an antineutrino is emitted, not a neutrino.
  • D. A positron is emitted in beta-plus decay, where a proton is converted into a neutron. However, in beta-minus decay, a neutron decays into a proton, electron, and antineutrino.

Q176. Two wave sources are oscillating in phase. Each source produces a wave of wavelength 𝜆. The two waves from the sources meet at point 𝑋 with a phase difference of 90°.What is a possible difference in the distances from the two wave sources to point 𝑋?

  • A. 𝜆/8
  • B. 𝜆/4
  • C. 𝜆/2
  • D. 𝜆

Explanation: The two given sources are in phase. A distance equal to the wavelength corresponds to a phase difference of 360, this means that they are in phase. When two things are in phase it infers that they have no phase difference.This shows us that a phase difference of 90 corresponds to a distance equal to 𝜆/4.

Why the other options are wrong
  • A. 𝜆/8 corresponds to a phase difference of 45°, not 90°.
  • C. 𝜆/2 corresponds to a phase difference of 180°, which is incorrect for a 90° phase difference.
  • D. 𝜆 corresponds to a phase difference of 360°, which is incorrect for a 90° phase difference.

Q177. The activity of a certain nuclide is governed by the relation ∆𝑁/∆𝑡= −𝜆𝑁 where 𝜆 = 2.4 × 10−8𝑠−1. What is the half-life of the nuclide?

  • A. 2.9 × 107𝑠
  • B. 1.3 × 107𝑠
  • C. 1.2 × 10−8𝑠
  • D. 3.4 × 10−8𝑠

Explanation: Using the following formulaT1/2= 0.693/decay constant

Why the other options are wrong
  • B. This option is incorrect. This value does not align with the calculated half-life using the given decay constant.
  • C. This option is incorrect. This value is orders of magnitude smaller than the calculated half-life, indicating a misunderstanding of the formula.
  • D. This option is incorrect. The value is not consistent with the expected half-life calculation, suggesting a calculation error.

Q178. Four resistors are connected in a square as shown. The resistance may be measured between any two junctions. Between which two junctions is the measured resistance greatest?

  • A. P and Q
  • B. Q and S
  • C. R and S
  • D. S and P

Explanation: Formula for total resistance in a parallel circuit will be used 1/Rt=1/R1 + 1/R2

Why the other options are wrong
  • A. The resistance between P and Q involves only two resistors in series, resulting in a moderate resistance.
  • C. The resistance between R and S involves two resistors in series, similar to between P and Q, providing a moderate resistance.
  • D. The resistance between S and P involves two resistors in parallel, leading to a lower resistance than between Q and S.

Q179. The power loss 𝑃 in a resistor is calculated using the formula: 𝑃 =𝑉2/R The uncertainty in the potential difference 𝑉 is 3% and the uncertainty in the resistance 𝑅 is 2%. What is the uncertainty in 𝑃?

  • A. 4%
  • B. 7%
  • C. 8%
  • D. 11%

Explanation: •The fractional error in V would be3×2=6•The fractional error in R would be2•So the fractional error of power would be equal to the sum of the fractional errors of both potential difference and resistance;6+3=8•NOTE= The given % error is multiplied by the power as in case of potential difference.

Why the other options are wrong
  • A. 4% is incorrect. It assumes incorrect calculations for uncertainties in V and R. Revisit how uncertainties are combined.
  • B. 7% is incorrect. While it may seem plausible, it doesn't account for the proper addition of uncertainties in quadrature. Recalculate using the correct method.
  • D. 11% is incorrect. This option overestimates the uncertainty. Review the correct way to combine uncertainties for quantities involving powers.

Q180. A quantity 𝑥 is to be determined from the equation, 𝑥 = 𝑃 – 𝑄. 𝑃 is measured as (1.27 ± 0.02) 𝑚 and 𝑄 is measured as (0.83 ± 0.01) 𝑚. What is the percentage uncertainty in 𝑥 to one significant figure?

  • A. 0.4%
  • B. 2%
  • C. 3%
  • D. 7%

Explanation: The following is the solution:•The first figures are to be subtracted:1.27-0.83=0.44•The second figures (least counts) are to be added:0.02+0.01=0.03•Now the results from both steps are divided:=(0.03/0.44)x100=6.82% ≈ 7%Hence, option D is correct.

Why the other options are wrong
  • A. This option underestimates the percentage uncertainty. Ensure you correctly calculate the absolute uncertainty and apply it to the result.
  • B. This option is incorrect. Re-evaluate the absolute uncertainty and ensure it corresponds to the total measurement.
  • C. This option is incorrect. Double-check your calculations for both absolute uncertainty and percentage conversion.

Q181. The number of electrons in one coulomb of charge are:

  • A. 6.25 × 1021
  • B. 1.6 × 1019
  • C. 6.25 × 1018
  • D. 9.1 × 1031

Explanation: 6.25×1018 are the number of electrons in one coulomb of charge.

Why the other options are wrong
  • A. This is incorrect. This number is much larger than the actual count of electrons in one coulomb of charge.
  • B. This is incorrect. This value is related to the charge of a single electron in coulombs, not the number of electrons.
  • D. This is incorrect. This number is related to the mass of an electron in kilograms, not the number of electrons in a coulomb of charge.

Q182. Which of the following series lie in the visible region?

  • A. Lyman
  • B. Paschen
  • C. Balmer
  • D. Pfund

Explanation: Four of the Balmer lines are in the technically visible part of the spectrum, with wavelengths between 400nm−700nm.The Lyman, Balmer, Paschen, and Pfund series are terms used to describe different series of spectral lines in the emission spectrum of hydrogen and other elements. These series correspond to transitions of electrons between different energy levels within the atom.1. **Lyman Series:** The Lyman series is a series of spectral lines in the ultraviolet region of the electromagnetic spectrum. It corresponds to transitions of electrons from higher energy levels to the n = 1 energy level (ground state) of the hydrogen atom. The lines in this series are named after the scientist Theodore Lyman who studied them.2. **Balmer Series:** The Balmer series is a series of spectral lines in the visible region of the electromagnetic spectrum. It corresponds to transitions of electrons from higher energy levels to the n = 2 energy level of the hydrogen atom. The lines in this series were discovered by Johann Balmer.3. **Paschen Series:** The Paschen series is a series of spectral lines in the infrared region of the electromagnetic spectrum. It corresponds to transitions of electrons from higher energy levels to the n = 3 energy level of the hydrogen atom. The lines in this series were studied by Friedrich Paschen.4. **Pfund Series:** The Pfund series is a series of spectral lines in the infrared region of the electromagnetic spectrum. It corresponds to transitions of electrons from higher energy levels to the n = 4 energy level of the hydrogen atom. The lines in this series were observed by August Herman Pfund.These series of spectral lines occur because of the quantized nature of energy levels in atoms. When electrons transition from higher energy levels to lower energy levels, they emit photons of specific energies, which correspond to specific wavelengths or frequencies of light. Each series corresponds to transitions ending at a specific lower energy level, and the lines within each series represent different possible paths for electrons to take while transitioning to that level.These spectral series provided crucial insights into the quantization of energy in atoms and played a significant role in the development of quantum mechanics.

Why the other options are wrong
  • A. The Lyman series is found in the ultraviolet region, formed when electrons transition from higher energy levels to the n = 1 level.
  • B. The Paschen series is located in the infrared region, resulting from electron transitions to the n = 3 level.
  • D. The Pfund series appears in the infrared region, occurring when electrons move to the n = 5 level.

Q183. Two springs of spring constant 𝐾1 and 𝐾2 are arranged in parallel and a body of mass 𝑚 is attached to it then calculate the time period of the system:

  • A. T = 2π√(m/(K1 + K2))
  • B. T = 2π√(2m/(K1 + K2))
  • C. T = 2π√(m/(K1 * K2))
  • D. T = 2π√((K1 + K2)/m)

Explanation: T=2π(M/K)½T=2π(M/K1+K2)½

Why the other options are wrong
  • B. This option is incorrect because it incorrectly introduces a factor of 2 in the mass. The correct formula only involves the mass m, not 2m.
  • C. This option is incorrect because it uses the product of the spring constants K1 and K2 instead of their sum. The correct formula for parallel springs involves the sum.
  • D. This option is incorrect because it places the sum of the spring constants in the numerator instead of the denominator. The correct formula involves the square root of the mass divided by the sum of the spring constants.

Q184. To determine the resistance of a voltmeter by discharging a capacitor through it, the instantaneous voltage is then given by the relation:

  • A. V(t) = V0e-t/RC
  • B. V(t) = V0(1 - e-t/RC)
  • C. V(t) = V0et/RC
  • D. V(t) = V0t/RC

Explanation: Option A is the correct option since Voe-t/RC gives the correct instantaneous voltage.

Why the other options are wrong
  • B. This option is incorrect as it represents the charging of a capacitor over time, not discharging.
  • C. This option is incorrect as the presence of a positive exponent suggests an increase in voltage, which does not occur during discharging.
  • D. This option is incorrect because it implies a linear relationship, which does not describe the exponential nature of capacitor discharge.

Q185. The amount of heat required to raise the temperature of 10 moles of water from 70𝐾 to 80𝐾 (molar heat capacity of water 75.24𝐽) is:

  • A. 0.7524𝐽
  • B. 7524𝐽
  • C. 95.24𝐽
  • D. 752.4𝐽

Explanation: We use the formula E= nC x (change in temperature) i.e 10 x 75.24 x 10 = 7524 J

Why the other options are wrong
  • A. This option mistakenly considers a much smaller scale by miscalculating either the number of moles or the change in temperature.
  • C. This option incorrectly uses a different set of values, possibly misrepresenting the number of moles or the heat capacity.
  • D. This option likely results from a calculation error, perhaps by misapplying the units or missing a factor of 10 in the calculation.

Q186. To determine Young’s modulus of a material of a given wire of length 𝐿 we use:

  • A. Melda's Apparatus
  • B. Young’s Apparatus
  • C. Searle’s Apparatus
  • D. Cavendish Apparatus

Explanation: •Searle's apparatus is used for the measurement of Young's modulus. It consists of two equal-length wires that are attached to a rigid support.•Melde's Apparatus is a simple way to introduce students to the concept of standing waves. The apparatus consists of a string and an oscillator to generate different frequencies. Melde's experiment is ideal to study the behavior of standing waves. Supplied with accessories like pulley and clamp, scale pan, and cord.•Young's modulus apparatus is used to measure Young's modulus of a bar, not a wire.•By measuring the angle of the rod and knowing the twisting force (torque) of the wire for a given angle, Cavendish was able to determine the force between the pairs of masses, by using the Cavendish apparatus.

Why the other options are wrong
  • A. Melda's Apparatus is used for demonstrating standing waves. It is not related to the measurement of Young's modulus of a material. Therefore, this option is incorrect.
  • B. Young's modulus apparatus is typically used for measuring Young's modulus of bars, not wires. Thus, this option is not suitable for the given question.
  • D. The Cavendish apparatus is used to measure gravitational forces and is not related to the determination of Young's modulus. Therefore, this option is incorrect.

Q187. An electron is projected horizontally from south to north in a uniform horizontal magnetic field acting from west to east. The direction along which it will be deflected is:

  • A. Northwards
  • B. Southwards
  • C. Vertically upwards
  • D. Vertically downwards

Explanation: Apply the rule as shown in the following image.By this, we get a downward direction. But keep in mind we use the right-hand rule for positive charge. In case of a negative charge, we will take opposite conclusions so the direction of force (deflection) would be vertically upward in the case of an electron.

Why the other options are wrong
  • A. Using the right-hand rule, the force would be perpendicular to both the velocity of the electron and the magnetic field. This option is incorrect.
  • B. Applying the right-hand rule indicates the direction of force is not southwards. Hence, this option is incorrect.
  • D. For a positive charge, the force would be directed downwards using the right-hand rule, but for a negative charge like an electron, it is reversed to upwards. This option is incorrect.

Q188. When we are measuring the internal resistance of a cell by potentiometer, the emf of the battery must be greater than the :

  • A. Emf of the cell
  • B. P.D in the circuit
  • C. Current in the cell
  • D. Current in the circuit

Explanation: The emf of the battery in the potentiometer experiment should be greater than the emf of the cell to be determined because The fall of potential across the potentiometer wire should not be less than the emf of the cell to be determined. And the potential across the wire is determined by the emf of the battery. If either the emf of the battery or the potential difference across the whole potentiometer wire is lesser than the emf of the experimental cell, the balance point will not be obtained. The balance point indicates that the emf of the cell to be determined is just balanced by the voltage drop that appears across the wire.

Why the other options are wrong
  • B. This option is incorrect. The potential difference (P.D) in the circuit is not relevant to the requirement that the battery's emf must exceed the cell's emf for accurate measurement.
  • C. This option is incorrect. The current in the cell does not directly influence the need for a higher battery emf in the potentiometer setup.
  • D. This option is incorrect. The current in the circuit is not directly related to the condition that the battery's emf should be higher than the cell's emf when using a potentiometer.

Q189. The Young’s modulus of a given rod of uniform length 𝐿 is given by the relation:

  • A. 𝐹𝐿/𝐴
  • B. 𝐹𝐴/L
  • C. F𝐿/𝜋𝑟2𝑙
  • D. F𝑙/𝜋𝑟2L

Explanation: Young modulus=stress/strain FL/Al where l is the extension

Why the other options are wrong
  • A. This option represents the formula for stress (σ), not Young's modulus (E).Stress (σ) is defined as force (F) per unit area (A): σ=F/A While stress is related to Young's modulus through Hooke's Law (σ=E⋅ϵ), it is not the same as Young's modulus itself, which includes the original or undeformed length in its calculation.
  • B. This expression does not include the necessary terms for calculating Young's modulus.Young's modulus (E) is determined by the ratio of stress to strain, where strain involves the original length (L).This formula lacks the dimensional balance to represent Young's modulus correctly.
  • D. This option includes the elongation (l) in the numerator, which is incorrect for Young's modulus.Young's modulus (E) is defined as the ratio of stress to strain, where strain is the elongation divided by the original length (L), not the other way around.This formula misrepresents the relationship between stress and strain.

Q190. The inward and outward electric flux from a closed surface is respectively 8×103units and 4×103 units, then the net charge inside the closed surface is:

  • A. A:+4×103 ε0
  • B. B:-4×103 ε0
  • C. C:0 ε0
  • D. D:+8×103 ε0

Explanation: Flux2-flux1= q/epsilon notQ= (4×103 - 8×103) epsilon

Why the other options are wrong
  • A. The net charge is calculated by considering inward and outward flux. The formula is: Q = (fluxout - fluxin) ε0. If inward flux is greater, the charge should be negative.
  • C. This option suggests that the inward and outward flux are equal, resulting in no net charge. However, this is not the case here.
  • D. This option suggests an incorrect calculation of net charge, assuming an incorrect relationship between flux and charge.

Q191. A radioactive isotope has a half-life of 3 days. The time after which its activity is reduced to 6.25% of its original activity is:

  • A. 6 days
  • B. 8 days
  • C. 12 days
  • D. 16 days

Explanation: 50% in 3 days25% in 6 days12.5% in 9 days6.25% in 12 days

Why the other options are wrong
  • A. After 6 days, the activity will have reduced to 25% (two half-lives: 100% -> 50% -> 25%). This is not sufficient to reach 6.25%.
  • B. After 8 days, the activity does not align with any specific percentage reduction based on the half-life of 3 days. This is not a valid option.
  • D. After 16 days, the percentage would further reduce beyond 6.25%, which is not required based on the question. This is incorrect.

Q192. There are two charges +2𝜇𝐶 and -3𝜇𝐶. The ratio of the force acting on them will be:

  • A. 3 ∶ 1
  • B. 1 ∶ 1
  • C. 11 ∶ 8
  • D. 3 ∶ 8

Explanation: Electrostatic force is a mutual force that will not act on a single charge.

Why the other options are wrong
  • A. This option is incorrect. The force on each charge is equal in magnitude due to Newton's third law.
  • C. This option is incorrect. There is no calculation involving these numbers that pertains to the forces between the charges.
  • D. This option is incorrect. The forces are not calculated based on these numbers but are equal and opposite according to electrostatic principles.

Q193. Two radioactive samples 𝑆1 and 𝑆2 have half-lives of 3 hours and 7 hours respectively. If they have the same activity at certain instant 𝑡, what is the ratio of the number of atoms of 𝑆1 to 𝑆2 at instant 𝑡?

  • A. 9: 49
  • B. 49: 9
  • C. 3: 7
  • D. 7: 3

Explanation: Explanation is given below:

Why the other options are wrong
  • A. This option incorrectly calculates the ratio by squaring the half-lives instead of using them directly in the decay constant formula.
  • B. This option incorrectly reverses the ratio calculation, misunderstanding the inverse relationship between half-life and number of atoms for equal activity.
  • D. This option incorrectly reverses the ratio, assuming that the longer half-life corresponds to a greater number of atoms, which is not the case for equal activity.

Q194. The reciprocal of resistivity is called:

  • A. Resistance
  • B. Inductance
  • C. Conductivity
  • D. Flexibility

Explanation: Conductivity is the measure of a material's ability to conduct electric current. It is the reciprocal of resistivity.The higher the conductivity, the better the material is at allowing the flow of electric current

Why the other options are wrong
  • A. Resistance is a property of a material that opposes the flow of electric current. It is measured in ohms (Ω) and is the ratio of voltage to current in a circuit.The reciprocal of resistance is conductance.
  • B. Inductance is a property in electrical circuits that describes the ability of a coil or wire to store energy in a magnetic field when an electric current is passed through it.The reciprocal of inductance is called "capacitance."
  • D. Flexibility is not directly related to electrical properties like resistivity or conductivity. It refers to the ability of a material to bend, deform, or flex without breaking.There is no reciprocal term specifically associated with flexibility in the context of electrical properties.

Q195. Doubly ionized atoms 𝑋 and 𝑌 of two different elements are accelerated through the same P.D. on entering a uniform magnetic field they describe circular paths of radii 𝑅1 and 𝑅2. The masses of 𝑋 and 𝑌 are in the ratio of:

  • A. R1: 𝑅2
  • B. 𝑅2: 𝑅1
  • C. R21 : 𝑅22
  • D. R22: 𝑅21

Explanation: Refer to the following

Q196. The rest mass of Photon is 𝑚𝑜. Its linear momentum, when it moves with the speed equal to half of the speed of light in space, will be:

  • A. Option A
  • B. Option B
  • C. Option C
  • D. Option D

Explanation: Refer to the following.

Why the other options are wrong
  • A. This option is incorrect. Photons have zero rest mass, so using rest mass in the formula for momentum is not applicable.
  • B. This option is incorrect. The formula for momentum of a photon does not involve rest mass.
  • D. This option is incorrect because the momentum of a photon is not halved even if it moves at half the speed of light, since momentum depends on wavelength, not speed.

Q197. The charge on the electron and proton is reduced to half. If the present value of Rydberg constant is 𝑅, then the new value of Rydberg constant will be:

  • A. 𝑅/2
  • B. 𝑅/4
  • C. 𝑅/8
  • D. 𝑅/16

Explanation: Explaination is given in the image.

Why the other options are wrong
  • A. This option is incorrect. Reducing the charge affects the Rydberg constant more significantly than halving it.
  • B. This option is incorrect. The dependency is stronger than just reducing it by a factor of 4.
  • C. This option is incorrect. The Rydberg constant decreases more significantly with the charge reduction.

Q198. The paratrooper of mass 80 𝑘𝑔 descends vertically at a constant velocity of 3 𝑚 𝑠−1taking the acceleration of free fall as 10 𝑚 𝑠−2. Find out what is the net force acting on him?

  • A. Zero
  • B. 800 𝑁 upward
  • C. 800 𝑁 downward
  • D. 240 𝑁 downward

Explanation: The correct answer is zero net force. Since the paratrooper is descending at a constant velocity, there is no acceleration (Newton's first law). This means the forces are balanced: the gravitational force (weight) is exactly balanced by the upward force from the parachute. Thus, the net force is zero. Other options are incorrect because they suggest a net force which would imply acceleration, conflicting with the situation of constant velocity.

Why the other options are wrong
  • B. This option is incorrect. An upward net force of 800 N would cause the paratrooper to accelerate upwards, which contradicts the scenario of constant velocity downwards.
  • C. This option is incorrect because a net downward force would cause the paratrooper to accelerate downwards, conflicting with the constant velocity of the descent.
  • D. This option is incorrect because a net downward force of 240 N would result in significant acceleration, contrary to the constant velocity of the paratrooper.

Q199. The dimensional formula for change in momentum is same as that for:

  • A. Force
  • B. Impulse
  • C. Acceleration
  • D. Velocity

Explanation: The following is the solution:Impulse can be defined as “The sudden force acting on an object for a short interval of time”.It is equal to ∆PThe units of both momentum and impulse are the same so their dimensional formulas are also same.

Why the other options are wrong
  • A. Incorrect. The dimensional formula for force is different from that of momentum or impulse, as it includes time squared in the denominator.
  • C. Incorrect. Acceleration has a different dimensional formula, which involves a change in velocity over time.
  • D. Incorrect. Velocity's dimensional formula lacks the mass component, which is crucial in momentum and impulse.

Q200. What is NOT true of 2 forces that give rise to a couple?

  • A. They act in opposite directions
  • B. They both act at the same point
  • C. They both act on the same body
  • D. They both have the same magnitude

Explanation: Two equal and opposite parallel forces not acting along the same line form a couple.

Why the other options are wrong
  • A. This is a true statement. For two forces to form a couple, they must act in opposite directions.
  • C. This is a true statement. A couple consists of two forces acting on the same body.
  • D. This is a true statement. The forces in a couple must have equal magnitude.

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