Home/Past Papers/KPK / ETEA/Kpk Chemistry 2009
Kpk Chemistry 2009 — Solved Past Paper with Answers
All 17 MCQs from Kpk Chemistry 2009, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT KPK / ETEA past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all KPK / ETEA papers.
Attempt this paper interactively →Q1. Potassium dichromate acts as a strong?
- A. Reducing
- B. Oxidizing
- C. Bleaching
- D. Dehydrating✓
Explanation: This is the correct answer. Potassium dichromate acts as a strong dehydrating agent in certain reactions. It can oxidize alcohol to a ketone or aldehyde, removing water molecules in the process. This dehydration property is particularly useful in organic chemistry reactions where the removal of water is desired to form specific products..
Why the other options are wrong
- A. Potassium dichromate is not a reducing agent; it is an oxidizing agent. It causes other substances to lose electrons (be oxidized) and itself gains electrons (is reduced). This process is the opposite of reduction.
- B. Potassium dichromate is indeed an oxidizing agent. It causes other substances to lose electrons (be oxidized). However, it does not itself undergo reduction to release water.
- C. While potassium dichromate can be used in bleaching processes, its primary function in this context is as an oxidizing agent rather than a bleaching agent. It causes the oxidation of certain substances, which can result in color changes associated with bleaching, but its role is not primarily bleaching.
Q2. The carbon content in steel is:
- A. 2.5-4.5%
- B. 0.12-0.25%
- C. 0.01-0.05%
- D. 0.1-1.5%✓
Explanation: This is the correct range for the carbon content in steel. Carbon content in this range allows for a wide range of steel types, from low to high carbon steels, each with different properties suited for various applications.
Why the other options are wrong
- A. This range is too high for carbon content in steel. Steel with this level of carbon would be considered high carbon steel, which is typically used for applications requiring high strength and hardness, such as tools.
- B. This range is lower than the typical carbon content in steel. Steel with this level of carbon would likely be considered low carbon steel, which is more ductile and easy to weld but has lower strength compared to higher carbon steels.
- C. This range is lower than the typical carbon content in steel. Steel with this level of carbon would likely be considered low carbon steel, which is more ductile and easy to weld but has lower strength compared to higher carbon steels.
Q3. The color of transition metal complexes is due to:
- A. D-d transition
- B. Ionization
- C. Loss of
- D. Paramagnetic✓
Explanation: This is the correct answer. Transition metal complexes often have unpaired electrons in their d orbitals, which leads to paramagnetism. The presence of unpaired electrons allows these complexes to interact with magnetic fields, giving rise to their paramagnetic properties and often contributing to their characteristic colors.
Why the other options are wrong
- A. This is a mechanism by which transition metal complexes absorb light and can contribute to their color, but it is not the primary reason for the color. D-d transitions involve the excitation of electrons from one d orbital to another, which can lead to color changes, but the underlying cause is the presence of unpaired electrons.
- B. Ionization of transition metal complexes can lead to changes in their electronic structure and can affect their color, but ionization itself is not the primary reason for their color. The presence of unpaired electrons in the transition metal ions is the key factor.
- C. This option seems incomplete and unclear. It's not clear what is being referred to as "loss of." If this option is referring to the loss of electrons, it can be related to ionization or oxidation, but again, the primary reason for the color is the presence of unpaired electrons.
Q4. Milk of "magnesia" is?
- A. Solution of barium hydroxide
- B. Saturated solution of calcium hydroxide
- C. Suspension of magnesium hydroxide✓
- D. None of these
Explanation: Milk of magnesia is a suspension of magnesium hydroxide in water. It is commonly used as an antacid or a laxative due to its ability to neutralize stomach acid and relieve constipation.
Why the other options are wrong
- A. This is incorrect. Milk of magnesia does not contain barium hydroxide. It contains magnesium hydroxide.
- B. This is incorrect. Milk of magnesia does not contain calcium hydroxide. It contains magnesium hydroxide.
- D. This is incorrect. The correct answer is C, as milk of magnesia is indeed a suspension of magnesium hydroxide.
Q5. Alkali metals are.....?
- A. Oxidized by water
- B. Reduced by hydrogen
- C. Stores under water
- D. From reactive cations✓
Explanation: Alkali metals readily lose their outermost electron to form positively charged ions (cations). These cations are highly reactive due to their strong tendency to regain stability by accepting electrons from other substances.
Why the other options are wrong
- A. Alkali metals are indeed oxidized by water. When alkali metals react with water, they lose electrons and form hydroxide ions and hydrogen gas.
- B. This statement is incorrect. Alkali metals are not reduced by hydrogen. In fact, alkali metals are more reactive than hydrogen and can displace it from compounds such as water.
- C. Alkali metals are stored under oil or inert gases such as argon because they react vigorously with water, producing hydrogen gas and hydroxide ions.
Q6. Nitrous oxide is sometimes called:
- A. Combat
- B. Tear gas
- C. Water
- D. Laughing✓
Explanation: This is the correct answer. Nitrous oxide is sometimes referred to as "laughing gas" because of its euphoric effects when inhaled in small doses. It can cause laughter and a sense of light-headedness or euphoria, which has led to its recreational use in some settings.
Why the other options are wrong
- A. This term is not commonly associated with nitrous oxide. Nitrous oxide is used for medical and dental purposes as an anesthetic and analgesic, not for combat.
- B. Nitrous oxide is not a tear gas. Tear gases are substances that irritate the eyes, causing tearing, pain, and even temporary blindness. Nitrous oxide does not have these properties.
- C. Nitrous oxide is not called "water." Water is a different substance with its own distinct properties.
Q7. In the periodic table the majority of gases are found in the?
- A. Upper
- B. Middle
- C. Upper
- D. Lower part✓
Explanation: This is the correct answer. The majority of gases in the periodic table are found in the lower part, specifically in Group 18 (noble gases). These gases are in the gas phase at room temperature and are chemically inert.
Why the other options are wrong
- A. Gases are indeed found in the upper part of the periodic table, specifically in Group 18 (noble gases), which is located at the top of the table. These gases are all in the gas phase at room temperature and are known for their inertness and lack of reactivity.
- B. Gases are not predominantly found in the middle of the periodic table. The middle of the table contains transition metals, which are typically solids at room temperature.
- C. Gases are indeed found in the upper part of the periodic table, specifically in Group 18 (noble gases), which is located at the top of the table. These gases are all in the gas phase at room temperature and are known for their inertness and lack of reactivity.
Q8. Aqueous solution of borax is....?
- A. Alkaline
- B. Acidic
- C. Neutral
- D. Amphoteric✓
Explanation: Borax solution is amphoteric, meaning it can behave as both an acid and a base depending on the reaction conditions. This property is due to the presence of both acidic (H₃BO₃) and basic (BO₃²⁻) species in the solution.
Why the other options are wrong
- A. Borax solution is alkaline in nature. It can accept protons (H⁺ ions), making it basic. This property is due to the presence of the borate ion (BO₃²⁻), which can accept a proton to form boric acid (H₃BO₃).
- B. Borax solution is not acidic. While it can act as an acid in certain reactions, its overall nature in solution is basic.
- C. Borax solution is not neutral. It is basic in nature due to its ability to accept protons.
Q9. Which one of the following acid on large scale is produced from bone ash:
- A. H2SO
- B. H3PO4
- C. H2CO3
- D. None of these✓
Explanation: Bone ash is mainly composed of calcium phosphate, which is primarily used in the production of phosphoric acid (H3PO4) on a large scale. However, bone ash itself is not a direct source of any of the acids mentioned in the options. Instead, it serves as a raw material for the production of phosphoric acid through various chemical processes. Therefore, the correct answer is D..
Why the other options are wrong
- A. It is not produced from bone ash on a large scale. It is typically produced by the Contact process, which involves the reaction of sulfur dioxide with oxygen over a vanadium(V) oxide catalyst.
- B. It is not produced from bone ash on a large scale. It is commonly produced by treating phosphate rock with sulfuric acid.
- C. It is not produced from bone ash on a large scale. It is a weak acid that is formed when carbon dioxide dissolves in water.
Q10. A compound "x" when heated with anhydrous silver oxide forms an ether, identify "x".
- A. C2H6
- B. C2H4
- C. C2H2
- D. CH4✓
Explanation: CH4 can undergo the Favorskii rearrangement to form an ether.
Why the other options are wrong
- A. Ir does not contain any halogen atom and therefore cannot undergo the Favorskii rearrangement to form an ether.
- B. It is more likely to undergo dehydrohalogenation to form an ether, as mentioned in the previous question.
- C. It is a highly reactive compound and does not typically form ethers through the Favorskii rearrangement.
Q11. Lucas test is used to distinguish between....?
- A. Alcohol
- B. Aldehyde
- C. Carboxylic
- D. Alakyl✓
Explanation: The Lucas test is primarily used to differentiate between primary, secondary, and tertiary alkyl alcohols. Tertiary alkyl alcohols react rapidly with Lucas reagent to form alkyl halides, which are insoluble in the reaction mixture and appear as a cloudy solution or a separate layer. Secondary alkyl alcohols react more slowly, while primary alkyl alcohols do not react at all under the test conditions.
Why the other options are wrong
- A. While the Lucas test is used to test alcohols, it specifically focuses on alkyl alcohols and their classification based on their reactivity with Lucas reagent.
- B. Aldehydes do not typically react with Lucas reagent to form alkyl halides. They are not the main focus of the Lucas test, which is more specific to alcohol classification.
- C. Carboxylic acids do not react with Lucas reagent in the same manner as alcohols. The Lucas test is not used to distinguish carboxylic acids from other compounds.
Q12. Organic catalyst produced by living organisms are called..?
- A. Vitamins
- B. Lipids
- C. Nucleic
- D. Enzymes✓
Explanation: Enzymes are organic catalysts produced by living organisms. They are typically proteins that speed up biochemical reactions without being consumed in the process. Enzymes are crucial for various biological processes..
Why the other options are wrong
- A. Vitamins are organic compounds that are essential for normal growth and metabolism, but they are not catalysts. They act as coenzymes or precursors to coenzymes, which can be required for enzyme activity.
- B. Lipids are a diverse group of organic compounds that include fats, oils, and some steroids. While lipids are essential components of cell membranes and serve other important functions, they are not catalysts.
- C. Nucleic acids, such as DNA and RNA, are biomolecules that store and transmit genetic information. They are not catalysts but are involved in the synthesis of proteins, which are often enzymatically catalyzed.
Q13. All the compounds are inorganic except?
- A. KCN
- B. CaC3
- C. CaC2
- D. (NH2)2C✓
Explanation: It is the correct answer. Urea is an organic compound that contains carbon-hydrogen bonds and is produced by living organisms as a waste product of metabolism. It is not considered an inorganic compound.
Why the other options are wrong
- A. It is an inorganic compound. It is a salt containing potassium and the cyanide ion.
- B. CaC3 is not a valid chemical formula. Assuming you meant CaCO3, it is an inorganic compound known as calcium carbonate. It is a common mineral and the main component of shells, pearls, and the skeletons of marine organisms.
- C. It is an inorganic compound. It is used in the production of acetylene and other chemicals.
Q14. Acetamide is obtained by?
- A. Heating methyl cynanide
- B. Heating ammonium acetate
- C. Heating ethyl acetate
- D. Hydrolysis of methyl cynanide✓
Explanation: Hydrolysis of methyl cyanide is correct. Acetamide is obtained by the hydrolysis of methyl cyanide (also known as acetonitrile) in the presence of acid or base. This reaction produces acetamide and ammonia.
Why the other options are wrong
- A. Heating methyl cyanide (acetonitrile) does not directly lead to the formation of acetamide. Acetonitrile is a different compound and does not contain the necessary functional groups to form acetamide through heating alone.
- B. Heating ammonium acetate does not directly lead to the formation of acetamide. Ammonium acetate is a salt that can decompose to form acetamide, but this process typically involves heating with a strong base, not simply heating alone.
- C. Heating ethyl acetate does not lead to the formation of acetamide. Ethyl acetate is a different compound and does not contain the necessary functional groups to form acetamide through heating alone.
Q15. Which of the following is not a fatty acid?
- A. Propanoic acid
- B. Ethanoic acid
- C. Phthalic acid
- D. Butanoic acid✓
Explanation: Butanoic acid is not a fatty acid. Fatty acids are carboxylic acids with long hydrocarbon chains, typically containing between 4 and 24 carbon atoms. Butanoic acid, also known as butyric acid, has a four-carbon chain and is considered a short-chain fatty acid.
Why the other options are wrong
- A. Propanoic acid is also known as propionic acid and is a short-chain fatty acid with a three-carbon chain.
- B. Ethanoic acid is also known as acetic acid and is a short-chain fatty acid with a two-carbon chain.
- C. Phthalic acid is not a fatty acid. It is a benzene dicarboxylic acid used in the production of phthalate esters, which are commonly used as plasticizers.
Q16. In SN2 reaction the rate depends upon the structure of alkyl halides in the following order?
- A. Tertiary>Secondary>Primary
- B. Primary>Secondary>Tertiary
- C. Secondary>Primary>Tertiary
- D. Primary>Tertiary>Secondary✓
Explanation: Primary alkyl halides react the fastest in SN2 reactions because the nucleophile can easily access the backside of the carbon center, facilitating the attack.
Why the other options are wrong
- A. Tertiary alkyl halides react the slowest in SN2 reactions because steric hindrance prevents the nucleophile from accessing the carbon center effectively.
- B. Primary alkyl halides react faster than secondary alkyl halides due to the lesser steric hindrance in primary compounds.
- C. Secondary alkyl halides react faster than tertiary alkyl halides but slower than primary alkyl halides due to the increased steric hindrance in secondary compounds compared to primary compounds.
Q17. Benzene cannot undergo?
- A. Oxidation reactions
- B. Addition reactions
- C. Elimination reactions
- D. Substitution reactions✓
Explanation: Substitution reactions is correct. Benzene undergoes substitution reactions rather than addition reactions due to its high stability resulting from resonance. In substitution reactions, one atom or group is replaced by another atom or group.
Why the other options are wrong
- A. Benzene can undergo oxidation reactions under specific conditions, leading to the formation of various products, including phenol, benzoic acid, and nitrobenzene.
- B. Benzene does not readily undergo addition reactions under typical conditions due to its high stability from resonance. However, under certain conditions and with the use of strong reagents, benzene can undergo addition reactions, such as the addition of bromine in the presence of a catalyst to form bromobenzene.
- C. Benzene does not typically undergo elimination reactions, which involve the removal of atoms or groups to form a double bond or a ring structure. Benzene's stability prevents it from undergoing such reactions readily.
More KPK / ETEA Solved Papers
Biology
Etea Mdcat 2005
161 solved MCQs
Biology
Etea Mdcat 2005
161 solved MCQs
Chemistry
Etea Mdcat 2006
170 solved MCQs
Biology
Etea Mdcat 2006
170 solved MCQs
Biology
Etea Mdcat 2008
198 solved MCQs
Biology
Etea Mdcat 2008
200 solved MCQs
Chemistry
Etea Mdcat 2009
200 solved MCQs
Biology
Etea Mdcat 2009
200 solved MCQs
Chemistry
Etea Mdcat 2010
200 solved MCQs