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Kpk Chemistry 2010 — Solved Past Paper with Answers

All 18 MCQs from Kpk Chemistry 2010, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT KPK / ETEA past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all KPK / ETEA papers.

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Q1. Which one is correct according to atomic size?

  • A. K>Na
  • B. Cl>I
  • C. Mg>Ca
  • D. Cu>Co

Explanation: Cu > Co is correct because copper (Cu) has a larger atomic size than cobalt (Co). This is because as you move down a group in the periodic table, atomic size generally increases due to the addition of new electron shells. Copper is located below cobalt in the same period, so it has more electron shells and a larger atomic size.

Why the other options are wrong
  • A. K > Na is incorrect because potassium (K) has a smaller atomic size than sodium (Na). As you move from left to right across a period in the periodic table, atomic size generally decreases due to increased nuclear charge pulling the electrons closer to the nucleus.
  • B. Cl > I is incorrect because iodine (I) has a larger atomic size than chlorine (Cl). As you move down a group in the periodic table, atomic size generally increases due to the addition of new electron shells.
  • C. Mg > Ca is incorrect because calcium (Ca) has a larger atomic size than magnesium (Mg). As you move down a group in the periodic table, atomic size generally increases due to the addition of new electron shells.

Q2. Nelson's cell is used for the manufacturing of:

  • A. NaCl
  • B. NaOH
  • C. Na
  • D. Na (OH)2

Explanation: NaOH is correct because the Nelson cell is used for the manufacturing of sodium hydroxide (NaOH) through the electrolysis of brine (sodium chloride solution). In the Nelson cell, brine is electrolyzed to produce chlorine gas (Cl2) at the anode and sodium hydroxide (NaOH) at the cathode.

Why the other options are wrong
  • A. NaCl is incorrect because the Nelson cell is not used for the manufacturing of sodium chloride (NaCl). NaCl is the starting material (brine) that is electrolyzed in the cell.
  • C. Na is incorrect because the Nelson cell does not produce elemental sodium (Na). Instead, it produces sodium hydroxide (NaOH) at the cathode.
  • D. Na(OH)2 is incorrect because this compound does not exist. Sodium hydroxide (NaOH) is a compound with the formula NaOH.

Q3. Gypsum has the molecular formula?

  • A. CaSO4H2O
  • B. CaSO4.2H2O
  • C. CaSO4.3H2O
  • D. CaSO4.4H2O

Explanation: CaSO4.3H2O is correct because gypsum has the molecular formula CaSO4·2H2O. Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. When gypsum is heated to a certain temperature, it loses water molecules and forms calcium sulfate hemihydrate, commonly known as plaster of Paris.

Why the other options are wrong
  • A. Thisi for dihydrate (gypsum). s incorrect because this formula does not exist. It should be written as CaSO4·H2O for hemihydrate, or as CaSO4·2H2O.
  • B. This is incorrect because this formula does not represent the correct molecular formula for gypsum. The correct formula is CaSO4·2H2O.
  • D. This is incorrect because this formula does not exist. Gypsum is calcium sulfate dihydrate, so the correct formula is CaSO4·2H2O.

Q4. Which of the following ions are responsible for the hardiness of water?

  • A. Cl-
  • B. CO-23
  • C. HCO-3
  • D. Mg

Explanation: This is correct because bicarbonate ions (HCO3-) are responsible for the hardness of water. Hard water contains dissolved calcium and magnesium ions, which can combine with bicarbonate ions to form calcium carbonate (CaCO3) and magnesium carbonate (MgCO3), which are insoluble and contribute to the hardness of water.

Why the other options are wrong
  • A. Cl- is incorrect because chloride ions (Cl-) do not contribute to the hardness of water. Chloride ions are not involved in the formation of insoluble compounds that cause hardness.
  • B. This is incorrect because carbonate ions (CO3-2) can contribute to the hardness of water, but they are not the primary ions responsible. Bicarbonate ions (HCO3-) are more commonly found in natural water sources and are a major contributor to water hardness.
  • D. Mg is incorrect because magnesium ions (Mg2+) contribute to water hardness, but they are not the ions primarily responsible. The bicarbonate ions (HCO3-) play a larger role in water hardness than magnesium ions.

Q5. Termite process is?

  • A. Exothermic
  • B. Endothermic
  • C. Reversible
  • D. None of these

Explanation: The termite process is reversible in the sense that the products of wood digestion (such as simple sugars and other organic compounds) can be further metabolized or assimilated by the termite to support its growth and energy needs. In this sense, the process is reversible within the termite's digestive system.

Why the other options are wrong
  • A. This is incorrect. The termite process involves the breakdown of wood, which is an endothermic process overall. While some reactions within the termite's digestive system might be exothermic, the overall process is endothermic because it requires energy to break down the complex molecules in wood.
  • B. This is incorrect. While the breakdown of wood by termites does require energy input and is generally considered endothermic, the termite process itself is not specifically characterized as endothermic. The termite process involves the breakdown of wood, not the absorption of heat from the surroundings, which is more typically associated with the term "endothermic."
  • D. This is incorrect based on the explanation above. The correct answer is C, as the termite process is best described as reversible in the context of termite digestion and metabolism.

Q6. Molecule of oxygen is diatomic and behaves as:

  • A. paramagnetic
  • B. ferromagnetic
  • C. none of these
  • D.

Explanation: Explanation will be added soon

Q7. Which one is the weakest acid?

  • A. HF
  • B. HCl
  • C. HBr
  • D. HI

Explanation: This is the weakest acid among the given options. The H-Br bond is the weakest among the hydrogen halides, so HBr is the weakest acid among HF, HCl, HBr, and HI.

Why the other options are wrong
  • A. This is a weak acid but stronger than HBr. Fluorine is more electronegative than bromine, so the H-F bond is stronger than the H-Br bond, making HF a stronger acid than HBr.
  • B. This is a strong acid. The H-Cl bond is stronger than the H-Br bond, so HCl is a stronger acid than HBr.
  • D. This is the strongest acid among the given options. The H-I bond is the weakest among the hydrogen halides, so HI is the strongest acid among HF, HCl, HBr, and HI.

Q8. The coordination number of iron in [Fe(CN)6]-4:

  • A. 3
  • B. 5
  • C. 6
  • D. 7

Explanation: In the complex ion FeCN64-, iron is bonded to six cyanide ligands, resulting in a coordination number of 6.

Why the other options are wrong
  • A. This option suggests a coordination number of 3 for iron in the complex ion. However, in the complex ion (FeCN64-), iron is bonded to six cyanide ligands, resulting in a coordination number of 6, not 3.
  • B. This option implies a coordination number of 5 for iron in the complex ion. Again, in the complex ion FeCN64-, iron is bonded to six cyanide ligands, leading to a coordination number of 6, not 5.
  • D. This option suggests a coordination number of 7 for iron in the complex ion. However, in the complex ion FeCN64-, iron is bonded to six cyanide ligands, not seven, leading to a coordination number of 6, not 7.

Q9. All the compounds are inorganic except:

  • A. CaCO3
  • B. CaC2
  • C. KCN
  • D. (NH2)2CO

Explanation: This is an organic compound. Urea is a compound found in urine and is also produced synthetically for use in fertilizers, plastics, and pharmaceuticals. It contains carbon-hydrogen bonds and is considered organic due to its carbon-based structure.

Why the other options are wrong
  • A. This is an inorganic compound. It is composed of calcium ions (Ca2+) and carbonate ions (CO32-) and is commonly found in minerals such as limestone and chalk.
  • B. This is an inorganic compound. It is used in the production of acetylene gas and is formed by the reaction of calcium oxide with carbon at high temperatures.
  • C. This is an inorganic compound. It is a highly toxic salt that is used in various industrial processes, such as gold mining and electroplating.

Q10. Which of the following hydrocarbon will give product through the substitution reaction?

  • A. C2H4
  • B. C3H6
  • C. C2H4
  • D. C2H6

Explanation: Ethylene can undergo substitution reactions, particularly under high-temperature conditions. For example, it can undergo halogenation to form products like dichloroethane (C2H4Cl2) in the presence of chlorine gas.

Why the other options are wrong
  • B. Propylene is more likely to undergo addition reactions rather than substitution reactions due to its unsaturated nature. It can undergo reactions like hydrogenation to form propane.
  • C. Same as option A, ethylene can undergo substitution reactions.
  • D. Ethane is unlikely to undergo substitution reactions due to its saturated nature. It is more stable and tends to undergo reactions like combustion or halogenation to form products like chloroethane (C2H5Cl) rather than substitution products.

Q11. All the C-C bond length in benzene is equal to?

  • A. 1.54 A
  • B. 1.19 A
  • C. 1.34 A
  • D. 1.20 A

Explanation: This is the correct answer. In benzene, all C-C bond lengths are equal and are approximately 1.40 Å due to the delocalization of π-electrons in the aromatic ring.

Why the other options are wrong
  • A. This value is incorrect for benzene. It is too long for the C-C bond length in benzene, where all bond lengths are equal and shorter than 1.45 Å.
  • B. This value is incorrect for benzene. It is too short for the C-C bond length in benzene, where all bond lengths are equal and longer than 1.19 Å.
  • C. This value is incorrect for benzene. It is close to the typical C-C single bond length but not applicable to benzene, where all bond lengths are equal and shorter than 1.34 Å.

Q12. The reaction is called:

  • A. Acylation
  • B. Alkylation
  • C. Tertiary alcohol
  • D. None of these

Explanation: Alkylation involves adding an alkyl group to a molecule. It is a common reaction in organic chemistry.

Why the other options are wrong
  • A. Acylation is the process of adding an acyl group to a compound. It is different from alkylation, which involves adding an alkyl group.
  • C. This option is unrelated to the given question. Tertiary alcohol refers to a specific type of alcohol where the carbon atom bearing the hydroxyl group is bonded to three other carbon atoms.
  • D. This is incorrect because alkylation is the appropriate term for the described reaction, where an alkyl group is added to a molecule.

Q13. Grignard Reagent reacts with ketones and produces:

  • A. Primary Alcohol
  • B. Secondary Alcohol
  • C. Tertiary Alcohol
  • D. None of these

Explanation: When a Grignard reagent reacts with a ketone, it adds to the carbonyl carbon, leading to the formation of a tertiary alcohol.

Why the other options are wrong
  • A. A Grignard reagent reacting with a ketone does not produce a primary alcohol. Thus, this option is incorrect.
  • B. This is incorrect. A Grignard reagent reacting with a ketone does not produce a secondary alcohol.
  • D. This is incorrect. The reaction between a Grignard reagent and a ketone results in the formation of a tertiary alcohol.

Q14. Formaldehyde polymerizes to:

  • A. 0 formaldehyde
  • B. m-formaldehyde
  • C. Paraldehyde
  • D. None of these

Explanation: Paraldehyde is a cyclic trimer of formaldehyde, formed when formaldehyde undergoes polymerization. It is a liquid at room temperature and is used in some medical applications as a sedative and anticonvulsant.

Why the other options are wrong
  • A. This option is incorrect. Formaldehyde does not polymerize to form "0 formaldehyde." Instead, it can undergo polymerization reactions to form various products.
  • B. This option is incorrect. "m-formaldehyde" is not a recognized compound or product of formaldehyde polymerization.
  • D. This option is incorrect because formaldehyde can indeed polymerize to form paraldehyde.

Q15. Taj Mahal, a monument in Agra is suffering from?

  • A. Stone cancer
  • B. Earthquakes
  • C. Land depression
  • D. Nuisance

Explanation: The Taj Mahal is facing issues related to land subsidence or land depression. Due to excessive groundwater extraction in the region, the ground beneath the monument is gradually sinking. This subsidence can lead to structural instability and damage to the Taj Mahal over time.

Why the other options are wrong
  • A. Stone cancer, or marble cancer, refers to the deterioration of stones, particularly marble, due to environmental factors like pollution and acid rain. While this is a known issue affecting many historic structures, including the Taj Mahal, it is not the specific problem referred to in this context.
  • B. Earthquakes are not a significant concern for the Taj Mahal. While India is seismically active, the Taj Mahal has stood for centuries without major damage from earthquakes. It is not currently at risk from seismic activity.
  • D. Nuisance typically refers to minor annoyances or inconveniences. While there may be various nuisances around the Taj Mahal, such as crowds or pollution, these are not the primary issues affecting the monument's preservation.

Q16. Sulphur dioxide is responsible for the formation of?

  • A. Greenhouse effect
  • B. Global warming
  • C. Ozone depletion
  • D. Acid rain

Explanation: This is the correct answer. Sulfur dioxide reacts with water vapor and other chemicals in the atmosphere to form sulfuric acid (H2SO4), a major component of acid rain. Acid rain can have harmful effects on the environment, including damage to forests, aquatic ecosystems, and buildings.

Why the other options are wrong
  • A. Sulfur dioxide itself is not a significant contributor to the greenhouse effect. The greenhouse effect is primarily caused by gases like carbon dioxide (CO2), methane (CH4), and water vapor trapping heat in the Earth's atmosphere.
  • B. While sulfur dioxide can contribute to localized warming near the source of emissions, it is not a major greenhouse gas like CO2. Global warming is primarily driven by the accumulation of greenhouse gases in the atmosphere, particularly CO2 from human activities like burning fossil fuels.
  • C. Sulfur dioxide is not responsible for ozone depletion. Ozone depletion is primarily caused by chlorofluorocarbons (CFCs) and other halogenated compounds that release chlorine and bromine into the stratosphere, where they catalytically destroy ozone molecules.

Q17. Metallic oxides are?

  • A. Acidic
  • B. Basic
  • C. Neutral
  • D. None of these

Explanation: Metallic oxides are generally basic because they react with acids to form salts and water. They often show properties of bases, such as turning red litmus paper blue.

Why the other options are wrong
  • A. Metallic oxides are not acidic. Acidic oxides typically contain nonmetals and react with bases to form salts and water.
  • C. Metallic oxides are not neutral. Neutral oxides neither react with acids nor bases under normal conditions.
  • D. This is incorrect because metallic oxides are known for their basic properties, making option B the correct choice.

Q18. Polystyrene is:

  • A. Polystearic acid
  • B. Polyvinyl benzene
  • C. Polyvinyl toulene
  • D. Polyvinyl xylene

Explanation: Polystyrene is a synthetic aromatic polymer made from the monomer styrene. The correct chemical name for polystyrene is polyvinyl benzene, as it is a polymer of the vinyl group (-CH=CH2) attached to a benzene ring.

Why the other options are wrong
  • A. Polystearic acid would be a polymer of stearic acid, which is a fatty acid, not related to polystyrene.
  • C. While toluene is similar to benzene, it has a methyl group (-CH3) attached to the benzene ring. Polyvinyl toluene would refer to a polymer made from styrene (vinyl benzene) with a methyl group attached, which is not polystyrene.
  • D. Xylene is a compound similar to benzene but with two methyl groups attached to the benzene ring. Polyvinyl xylene would refer to a polymer made from a vinyl group attached to a xylene ring, which is not polystyrene.

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