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Punjab Chemistry 2015 Paper 1 — Solved Past Paper with Answers

All 17 MCQs from Punjab Chemistry 2015 Paper 1, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT Punjab / UHS past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all Punjab / UHS papers.

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Q1. Which one is an incomplete period?

  • A. 4th
  • B. 5th
  • C. 6th
  • D. 7th

Explanation: The period 7 is incomplete so far. It contains only two normal elements 87Fr and 88Ra, ten transition elements and fourteen inner transition elements. The inner transition elements of this period are called Actinides, as they follow 89Ac.The actinides are also shown at the bottom of the periodic table under the Lanthanides. Due to their scarcity, the inner transition elements are also called rare earth elements.

Q2. The Oxides of Beryllium are:

  • A. Acidic
  • B. Basic
  • C. amphoteric
  • D. azeotropic

Explanation: The oxides of alkali and alkaline earth metals except beryllium are basic and contain O2- ions. The O2- ion has high affinity for proton and cannot exist alone in an aqueous solution. Therefore, it immediately takes proton from water and forms OH- ion. Oxides of relatively less electropositive elements, such as BeO, Al2O3 , Bi2O3 and ZnO are amphoteric and behave as acids towards strong bases and as bases towards strong acids.

Q3. Which metal is used in thermite process because of its activity?

  • A. Iron
  • B. Aluminium
  • C. Copper
  • D. Zinc

Explanation: The metal typically used in the thermite process due to its high activity is aluminum (Al). In the thermite reaction, aluminum acts as the reducing agent, providing the necessary electrons to reduce another metal oxide, usually iron(III) oxide (Fe2O3), resulting in the production of elemental iron and aluminum oxide (Al2O3). This reaction is highly exothermic and is often used for welding and metallurgical purposes. The high reactivity of aluminum makes it suitable for this process.

Q4. The most electronegative element of group V–A is:

  • A. N
  • B. P
  • C. Sb
  • D. Bi

Explanation: Nitrogen has the highest electronegativity in group VA because the electronegative character decreases down the group.

Q5. Alpha decay of the Radium gives:

  • A. Neon
  • B. Argon
  • C. Xenon
  • D. Radon

Explanation: Radon is the a-decay product of the radium. Radon is present to a very small extent in the atmosphere and it could be obtained as a by-product from the liquefaction of air.

Q6. Which of the following is a typical transition metal?

  • A. Sc
  • B. Y
  • C. Co
  • D. Ra

Explanation: Group IIB elements (Zn, Cd and Hg) do not have a partially filled d-subshell either as elements or in any of their ionic state. Neither do they show typical properties of transition elements to any appreciable extent (except complex formation). Similarly, IIIB (Sc, Y and La) is another group of elements which do not show many of the properties associated with typical transition elements.

Q7. Which one is the heterocyclic compound of oxygen?

  • A. Pyrridine
  • B. Pyrrole
  • C. Furan
  • D. Thiophene

Explanation: The compounds in which the ring consists of atoms of more than one kind are called heterocyclic compounds or heterocycles. In heterocyclic compounds generally one or more atoms of elements such as nitrogen (Pyridine), oxygen (Furan) or sulphur (Thiophene) are present. The atom other than carbon viz, N, 0, or S, present in the ring is called a hetero atom.

Q8. Preparation of vegetable ghee involves:

  • A. Halogenation
  • B. Hydrogenation
  • C. Hydroxylation
  • D. Dehydrogenation

Explanation: Hydrogenation of alkenes or alkynes in the presence of nickel at 200-300*C yields alkanes. The hydrogenation can also be carried out with platinum or palladium at room temperature but they are expensive than nickel. The method is of industrial importance. Production of vegetable ghee by the catalytic hydrogenation of vegetable oil (unsaturated fatty acids) is an example of the application of this method on industrial scale.

Why the other options are wrong
  • A. Halogenation of hydrocarbons produce alkyl halides.
  • C. Hydroxylation is the addition of cold alkaline KMnO4 solution. It produces vicinal glycols with alkenes.
  • D. Dehydrogenation is elimination of hydrogen to produce unsaturated hydrocarbons.

Q9. Which compound is the most reactive one?

  • A. Benzene
  • B. Ethyne
  • C. Ethene
  • D. Ethane

Explanation: The unreactivity of alkanes can also be explained on the basis of inertness of a s-bond. In a s -bond the electrons are very tightly held between the nuclei which makes it a very stable bond. A lot of energy is required to break it. A pi-bond is, therefore, a weak bond as compared to a s-bond. During a reaction it breaks comparatively easily rendering alkenes as reactive group of compounds. In alkynes, the carbon atoms are held together by a triple bond, a s-bond and two p-bonds. The electron density between the carbon atoms is very high which draws atoms very close to each other. Electrons in a triple bond are, therefore, less exposed and thus less reactive towards electrophilic reagents.Order of reactivity:Alkenes>ALkynes>Benzene>Alkanes

Q10. Which one of the following is not a nucleophile?

  • A. H2O
  • B. BF3
  • C. NH3
  • D. H2S

Explanation: Nucleophile means nucleus loving. It has an unshared electron pair available for bonding and in most cases it is basic in character. It may be negatively charged or neutral.BF3 is electron deficient and hence is an electrophile.

Q11. Which one is a dihydric alcohol?

  • A. Ethanol
  • B. Cyclohexane
  • C. Glycerol
  • D. Glycol

Explanation: Alcohols are classified into monohydric and polyhydric alcohols. Monohydric alcohols contain one -OH group while polyhydric alcohols may contain two, three or more OH groups and named as dihydric or trihydric alcohols, etc. Glycol has two hydroxyl groups so it is dihydric alcohol.

Q12. Which of the following will react with both aldehydes and ketones?

  • A. Grignard's reagent
  • B. Tollen’s reagent
  • C. Fehling'’s reagent
  • D. Benedict's reagent

Explanation: Tollen's reagent, Benedict's reagent and Fehling's reagent react only with aldehydes whereas Grignard reagent reacts with both aldehydes and ketones to yield primary and secondary alcohols respectively.

Q13. Ketones are prepared by the oxidation of:

  • A. Primary alcohol
  • B. Secondary alcohol
  • C. Tertiary alcohol
  • D. Quarternary alcohol

Explanation: Primary alcohols on oxidation form aldehydes whereas secondary alcohols on oxidation form ketones. Tertiary alcohols are resistant towards oxidation and instead yield alkenes upon oxidation.

Q14. Which of the following is not a fatty acid?

  • A. Propanoic acid
  • B. acetic acid
  • C. Phthalic acid
  • D. Butanoic acid

Explanation: The aliphatic monocarboxylic acids are commonly called fatty acids because higher members of this series such as palmitic acid and stearic acid etc. are obtained by the hydrolysis of fats and oils. Phthalic acid is an aromatic carboxylic acid hence it is not classified as fatty acid.

Q15. Which one is a disaccharide?

  • A. Glucose
  • B. Sucrose
  • C. Fructose
  • D. Cellulose

Explanation: Glucose and fructose are monosaccharides. Starch and cellulose are polysaccharides.Sucrose is a disaccharide.

Q16. Ammonium nitrate fertilizer is not used for which crop?

  • A. Cotton
  • B. Wheat
  • C. Paddy rice
  • D. Sugarcane

Explanation: It is a useful fertilizer for many crops except paddy rice because the microbial bacteria in flooded fields decomposes it to nitrogen gas. It is also used in combination with limestone. It is hygroscopic in nature.

Q17. Which are carcinogenic class of compounds?

  • A. Dioxins
  • B. Lower alkanes
  • C. Fatty acids
  • D. Proteins

Explanation: Dioxins are a group of highly toxic and persistent organic pollutants that can be formed as byproducts of various industrial processes, including waste incineration, chemical manufacturing, and certain combustion processes.

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