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Punjab Chemistry 2019 — Solved Past Paper with Answers
All 17 MCQs from Punjab Chemistry 2019, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT Punjab / UHS past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all Punjab / UHS papers.
Attempt this paper interactively →Q1. For which mechanism, the first step involved is the same?
- A. E1 and E2
- B. E2 and S,2
- C. S,1 and E2
- D. E1 and S,1✓
Explanation: E1: Leaving group departure followed by carbocation formation and deprotonation.S,1: Leaving group departure followed by nucleophilic attack.
Why the other options are wrong
- A. E1: Formation of carbocation followed by deprotonation.E2: Simultaneous deprotonation and leaving group departure.
- B. E2: Simultaneous deprotonation and leaving group departure. S,2: Simultaneous nucleophilic attack and leaving group departure.
- C. S,1: Leaving group departure followed by nucleophilic attack.E2: Simultaneous deprotonation and leaving group departure.
Q2. Ethanol can be converted into ethanoic acid by:
- A. Hydrogenation
- B. Hydration
- C. Oxidation✓
- D. Fermentation
Explanation: Ethanol can be oxidized to form ethanoic acid. This process typically involves the use of an oxidizing agent such as potassium dichromate (K2Cr2O7) or potassium permanganate (KMnO4) in the presence of an acidic medium.
Why the other options are wrong
- A. This process involves the addition of hydrogen to a compound. It is used to convert unsaturated compounds into saturated compounds, but it does not convert ethanol into ethanoic acid.
- B. Hydration involves the addition of water to a compound. While it can convert some compounds into acids, it does not specifically convert ethanol into ethanoic acid.
- D. Fermentation is the process by which yeast or bacteria convert sugars into alcohol and carbon dioxide. While fermentation produces ethanol from sugars, it does not directly convert ethanol into ethanoic acid.
Q3. The carbon atom of a carbonyl group is:
- A. sp hybridized
- B. sp2 hybridized✓
- C. sp3 hybridized
- D. None of these
Explanation: Organic compounds containing the carbonyl functional group, are called carbonyl compounds. In a carbonyl group, a carbon atom is bonded to oxygen with a double bond. It is sp2 hybridized.
Why the other options are wrong
- A. It has 2 sigma and 2 pi bond
- C. It has 4 sigma bond
Q4. Which reagent is used to reduce carboxylic group to alcoholic group?
- A. H2 / Ni
- B. H2 / Pt
- C. H2 / Fe
- D. LiAlH4✓
Explanation: Lithium aluminum hydride is a powerful reducing agent commonly used to reduce carboxylic acids (and their derivatives) to alcohols.
Why the other options are wrong
- A. This reagent is typically used for the reduction of alkenes or alkynes, not carboxylic acids.
- B. This reagent is commonly used for the reduction of alkenes or alkynes, not carboxylic acids.
- C. This combination is not commonly used for the reduction of carboxylic acids. H2/Fe is more commonly used in the reduction of nitro compounds to amines.
Q5. Which one of the following polymers is an addition polymer?
- A. Nylon-6,6
- B. Polystyrene✓
- C. Terylene
- D. Epoxy resin
Explanation: Polystyrene is indeed an addition polymer. It's formed through the addition polymerization of styrene monomers, where the double bond in styrene opens up and links with other styrene molecules.
Why the other options are wrong
- A. Nylon-6,6 is a condensation polymer formed by the condensation reaction between adipoyl chloride and hexamethylene diamine. It doesn't fall under addition polymerization.
- C. Terylene is a condensation polymer formed by the reaction between ethylene glycol and terephthalic acid. So, it's not an addition polymer.
- D. Epoxy resin is not an addition polymer either. It's a thermosetting polymer formed through a reaction between epoxide groups and a curing agent, often amines or acids.
Q6. Micronutrients are required in quantity ranging from:
- A. 4-40 gm
- B. 6-200 kg
- C. 6-200 gm✓
- D. 4-40 kg
Explanation: This range is more reasonable, but still, it's on the higher side. Micronutrients are generally required in smaller quantities.
Why the other options are wrong
- A. This range seems too small for micronutrients. Most micronutrients are required in much smaller quantities.
- B. This range is too large. Micronutrients are needed in very small amounts, typically measured in milligrams or micrograms, not kilograms.
- D. This range is far too large. Again, micronutrients are needed in very small amounts, not kilograms.
Q7. Peroxyacetylnitrate (PAN) is an irritant to human beings and it affects:
- A. Eyes
- B. Ears
- C. Stomach
- D. Nose✓
Explanation: PAN exposure can irritate the nasal passages, causing symptoms such as nasal congestion, runny nose, and irritation.
Why the other options are wrong
- A. PAN exposure can cause irritation to the eyes, leading to symptoms such as redness, tearing, and burning sensation.
- B. PAN typically does not directly affect the ears. Its primary irritant effects are on mucous membranes and respiratory tissues rather than the ears.
- C. While PAN can cause respiratory irritation, it is not typically associated with direct effects on the stomach.
Q8. Newspaper can be recycled again and again by how many times?
- A. 2
- B. 3
- C. 4
- D. 5✓
Explanation: 5 is correct because newspaper can typically be recycled about 5 to 7 times before the fibers become too short and weak to be used again in high-quality paper products. After multiple recycling cycles, the fibers become too degraded to be effectively reprocessed into new paper, so they are often used for lower-grade paper products or other materials.
Why the other options are wrong
- A. 2 is incorrect because newspaper can typically be recycled more than twice before the fibers degrade significantly.
- B. 3 is incorrect because newspaper can typically be recycled more than three times before the fibers degrade significantly.
- C. 4 is incorrect because newspaper can typically be recycled more than four times before the fibers degrade significantly.
Q9. Keeping in view the size of atoms, which order is the correct one:
- A. Mg > Sr
- B. Ba > Mg✓
- C. Lu > Ce
- D. Cl > I
Explanation: Ba and magnsium are in same group . Ba comes after Mg it means it has more shell so it has large atomic sizeAtomic Radius:Atoms are so small that it is impossible to see an atom even with a powerful optical microscope. The size of a single atom therefore cannot be directly measured. However, techniques have been developed which can measure the distance between the centres of two bonded atoms of any element. Half of this distance is considered to be the radius of the atom. In the periodic table, the atomic radius increases from top to bottom within a group due to increase in atomic number . This is because of the addition of an extra shell of electrons in each period. In a period, however, as the atomic number increases from left to right, the atomic radius decreases . This gradual decrease in the radius is due to increase in the positive charge in the nucleus . As the positive nuclear charge increases, the negatively charged electrons in the shells are pulled closer to the nucleus. Thus, the size of the outermost shell becomes gradually smaller. This effect is quite remarkable in the elements of longer periods in which “d” and “f ” subshells are involved. For example, the gradual reduction in the size of Lanthanides is significant and called Lanthanide Contraction.
Why the other options are wrong
- A. Mg has less number of shell then Sr so it is smaller in size
- C. Lu has less number of shell then Ce so it is smaller in size
- D. Cl has less number of shell then I so it is smaller in size
Q10. Tincal is a mineral of:
- A. Al
- B. B✓
- C. Si
- D. C
Explanation: Borax is the sodium salt of tetraboric acid. It is the most important of all borates .Borax occurs as a natural deposit called tincal in the dried up lakes of Tibet and California.Borax may also be obtained from tincal (Na2B4O7.10H2O) by treating tincalwith water and subsequently evaporating the clear solution, when crystalsof borax separate out.
Why the other options are wrong
- A. It is not a mineral of Al
- C. It is not a mineral of Si
- D. It is not a mineral of carbon
Q11. Laughing gas is chemically:
- A. NO
- B. N2O✓
- C. NO2
- D. N2O4
Explanation: Nitrous oxide, commonly known as laughing gas or happy gas, is a colorless, non-flammable gas. This gas is used in medical and dental procedures as a sedative. It helps to relieve anxiety before the procedure and allow the patient to relax
Why the other options are wrong
- A. Nitrous oxide, commonly known as laughing gas or happy gas, is a colorless, non-flammable gas. This gas is used in medical and dental procedures as a sedative. It helps to relieve anxiety before the procedure and allow the patient to relax
- C. Nitrous oxide, commonly known as laughing gas or happy gas, is a colorless, non-flammable gas. This gas is used in medical and dental procedures as a sedative. It helps to relieve anxiety before the procedure and allow the patient to relax
- D. Nitrous oxide, commonly known as laughing gas or happy gas, is a colorless, non-flammable gas. This gas is used in medical and dental procedures as a sedative. It helps to relieve anxiety before the procedure and allow the patient to relax
Q12. Which one of the following hydrogen halides is the weakest acid in aqueous solution?
- A. HF✓
- B. HCI
- C. HBr
- D. HI
Explanation: Hydrofluoric acid (HF) is the weakest acid among the hydrogen halides. This is because fluorine is the most electronegative element among the halogens, resulting in a strong hydrogen-fluorine bond that is less likely to dissociate in aqueous solution, making HF a weaker acid.
Why the other options are wrong
- B. Hydrochloric acid (HCl) is stronger than HF. Chlorine is less electronegative than fluorine, so the hydrogen-chlorine bond is weaker, making HCl a stronger acid than HF.
- C. Hydrobromic acid (HBr) is stronger than both HF and HCl. Bromine is less electronegative than chlorine, so the hydrogen-bromine bond is weaker, making HBr a stronger acid than both HF and HCl.
- D. Hydroiodic acid (HI) is the strongest acid among the hydrogen halides. Iodine is the least electronegative halogen, so the hydrogen-iodine bond is the weakest among the hydrogen halides, making HI the strongest acid.
Q13. Which one of the following sulphate is insoluble in water?
- A. Sodium sulphate
- B. Potassium sulphate
- C. Zinc sulphate
- D. Barium sulphate✓
Explanation: Barium sulphate is insoluble in water. It forms a white precipitate when mixed with water due to its low solubility. Unlike the other options, barium sulphate does not dissociate into ions when mixed with water, leading to its insolubility.
Why the other options are wrong
- A. Sodium sulphate is a white, crystalline solid that is highly soluble in water. When dissolved in water, it dissociates into sodium ions (Na+) and sulphate ions (SO42-), allowing it to dissolve completely.
- B. Potassium sulphate is a salt that is also highly soluble in water. Like sodium sulphate, it dissociates into potassium ions (K+) and sulphate ions (SO42-) when dissolved in water, resulting in complete dissolution.
- C. Zinc sulphate is a chemical compound that is soluble in water, but it is less soluble compared to sodium and potassium sulphate. However, it is still considered soluble under normal conditions. It dissociates into zinc ions (Zn2+) and sulphate ions (SO42-) when dissolved in water.
Q14. Which one of the following is a typical transition metal?
- A. Sc
- B. Y
- C. Co✓
- D. Ra
Explanation: Cobalt is a well-known transition metal with a variety of applications. It's used in the production of magnetic materials, rechargeable batteries, and as a catalyst in chemical reactions.
Why the other options are wrong
- A. Scandium is a transition metal, but it's not as commonly used or encountered as some other transition metals. It has applications in aerospace alloys and high-intensity lights.
- B. Yttrium is also a transition metal, although it's less well-known compared to some other transition metals. It's used in various technologies such as superconductors, lasers, and phosphors for color television tubes.
- D. Radium is not a transition metal; it's an alkaline earth metal. It's highly radioactive and has limited practical applications, primarily in the past for luminous paint and medical treatments, but its use has decreased due to its radioactive nature and associated health risks.
Q15. Which set of hybrid orbital has planar triangular shape?
- A. sp
- B. sp2✓
- C. sp3
- D. dsp2
Explanation: This hybridization involves one s orbital and two p orbitals, resulting in three hybrid orbitals. These orbitals are arranged in a trigonal planar geometry, forming a planar triangular shape.
Why the other options are wrong
- A. This hybridization involves one s orbital and one p orbital, resulting in two hybrid orbitals. These orbitals are linearly arranged, not planar triangular.
- C. This hybridization involves one s orbital and three p orbitals, resulting in four hybrid orbitals. These orbitals are arranged in a tetrahedral geometry, not planar triangular.
- D. This notation is not conventional for hybrid orbitals. The "d" usually refers to a d orbital, which is not involved in standard hybridization schemes like sp, sp2, or sp3.
Q16. Formula of chloroform is:
- A. CH3Cl
- B. CCl4
- C. CH2Cl2
- D. CHCl3✓
Explanation: CH3Cl is chloromethane.CH2Cl2 is dichloromethane.CHCl3 is trichloromethane (chloroform).CCL4 is tetrachloromethane (Carbon Tetrachloride).
Q17. During nitration of benzene, the active nitrating agent is:
- A. NO3
- B. NO+2✓
- C. NO2
- D. HNO3
Explanation: Nitration of benzene: Nitric acid and sulfuric acid used in nitration generate nitronium NO2+ ions as electrophiles. Nitronium NO2+ is the nitrating agent.
Why the other options are wrong
- A. Nitration of benzene: Nitric acid and sulfuric acid used in nitration generate nitronium NO2+ ions as electrophiles. Nitronium NO2+ is the nitrating agent.
- C. Nitration of benzene: Nitric acid and sulfuric acid used in nitration generate nitronium NO2+ ions as electrophiles. Nitronium NO2+ is the nitrating agent.
- D. Nitration of benzene: Nitric acid and sulfuric acid used in nitration generate nitronium NO2+ ions as electrophiles. Nitronium NO2+ is the nitrating agent.
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