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Punjab Chemistry 2022 Paper 2 — Solved Past Paper with Answers

All 17 MCQs from Punjab Chemistry 2022 Paper 2, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT Punjab / UHS past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all Punjab / UHS papers.

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Q1. Which catalyst is used in contact process?

  • A. Fe2O3
  • B. SO3
  • C. V2O5
  • D. Ag2O

Explanation: The Contact Process involves the oxidation of sulfur dioxide (SO2) to sulfur trioxide (SO3), which is then used to produce sulfuric acid.SO2 obtained by burning sulphur or iron pyrites is oxidized to SO3 in the presence of V2O5 which acts as a catalyst.

Why the other options are wrong
  • A. This option is incorrect because it is not the catalyst used in the contact process. Iron catalysts are used in other processes, such as the Haber process for ammonia synthesis.
  • B. This option is incorrect because it is not a catalyst but rather one of the reactants in the contact process.
  • D. This option is incorrect because it is not the catalyst used in the contact process. Silver catalysts are used in other processes, such as the production of ethylene oxide.

Q2. Chlorine heptaoxide Cl2O1 reacts with water to form:

  • A. Hypochlorous acid
  • B. Perchloric acid
  • C. Chloric acid
  • D. Chlorine and oxygen

Explanation: Chlorine heptoxide reacts vigorously with water to form perchloric acid (HClO4) and hydrochloric acid (HCl).

Why the other options are wrong
  • A. Hypochlorous acid (HClO) is incorrect because it is not the product of the reaction of chlorine heptoxide with water.
  • C. Chloric acid (HClO3) is incorrect because it is not the product of the reaction of chlorine heptoxide with water.
  • D. Chlorine and oxygen are incorrect because they are not the products of the reaction of chlorine heptoxide with water.

Q3. Group VI B of transition elements contains:

  • A. Zn, Cd, Hg
  • B. Fe, Fu, Os
  • C. Cr, Mo, W
  • D. Mn, Te, Re

Explanation: Chromium (Cr), molybdenum (Mo), and tungsten (W) belong to Group VI B of transition elements. These elements are known for their characteristic chemistry and properties, such as forming colored compounds and exhibiting multiple oxidation states.

Why the other options are wrong
  • A. This group consists of zinc (Zn), cadmium (Cd), and mercury (Hg), which belong to Group 12 of the periodic table. These elements are not part of Group VI B of transition elements.
  • B. "Fu" is not a recognized chemical element. The elements iron (Fe) and osmium (Os) belong to Group VIII B (8) and Group VIII A (8) respectively, not Group VI B of transition elements.
  • D. Manganese (Mn), tellurium (Te), and rhenium (Re) do not belong to Group VI B of transition elements. Manganese is in Group VII B (7), tellurium is a metalloid in Group XVI (16), and rhenium is in Group VIII B (8).

Q4. The chemist who synthesized urea from ammonium cyanate was:

  • A. G.N. Lewis
  • B. Fredrick Wohler
  • C. Kolbe
  • D. Berzelius

Explanation: In 1828, he synthesized urea from ammonium cyanate, thereby disproving the theory of vitalism, which held that organic compounds could only be synthesized by living organisms. This experiment laid the foundation for organic chemistry

Why the other options are wrong
  • A. Gilbert N. Lewis was an American physical chemist known for his discovery of the covalent bond and his concept of electron pairs. He did not synthesize urea from ammonium cyana
  • C. Adolph Wilhelm Hermann Kolbe was a German chemist known for his work in organic chemistry, particularly for the synthesis of organic compounds. However, he did not synthesize urea from ammonium cyanate.
  • D. Jöns Jacob Berzelius was a Swedish chemist known for his development of the modern system of chemical symbols and his early research on chemical composition. However, he did not synthesize urea from ammonium cyanate.

Q5. Vinyl acetylene combines with HCl to form:

  • A. Polyacetylene
  • B. Benzene
  • C. Chloroprene
  • D. Divinylacetylene

Explanation: When acetylene is passed through an acidic solution of cuprous chloride and ammonium chloride and then allowed to stand for several hours at room temperature, vinyl acetylene and divinyl acetylene are obtained. If HCl is added to vinyl acetylene, chloroprene is obtained which readily polymerize to neoprene, used as synthetic rubber.

Q6. Aromatic compounds burn with sooty flame because:

  • A. They have high percentage of hydrogen
  • B. They have a ring structure
  • C. They have high percentage of carbon
  • D. They resist reaction with air

Explanation: The aromatic compound displays aromaticity. They burn with a strong sooty yellow flame. A "sooty flame" indicates that incomplete combustion is occurring and the reason for this flame is the high percentage of carbon content. The carbon-hydrogen ratio is high in aromatic compounds.

Why the other options are wrong
  • A. The aromatic compound displays aromaticity. They burn with a strong sooty yellow flame. A "sooty flame" indicates that incomplete combustion is occurring and the reason for this flame is the high percentage of carbon content. The carbon-hydrogen ratio is high in aromatic compounds.
  • B. The aromatic compound displays aromaticity. They burn with a strong sooty yellow flame. A "sooty flame" indicates that incomplete combustion is occurring and the reason for this flame is the high percentage of carbon content. The carbon-hydrogen ratio is high in aromatic compounds.
  • D. The aromatic compound displays aromaticity. They burn with a strong sooty yellow flame. A "sooty flame" indicates that incomplete combustion is occurring and the reason for this flame is the high percentage of carbon content. The carbon-hydrogen ratio is high in aromatic compounds.

Q7. Elimination bimolecular reactions involve:

  • A. First order kinetics
  • B. Second order kinetics
  • C. Third order kinetics
  • D. Zero order kinetics

Explanation: :Kinetic studies of the reactions involving E2 mechanism have shownthat the rates of such reactions depend upon the concentrations of alkylhalide as well as the attacking nucleophile. Mathematically, the ratecan be expressed as:Rate = k [Alkyl halide][Nucleophile]In E2 MECHANISM there is only one step so it is bimolecular

Why the other options are wrong
  • A. E1 which has unimolecular is first order kinetics
  • C. Wrong

Q8. Which compound will have the maximum repulsion with H2O?

  • A. C6H6
  • B. CH3CH2CH2OH
  • C. C2H5OH
  • D. CH3 - O - CH3

Explanation: Benzene (C6H6) will have the maximum repulsion with H2O because benzene is nonpolar and does not readily interact with polar molecules like water. The benzene ring has a symmetrical, planar structure with delocalized pi-electrons, making it non-reactive and unable to form strong hydrogen bonds with water molecules.

Why the other options are wrong
  • B. 1-Propanol has a polar -OH group that can interact with water molecules through hydrogen bonding. However, the presence of the hydrocarbon chain allows for some degree of solubility in water, reducing the repulsion compared to benzene.
  • C. Ethanol also has a polar -OH group that can form hydrogen bonds with water molecules. However, like 1-propanol, the hydrocarbon chain in ethanol allows for some solubility in water, reducing the repulsion compared to benzene.
  • D. Dimethyl ether has an oxygen atom that can interact with water molecules through hydrogen bonding. However, the molecule is more polar than benzene, and the absence of a hydrocarbon chain reduces its repulsion compared to benzene.

Q9. Which of the following reagents will react with both aldehydes and ketones?

  • A. Grignard reagent
  • B. Fehling's reagent
  • C. Tollen's reagent
  • D. Benedict's reagent

Explanation: Grignard reagent (RMgX, where R is an alkyl or aryl group and X is a halogen) can react with both aldehydes and ketones to form alcohols. This reaction is known as a Grignard reaction and involves the nucleophilic addition of the Grignard reagent to the carbonyl group of the aldehyde or ketone, followed by protonation to give the alcohol.

Why the other options are wrong
  • B. Fehling's reagent is used to test for the presence of reducing sugars, such as aldoses (which include some aldehydes) but not ketones. It consists of two separate solutions, Fehling's A (copper(II) sulfate) and Fehling's B (sodium potassium tartrate in sodium hydroxide solution), which are mixed before use.
  • C. Tollen's reagent, also known as silver mirror test, is used to distinguish between aldehydes and ketones. It reacts with aldehydes to form a silver mirror but does not react with ketones under normal conditions.
  • D. Benedict's reagent is also used to test for the presence of reducing sugars, particularly in the detection of glucose in urine. It consists of copper(II) sulfate, sodium citrate, and sodium carbonate. Similar to Fehling's reagent, it can react with aldoses (some aldehydes) but not with ketones under normal conditions.

Q10. The solution of which acid is used for seasoning of food?

  • A. Formic acid
  • B. Acetic acid
  • C. Benzoic acid
  • D. Butanoic acid

Explanation: Acetic acid is correct because it is commonly used for seasoning food. Acetic acid, also known as vinegar when diluted, is a weak acid that adds a sour flavor to foods and is widely used in cooking and food preparation.

Why the other options are wrong
  • A. Acetic acid is correct because it is commonly used for seasoning food. Acetic acid, also known as vinegar when diluted, is a weak acid that adds a sour flavor to foods and is widely used in cooking and food preparation.
  • C. Benzoic acid is incorrect because it is primarily used as a preservative in food and is not commonly used for seasoning.
  • D. Butanoic acid is incorrect because it is not commonly used for seasoning food. It has a strong odor and is used more in the production of flavors and fragrances.

Q11. The fibre which is made from acrylonitrile as monomer?

  • A. PVC
  • B. Rayon fibre
  • C. Acrylic fibre
  • D. Polyester fibre

Explanation: These are closely related to the vinyl resins. The most important monomers of acrylic resins are methylmethacrylate, acrylic acid and butyl acrylate. The acrylic fibres are based largely on acrylonitrile. Acrylic resins are used in the manufacture of plastics, paints for car industry and water based weather resistant paints.

Why the other options are wrong
  • A. PVC (polyvinyl chloride) is incorrect because it is not made from acrylonitrile as a monomer. PVC is made from vinyl chloride monomers.
  • B. Rayon fiber is incorrect because it is not made from acrylonitrile as a monomer. Rayon is a regenerated cellulose fiber made from natural sources such as wood pulp.
  • D. Polyester fiber is incorrect because it is not made from acrylonitrile as a monomer. Polyester is a synthetic fiber made from ethylene glycol and terephthalic acid.

Q12. Which is not a calcarious material?

  • A. Lime
  • B. Clay
  • C. Marble
  • D. Marine Shell

Explanation: The important raw materials used for the manufacture of cement are:1. Calcarious material (limestone, marble, chalks, marine shell) as source of CaO.2. Argillaceous material (clay, shale, slate, blast furnace slag) They provide acidic components such as aluminates and silicates,3. Other raw material being used is gypsum.

Why the other options are wrong
  • A. Lime is incorrect because it is a calcareous material. Lime is calcium oxide (CaO), which can be produced by heating limestone (calcium carbonate).
  • C. Marble is incorrect because it is a calcareous material. Marble is a metamorphic rock composed of recrystallized carbonate minerals, usually calcite or dolomite.
  • D. Marine shell is incorrect because it is also a calcareous material. Marine shells, such as those from mollusks, are composed primarily of calcium carbonate.

Q13. Newspaper can be recycled again and again by how many times?

  • A. 2
  • B. 3
  • C. 4
  • D. 5

Explanation: 5 is correct because newspaper can typically be recycled about 5 to 7 times before the fibers become too short and weak to be used again in high-quality paper products. After multiple recycling cycles, the fibers become too degraded to be effectively reprocessed into new paper, so they are often used for lower-grade paper products or other materials.

Why the other options are wrong
  • A. 2 is incorrect because newspaper can typically be recycled more than twice before the fibers degrade significantly.
  • B. 3 is incorrect because newspaper can typically be recycled more than three times before the fibers degrade significantly.
  • C. 4 is incorrect because newspaper can typically be recycled more than four times before the fibers degrade significantly.

Q14. The normal amount of overhead ozone is about:

  • A. 335 DU
  • B. 340 DU
  • C. 345 DU
  • D. 350 DU

Explanation: The amount of ozone in the atmosphere is expressed in Dobson units (DU). The normal amount of overhead ozone is about 350 DU.

Q15. Mark the correct statement:

  • A. Na+is smaller than Na
  • B. Na+is larger than Na
  • C. Cl- is smaller than Cl
  • D. Cl- ion and Cl are equal

Explanation: When a neutral atom loses one or more electrons, it becomes a positive ion. The size of the atom is decreased in this process because of two reasons. First, the removal of one or more electrons from a neutral atom usually results in the loss of the outermost shell. Second, the removal of electrons causes an imbalance in the proton-electron ratio. Due to the greater attraction of the nuclear charge, the remaining electrons of the ion are drawn closer to the nucleus. Thus, a positive ion is always smaller than the neutral atom from which it is derived. The radius of Na is 157 pm, and the radius of Na+ is 95 pm

Why the other options are wrong
  • B. Wrong
  • C. The anionic size is larger than atomic size
  • D. The anionic size is larger than atomic size

Q16. Chile saltpetre has the chemical formula:

  • A. NaNO3
  • B. KNO₂
  • C. Na2B4O7
  • D. Na2CO3.H2O

Explanation: NaNO3 is correct because Chile saltpetre, also known as sodium nitrate, has the chemical formula NaNO3. It is a naturally occurring mineral that is used in fertilizers, explosives, and food preservation.

Why the other options are wrong
  • B. KNO₂ is incorrect because it is the formula for potassium nitrite, not sodium nitrate.
  • C. Na2B4O7 is incorrect because it is the formula for borax, not sodium nitrate.
  • D. Na2CO3.H2O is incorrect because it is the formula for sodium carbonate monohydrate, not sodium nitrate.

Q17. Which of the following elements is not present abundantly in earth's crust?

  • A. Silicon
  • B. Aluminium
  • C. Sodium
  • D. Oxygen

Explanation: Sodium is correct because it is not present abundantly in Earth's crust compared to silicon, aluminium, and oxygen. Sodium is a relatively reactive alkali metal and is not a major component of the Earth's crust.

Why the other options are wrong
  • A. Silicon is incorrect because it is one of the most abundant elements in the Earth's crust, making up about 27.7% of the crust by mass.
  • B. Aluminium is incorrect because it is also abundant in the Earth's crust, making up about 8.1% of the crust by mass.
  • D. Oxygen is incorrect because it is the most abundant element in the Earth's crust, making up about 46.6% of the crust by mass.

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