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Uhs Mdcat 2019 — Solved Past Paper with Answers
All 200 MCQs from Uhs Mdcat 2019, solved with the correct answer highlighted and a full explanation for every question. This is a free MDCAT Punjab / UHS past paper — no signup, no ads. Practise it interactively in timed mode, drill more with free MDCAT MCQs, or browse all Punjab / UHS papers.
Attempt this paper interactively →Q1. The culpable child _ some words to her mother for pardoning his delinquency.
- A. Mumbled✓
- B. Showy
- C. Rude
- D. Crazy
Explanation: 'Mumbled' is to say something indistinctly and quietly, making it difficult for others to hear. So, the correct sentence is, "The culpable child mumbled some words to her mother for pardoning his delinquency."
Why the other options are wrong
- B. This option is not correct because 'showy' means to have a striking appearance or style, typically by being excessively bright, colorful, or ostentatious.
- C. This option is also incorrect because 'rude' means to be offensively impolite or bad-mannered.
- D. This option is also incorrect because 'crazy' means to be mad, especially manifested in wild or aggressive behavior.
Q2. She was feeling _ even after five hours of the surgery.
- A. Mumbled
- B. Haggard✓
- C. Pally
- D. Grope
Explanation: 'Haggard' means looking exhausted and unwell, especially from fatigue, worry, or suffering. So, the correct sentence is, "She was feeling haggard even after five hours of the surgery."
Why the other options are wrong
- A. This option is not correct because 'mumbled' means to say something indistinctly and quietly, making it difficult for others to hear.
- C. This option is also incorrect because 'pally' means having a close, friendly relationship.
- D. This option is also incorrect because 'grope' means to search blindly or uncertainly by feeling with the hands.
Q3. The parents were stunned when they saw that children had created complete _ in the bedroom.
- A. Knack
- B. Groggy
- C. Dank
- D. Mayhem✓
Explanation: 'Mayhem' means violent or extreme disorder; chaos. So, the correct sentence is, "The parents were stunned when they saw that children had created complete mayhem in the bedroom."
Why the other options are wrong
- A. 'Knack' is an acquired or natural skill at doing something, which does not fit in the context of the sentence.
- B. This option is also incorrect because 'groggy' means to be unsteady and shaky.
- C. This option is also incorrect because 'dank' refers to unpleasantly damp and cold.
Q4. I _ caution in interpreting these results.
- A. Urge✓
- B. Usher
- C. Usurp
- D. Uproot
Explanation: As a noun, 'urge' means a desire. As a verb, it means to strongly encourage. 'Urge' is related to the word, 'urgent' or 'pressing'. An 'urge' is a pressing want, one that is almost a compulsion, like when you're so frustrated, you have the urge to scream. If you urge someone to do something, you feel strongly about it.
Why the other options are wrong
- B. This option is not correct because 'usher' is a person who shows people to their seats.
- C. This option is also incorrect because 'usurp' means to take (a position of power or importance) illegally or by force.
- D. This option is also incorrect because 'uproot' means to move (someone) from their home or a familiar location.
Q5. They sometimes feel a _ for the mountains and the sea.
- A. Yearning✓
- B. Yapping
- C. Yelling
- D. Yielding
Explanation: 'Yearning' is a feeling of intense longing for something. Phrase: "He felt a yearning for the mountains".
Why the other options are wrong
- B. This option is not correct because 'yapping' means talking for a long time in an irritating manner.
- C. This option is also incorrect because 'yelling' means screaming in a very loud voice.
- D. This option is also incorrect because 'yielding' means giving a product or generating a financial return after a process.
Q6. The new teacher showed no _ about hitting the students.
- A. Quakes
- B. Qualms✓
- C. Quarrel
- D. Quotation
Explanation: 'Qualms' is an uneasy feeling of doubt, worry, or fear, especially about one's own conduct; a misgiving. Phrase: "Military regimes generally have no qualms about controlling the press." “Some people have no qualms about correcting other people's grammar."
Why the other options are wrong
- A. This option is not correct because 'quakes' means shakes or trembles.
- C. This option is also incorrect because 'quarrel' is a heated argument or disagreement between two parties.
- D. This option is also incorrect because 'quotations' are a group of words, taken from a text or speech and repeated by someone else.
Q7. The accident happened due to the driver’s _ .
- A. Negligence✓
- B. Reluctance
- C. Regret
- D. Quotation
Explanation: 'Negligence' is the failure to take proper care over something. Phrase: "His injury was due to the negligence of his employers."
Why the other options are wrong
- B. This option is not correct because 'reluctance' is the unwillingness or disinclination to do something.
- C. This option is also incorrect because 'regret' means to feel sad, repentant, or disappointed over something that one has done or failed to do so.
- D. This option is also incorrect because 'Quotation' are a group of words taken from a text or speech and repeated by someone.
Q8. In the following question, four alternative sentences are given. Choose the CORRECT option.
- A. I was been to America for a medical check up.
- B. I had being to America for a medical check up.
- C. I have been to America for a medical check up.✓
- D. I has been to America for a medical check up.
Explanation: This is an example of a Past Perfect tense sentence due to the presence of 'have' and 'been' implies an incident, that occurred in the past. The best way to solve this question is to read each option in your head and then decide which one sounds the best and fits in well.
Why the other options are wrong
- A. This option is not correct because "been" is reducdant when used with "was." The correct form should be "I went to America."
- B. This option is also incorrect because "had being" is an incorrect verb tense. The correct form should be "had been."
- D. This option is also incorrect because "has been" is the third person singular form, and "I" is the first person singular object. The correct form should be "have been."
Q9. In the following question, four alternative sentences are given. Choose the CORRECT option.
- A. After breaking the glass, Ruby said "Please don't tell on me".
- B. After breaking the glass Ruby said: "Please don't tell on me."
- C. After breaking the glass, Ruby said: "Please don't tell on me."✓
- D. After breaking the glass Ruby said: please don't tell on me.
Explanation: The sentence 'after breaking the glass' is another idea in the sentence hence a comma should be added between these two sentences. The rule of punctuation in quotation marks is that the full stop or comma should come within the quotation marks. 'Don't' is a contraction, which stands for 'do not'.
Why the other options are wrong
- A. This option is not correct because there should be a colon after "said" instead of a comma. A colon is used to introduce a list or an explanation, not spoken words.
- B. This option is also incorrect because there should be a comma after "glass" to separate the introductory clause from the rest of the sentence. Also, the spoken words should be enclosed in quotation marks.
- D. This option is also incorrect because there are no quotation marks around the spoken words.
Q10. In the following question, a sentence is given with blanks to be filled in with an appropriate word. Four alternatives are suggested. Choose the correct alternative, out of the four as your answer.Ravens appear to behave _, actively helping one another to find food.
- A. Mysteriously
- B. Warily
- C. Aggressively
- D. Defensively✓
Explanation: Option D is the correct answer because this sentence asks you to look for a word that describes how the ravens behave. The information after the comma restates and defines the meaning of the missing word.
Why the other options are wrong
- A. 'Mysteriously' means in a mysterious or puzzling manner, which does not fit in the context of the sentence.
- B. "Warily" means in a cautious or suspicious manner, which does not fit in the context of the sentence.
- C. Aggressively" means in a forceful or hostile manner, which is the opposite of what the sentence suggests.
Q11. The prince abdicated the crown and returned to his castle. Abdicated means:
- A. Gave up✓
- B. Sold
- C. Reinvested into
- D. Auctioned
Explanation: 'The word "abdicated" means to renounce or give up a high office or responsibility, such as a monarch giving up their crown.
Why the other options are wrong
- B. "Sold" means to exchange something for money, which does not fit in the context of the sentence.
- C. "Reinvested into" means to put money or resources into something again, which also does not fit in the context of the sentence.
- D. "Auctioned" means to sell something through an auction, which is not what the sentence suggests.
Q12. SPOT THE ERROR: In the following sentence, some segments of the sentence are underlined. Your task is to identify that underlined segment of the sentence, which contains the mistake that needs to be corrected.
- A. Option A
- B. Option B✓
- C. Option C
- D. Option D
- E. No error
Explanation: Correct is option B as 'social and economic progress, good governance' are the main verbs which are plural so 'take' should be used.
Why the other options are wrong
- A. Incorrect option.
- C. Incorrect option
- D. Incorrect option.
- E. Wrong
Q13. SPOT THE ERROR: In the following sentences, some segments of the sentence are underlined. Your task is to identify that underlined segment of the sentence, which contains the mistake that needs to be corrected.
- A. Let's
- B. The
- C. is
- D. to✓
Explanation: The incorrect preposition 'of' is used here. It should be replaced by 'for'. 'The bus is leaving for the last stop.'
Why the other options are wrong
- A. This segment doesn't contain mistake.
- B. This segment doesn't contain mistake.
- C. This segment doesn't contain mistake.
Q14. Ester linkages occur in:
- A. Nucleic acids✓
- B. Nucleus
- C. Carbohydrates
- D. Proteins
Explanation: DNA and RNA are the chain of polynucleotides, that are joined by ester linkage known as 'phosphodiester bonds'. The two nucleotides, within a nucleotide chain, are linked by a phosphodiester bond. It is formed by the linkage between the 3' carbon atom of one sugar molecule and the 5' carbon atom of another, with the phosphate group acting as a bridge between the 2 carbons.So, the correct answer is option A.
Why the other options are wrong
- B. This option is not correct because ester linkages are not found in the nucleus, which is a membrane-bound organelle that contains the genetic material of eukaryotic cells.
- C. This option is also incorrect because carbohydrates are mainly composed of glycosidic linkages, which are different from ester linkages.
- D. This option is also incorrect because ester linkages are not found in proteins. Proteins are mainly composed of peptide bonds between amino acids in their primary structure, and other types of covalent bonds such as disulfide bonds, which help to stabilize the protein's three-dimensional structure.
Q15. The finger like infoldings, which are formed by inner membrane of mitochondria, are called:
- A. Ribosomes
- B. Matrix
- C. Porin
- D. Cristae✓
Explanation: Factual recall; 'Ribosomes' are organelles, that serve as sites of protein synthesis. 'Matrix' refers to the space confined by the inner mitochondrial membrane within the mitochondria. 'Porin' refers to a transport protein that enables the passive diffusion of certain molecules across a membrane. Cristea are finger-like infoldings, which are formed by the inner membrane of the mitochondria.
Why the other options are wrong
- A. Ribosomes are organelles that serve as sites of protein synthesis.
- B. Matrix refers to the space confined by the inner mitochondrial membrane within the mitochondria.
- C. 'Porin' refers to a transport protein that enables the passive diffusion of certain molecules across a membrane.
Q16. The main neurotransmitter for synapses is _, which lie outside the central nervous system.
- A. Acetylcholine✓
- B. Acetaldehyde
- C. Choline
- D. Phosphatidylcholine
Explanation: Acetylcholine is a neurotransmitter that is used in transmission across synapses within both, the central nervous system and peripheral nervous system (i.e. outside the central nervous system). Acetaldehyde (B) is an aldehyde with two carbon atoms and is not used as a neurotransmitter. Choline (C) is a constituent of the neurotransmitter, 'Acetylcholine' but, by itself, is not a neurotransmitter. Phosphatidylcholine (D) contains a choline subunit, similar to acetylcholine, but itself is not a neurotransmitter. It is actually a constituent of cell membranes as well as of surfactant, which is present in alveoli.
Why the other options are wrong
- B. Acetaldehyde (B) is an aldehyde with two carbon atoms and is not used as a neurotransmitter.
- C. Choline (C) is a constituent of the neurotransmitter, 'Acetylcholine' but, by itself, is not a neurotransmitter.
- D. Phosphatidylcholine (D) contains a choline subunit, similar to acetylcholine, but itself is not a neurotransmitter. It is actually a constituent of cell membranes as well as of surfactant, which is present in alveoli.
Q17. The structure present in a eukaryotic cell but absent in prokaryotic cells is:
- A. Nucleus✓
- B. DNA
- C. Ribosomes
- D. Cell surface membrane
Explanation: :The term ' prokaryotes' is derived from the Greek word ' pro meaning before' and ' karyon meaning nucleus'. Prokaryotic cells are cells that do not have a true nucleus and membrane-bound organelles.
Why the other options are wrong
- B. It is present in both.
- C. They are present in both.
- D. It is present in both.
Q18. If water has a high latent heat of vaporization, how could this property of water be helpful to plants and animals?
- A. With the release of large amount of water, a small amount of heat loss can take place.
- B. With the release of small amount of water vapours, a great amount of heat loss can take place.✓
- C. It will keep their temperature very high.
- D. No cooling effect, with the release of even a large amount of water vapours.
Explanation: As per the formula Q=mL, since water has a high latent heat of vaporization (L), for a small mass or amount of water (m), a large amount of energy (Q) will be released which results in a large amount of heat loss, enabling the organism to remain cool via sweating (animals) or transpiration (plants). Option A describes this effect but in reverse, option C states the opposite effect as this process prevents their temperature from becoming too high, and option D is false as a cooling effect does indeed occur.
Why the other options are wrong
- A. As per the formula Q=mL, since water has a high latent heat of vaporization (L), for a small mass or amount of water (m), a large amount of energy (Q) will be released which results in a large amount of heat loss, enabling the organism to remain cool via sweating (animals) or transpiration (plants). Option A describes this effect but in reverse.
- C. As per the formula Q=mL, since water has a high latent heat of vaporization (L), for a small mass or amount of water (m), a large amount of energy (Q) will be released which results in a large amount of heat loss, enabling the organism to remain cool via sweating (animals) or transpiration (plants). Option C states the opposite effect as this process prevents their temperature from becoming too high.
- D. As per the formula Q=mL, since water has a high latent heat of vaporization (L), for a small mass or amount of water (m), a large amount of energy (Q) will be released which results in a large amount of heat loss, enabling the organism to remain cool via sweating (animals) or transpiration (plants). Option D is false as a cooling effect does indeed occur.
Q19. Which cell organelle is responsible for protein modification?
- A. Chloroplast
- B. Golgi body✓
- C. Ribosome
- D. Mitochondrion
Explanation: The 'Golgi apparatus' is a cellular organelle responsible for the modification and trafficking of proteins to other organelles such as the lysosome, the digestive organelle of the cell.
Why the other options are wrong
- A. Chloroplasts are responsible for photosynthesis, converting light energy into chemical energy in the form of glucose, while releasing oxygen into the atmosphere.
- C. Ribosomes are cellular structures responsible for protein synthesis, translating genetic information from mRNA into functional proteins.
- D. Mitochondria are organelles found in most eukaryotic cells that are often referred to as the "powerhouses" of the cell due to their primary role in energy production.
Q20. Nowadays every newborn gets regular shots of vaccine for polio. It contains _ for polio to make a child immune against this disease.
- A. Antibiotics
- B. Antibodies
- C. Antigens✓
- D. Antisera
Explanation: A vaccine elicits an immune response by the host so that the host is better equipped to fight against the invading organism, in any potential future instance, via the production of memory cells. It may do so by containing the antigens of the invading organism (in this case, poliovirus) so that the host’s immune system produces memory cells against the specific organism, thereby conferring active immunity against the disease. Antibiotics (option A) are not present in vaccines; they are drugs used to treat bacterial illnesses. Antibodies (option B) are not present in vaccines; they are proteins, produced by plasma cells, to ward off infection. They are produced by the immune system to fight an active infection, but they are not used in vaccines since they do not confer active immunity as the host does not produce memory cells against the invading organism. Antisera (option D) is a blood serum preparation that contains antibodies against a certain antigen or disease; they are used as a treatment for certain conditions and do not confer active immunity to the individual.
Why the other options are wrong
- A. Antibiotics are a class of medications used to treat bacterial infections. They work by either killing bacteria or inhibiting their growth and reproduction. Antibiotics are specifically designed to target bacteria and have no effect on viruses.
- B. Antibodies, also known as immunoglobulins, are proteins produced by the immune system in response to the presence of foreign substances called antigens. Antibodies play a crucial role in the immune response and provide defense against harmful pathogens, such as bacteria, viruses, and other microorganisms.
- D. Antisera is a blood-derived product that contains antibodies specifically targeted against a particular antigen or group of antigens. It is obtained from the blood of animals or humans that have been immunized with the antigen of interest.
Q21. Change in frequency of alleles that occurs by chance is called as:
- A. Genetic drift✓
- B. Mutation
- C. Migration
- D. Natural selection
Explanation: The question describes the definition of a genetic drift, which is a change in the frequency of alleles that occurs purely by chance. A mutation (option B) describes a change in DNA sequence. Migration (option C) describes the influx or the efflux of individuals into or out of a population, respectively. Natural selection (D) can be confused with genetic drift as both are mechanisms for evolution, but the main difference lies in the fact that in natural selection, allele frequencies change over time not by chance, but due to certain alleles conferring a selective advantage to some individuals over the other (hence, it is not driven by chance, but driven by factors that are useful to the individual and ensures their survival).
Why the other options are wrong
- B. Mutation in DNA refers to a change in the genetic sequence of DNA molecules. It can occur due to various factors such as errors during DNA replication, exposure to mutagens (e.g., radiation, certain chemicals), or spontaneous genetic changes.
- C. Migration refers to the movement of individuals or populations from one geographic region to another. It is a common phenomenon observed in various organisms, including animals, birds, and even certain microorganisms. Migration can occur for several reasons, such as the search for better resources, seasonal changes, mating opportunities, or escaping unfavorable conditions. It plays a crucial role in population dynamics, gene flow between populations, and the distribution of species across different habitats.
- D. Natural selection is a fundamental mechanism of evolution that drives the process of adaptation in populations. It is based on the idea that individuals with traits better suited to their environment are more likely to survive and reproduce, passing those advantageous traits to future generations. This leads to a gradual change in the frequency of beneficial traits within a population over time. Natural selection acts on heritable variations in traits, favoring those that increase an organism's fitness and survival. It is the primary driving force behind the diversity and complexity of life on Earth.
Q22. Lipids contain double amount of energy as compared to the same amount of carbohydrates due to the presence of:
- A. Higher proportion of C-H✓
- B. Higher proportion of C-O
- C. Higher proportion of Oxygen
- D. Low proportion of C-H bonds
Explanation: C-H bond is a stronger bond than the C-O bond, and since lipids contain a much higher proportion of C-H bonds than carbohydrates (because lipids contain much less oxygen per mole than carbohydrates), lipids contain double the amount of energy than carbohydrates. The remaining three options (B,C,D) are incorrect as they explain the traits of lipids in reverse.
Why the other options are wrong
- B. The remaining three options (B,C,D) are incorrect as they explain the traits of lipids in reverse.
- C. The remaining three options (B,C,D) are incorrect as they explain the traits of lipids in reverse.
- D. The remaining three options (B,C,D) are incorrect as they explain the traits of lipids in reverse.
Q23. The phase of mitosis in which sister chromatids move towards opposite poles:
- A. Anaphase✓
- B. Metaphase
- C. Prophase
- D. Telophase
Explanation: Anaphase is the most critical phase of the mitosis, which ensures equal distribution of chromatids in the daughter cells. The kinetochore fibers of spindle contract towards their respective poles, at the same time polar microtubules elongates exert force and sister chromatids are separated from centromere. As a result, half sister chromatids travel towards each pole. In metaphase, chromosomes line at the equator of the spindle. In prophase, chromosomes condense and the nuclear envelope disintegrates. In telophase, the sister chromatids have reached their respective poles and the two daughter nuclei form.
Why the other options are wrong
- B. In metaphase, chromosomes line at the equator of the spindle.
- C. In prophase, chromosomes condense and the nuclear envelope disintegrates.
- D. In telophase, the sister chromatids have reached their respective poles and the two daughter nuclei form.
Q24. Starch is present in tubers, fruits, and grains but absent in animal cells. Instead, animals have a substance stored in liver and muscles known as:
- A. Galactose
- B. Glucagon
- C. Glycogen✓
- D. Glucose
Explanation: Glycogen is the storage form of carbohydrate found in animals. Galactose (A) is a monosaccharide, Glucagon (B) is a hormone, Glucose (D) is a monosaccharide and the monomer of glycogen and starch.
Why the other options are wrong
- A. Galactose is a monosaccharide, or a simple sugar, that is commonly found in dairy products and certain fruits. It is chemically similar to glucose and is often metabolized in the body as a source of energy. Galactose plays a crucial role in various biological processes, including the synthesis of lactose, a disaccharide found in milk.
- B. Glucagon is a hormone produced by the alpha cells of the pancreas. It acts in opposition to insulin and plays a vital role in regulating blood glucose levels. When blood sugar levels are low, such as during fasting or between meals, glucagon is released into the bloodstream. It triggers several processes that increase blood glucose levels, including the breakdown of stored glycogen in the liver (glycogenolysis) and the production of new glucose from non-carbohydrate sources (gluconeogenesis).
- D. Glucose is a simple sugar and the primary source of energy for living organisms. It is a monosaccharide, belonging to the carbohydrate group. Glucose is produced through photosynthesis in plants and is a key energy source obtained from food by animals.
Q25. Thin filaments of muscles contain _ chains of actin molecules.
- A. Two✓
- B. One
- C. Three
- D. Four
Explanation: The actin molecules contain active sites, to which myosin heads will bind, during contraction. The thin filaments contain two intertwined bands of actin monomers. Alongside, they possess regulatory proteins called tropomyosin and troponin, which regulate the interaction of actin and myosin.
Why the other options are wrong
- B. This option is incorrect, as the actin molecules contain active sites, to which myosin heads will bind, during contraction.
- C. This option is incorrect, as the actin molecules contain active sites, to which myosin heads will bind, during contraction.
- D. This option is incorrect, as the actin molecules contain active sites, to which myosin heads will bind, during contraction.
Q26. The reflex action is the phenomena which only involves:
- A. Brain. receptors, spinal cord
- B. Receptors, neurons, brain
- C. Receptors, effectors and spinal cord✓
- D. Receptors and effectors
Explanation: The simplest arrangement of a reflex are consists of the receptors, an interneuron, and an effector; together these units from a finctional reflex group. Brain is, however, excluded in the reflex arc.
Why the other options are wrong
- A. The simplest arrangement of a reflex consists of the receptors, an interneuron, and an effector; together these units form a functional reflex group. The brain is, however, excluded in the reflex arc.
- B. The simplest arrangement of a reflex consists of the receptors, an interneuron, and an effector; together these units form a functional reflex group. The brain is, however, excluded in the reflex arc.
- D. The simplest arrangement of a reflex are consists of the receptors, an interneuron, and an effector; together these units from a finctional reflex group. Brain is, however, excluded in the reflex arc.
Q27. Complementary DNA molecule is:
- A. DNA from mRNA✓
- B. An artificial DNA
- C. Single stranded DNA
- D. A small segment of chromosomal DNA
Explanation: A complementary DNA molecule or cDNA is, by definition, a DNA copy of a messenger RNA or mRNA molecule, produced by reverse transcriptase.
Why the other options are wrong
- B. The word complementary may confuse the candidate because if you recall, in a DNA double helix, each strand is complementary to the other, but when cDNA or complementary DNA is specifically asked for, it describes a DNA copy of mRNA.
- C. The word complementary may confuse the candidate because if you recall, in a DNA double helix, each strand is complementary to the other, but when cDNA or complementary DNA is specifically asked for, it describes a DNA copy of mRNA.
- D. The word complementary may confuse the candidate because if you recall, in a DNA double helix, each strand is complementary to the other, but when cDNA or complementary DNA is specifically asked for, it describes a DNA copy of mRNA.
Q28. An example of competitive inhibition of an enzyme is the inhibition of:
- A. Succinic dehydrogenase by malonic acid.✓
- B. Cytochrome oxidase by cyanide.
- C. Hexokinase by glucose.
- D. Carbonic anhydrase by carbon dioxide.
Explanation: The inhibition of succinic dehydrogenase by malonic acid is an example of competitive inhibition. Succinic dehydrogenase is an enzyme involved in the citric acid cycle (also known as the Krebs cycle) and plays a role in the conversion of succinate to fumarate. Malonic acid serves as a competitive inhibitor in this context. It structurally resembles the substrate (succinate) and competes with it for binding to the active site of succinic dehydrogenase. Malonic acid binds to the active site of the enzyme, preventing the normal substrate (succinate) from binding and undergoing the catalytic reaction. The presence of malonic acid decreases the rate of the succinic dehydrogenase-catalyzed reaction by interfering with the binding of succinate.
Why the other options are wrong
- B. Cyanide is a potent inhibitor of cytochrome c oxidase, also known as complex IV, which is a crucial enzyme in the electron transport chain of cellular respiration. Cytochrome c oxidase is responsible for the final step in the electron transport chain, where electrons are transferred to molecular oxygen, resulting in the production of water.
- C. Hexokinase is an enzyme that catalyzes the phosphorylation of glucose to form glucose-6-phosphate. This reaction is the first step in the glycolytic pathway, a central metabolic pathway that involves the breakdown of glucose to produce energy.
- D. Carbonic anhydrase is an enzyme that catalyzes the reversible hydration of carbon dioxide (CO2) to form bicarbonate ions (HCO3-) and protons (H+). This reaction is an essential part of various physiological processes, particularly in the transport of carbon dioxide in the blood and the regulation of acid-base balance.
Q29. Meselson and Stahl transferred few bacteria grown in N15 medium to N14 medium for replicating their DNA. What would be the result after two rounds of replication?
- A. 100% heavy duplex
- B. 100% hybrid duplex
- C. 50% hybrid duplex and 50% heavy duplex
- D. 50% hybrid duplex and 50% light duplex✓
Explanation: After two rounds of replication, half of the duplexes will be hybrid i.e. contain one N15 strand and one N14 strand, while the other half will contain only N14 or light strands.
Why the other options are wrong
- A. It describes the scenario in which the culture has not yet undergone replication in the new N14 medium since all of its DNA consists of N15 or heavy nitrogen. With each further replication, the DNA will start to consist of more and more N14.
- B. It describes the scenario in which the culture has undergone one round of replication. This is because DNA replicates semi-conservatively. Before replicating, all of its DNA strands contained N15. After one round of replication, each previously existing strand will now pair with a newly synthesized strand, which consists exclusively of N14, since that is the nitrogen present in the new medium. Hence, now all the duplexes will contain one previous/old strand of N15 and one new strand of N14, hence 100% hybrid.
- C. It cannot occur because, in order for heavy duplexes to be present after replication, DNA can NOT replicate semi-conservatively. After any round of replication, no duplex will be present, which contains only heavy or N15, because each old N15 will be paired with a N14 strand, and in subsequent replications, the duplexes will either consist of both N14 or hybrid duplex, because in semiconservative replication, an old strand will always be conserved paired with a new strand. Hence, a 50% heavy duplex cannot occur because the medium, in which the bacteria replicates, is N14 and DNA replication is exclusively semiconservative.
Q30. In an action potential, the permeability of sodium ions in the neurons increases due to:
- A. Repolarization
- B. Sodium ions forming an ionic bonding
- C. The opening of sodium channels/gates✓
- D. The action of the acetylcholinesterase enzyme
Explanation: Option A mentions repolarization, which is the stage where there is a large influx of potassium ions out from the cell, during which sodium ions do not enter the cell. Option B mentions the concept of ionic bonding which is irrelevant to the scenario. Option C is correct, as when sodium voltage-gated channels open, only then does the permeability of sodium ions across the membrane increases, resulting in their influx into the cell. Option D describes an enzyme, that is important in recycling ACh across synapses; it is not relevant to the concept of sodium permeability during action potentials.
Why the other options are wrong
- A. Option A mentions repolarization, which is the stage where there is a large influx of potassium ions out from the cell, during which sodium ions do not enter the cell.
- B. Option B mentions the concept of ionic bonding which is irrelevant to the scenario.
- D. Option D describes an enzyme, that is important in recycling ACh across synapses; it is not relevant to the concept of sodium permeability during action potentials.
Q31. In which situation are genes, are not assorted independently, during meiosis in a chromosome?
- A. When genes are linked and their loci are close to each other✓
- B. When some genes have mutated on the chromosome
- C. When there are too many Genes on a chromosome
- D. When genes are not linked and their loci are far apart
Explanation: According to the law of independent assortment, the alleles of two or more different genes get sorted into gametes independently of one another, i.e. the allele, a gamete receives for one gene, does not influence the allele received for another gene. Hence, two different traits or genes are inherited separately or independent of each other. For genes to NOT assort independently, this implies that they are inherited TOGETHER, i.e. are linked. This is more likely to occur when the positions of the genes (i.e. their loci) are close to each other on one chromosome. This scenario is only described by option A.
Why the other options are wrong
- B. It is incorrect.
- C. It is incorrect.
- D. It is incorrect.
Q32. During spermatogenesis, the _, which are haploid cells eventually mature into spermatozoa/mature sperms.
- A. Spermatogonia
- B. Primary spermatocytes
- C. Spermatids✓
- D. Secondary spermatocytes
Explanation: During spermatogenesis, the spermatids, which are haploid cells, eventually mature into spermatozoa or mature sperm. Spermatogenesis is the process by which male germ cells (spermatogonia) undergo a series of divisions and differentiations to ultimately form functional sperm cells.
Why the other options are wrong
- A. Option A, spermatogonia, are diploid cells and are the first stage in the process of spermatogenesis. They have not undergone meiotic division, and as such are diploid.
- B. Option B, primary spermatocytes, are also diploid cells, as they arise from mitotic divisions of the spermatogonia which themselves are diploid. They are not a product of meiosis.
- D. Option D, secondary spermatocytes, are also haploid cells and are the cells which give rise to spermatids. This is not the correct answer as the question is asking for a haploid cell that matures into spermatozoa/mature sperm cells. Secondary spermatocytes give rise to spermatids first which then go on to mature into spermatozoa so, spermatids fit the given scenario.
Q33. Site of mRNA translation:
- A. Lysosomes
- B. Ribosomes✓
- C. Cisternae
- D. Golgi body
Explanation: Factual recall; Option A mentions lysosomes, which contain hydrolytic enzymes that digest old organelles or phagocytosed particles. Option B mentions ribosomes; messenger RNA (mRNA) is decoded in a ribosome, outside the nucleus, to produce a specific amino acid chain or polypeptide. Option C, cisternae, describes the sac-like tubules that make up the endoplasmic reticulum. Option D, Golgi body, is involved in packaging of already synthesized proteins and their subsequent transport or secretion.
Why the other options are wrong
- A. Lysosomes contain hydrolytic enzymes that digest old organelles or phagocytosed particles.
- C. Cisternae are the sac-like tubules that make up the endoplasmic reticulum.
- D. Golgi body is involved in packaging of already synthesized proteins and their subsequent transport or secretion.
Q34. The photosynthetic pigments of plants are arranged as clusters in thylakoid membranes. The reaction centers of these clusters consist of _ molecules.
- A. Chlorophyll✓
- B. ATP
- C. Carotenoids
- D. Glucose
Explanation: The reaction centers of photosynthetic pigment clusters in thylakoid membranes consist of chlorophyll molecules. Chlorophyll is the primary pigment responsible for capturing light energy during the light-dependent reactions of photosynthesis. In the thylakoid membrane, chlorophyll molecules are organized into complexes known as photosystems.
Why the other options are wrong
- B. Option B, ATP, is the universal energy carrier, which is one of the end products of the light-dependent stage of photosynthesis and is not present within photosystems (which are clusters of photosynthetic pigments).
- C. Option C, carotenoids, are photosynthetic pigments, that are present within photosystems, but their main purpose is to collect/trap more light energy (of a shorter wavelength) and transfer it to the central chlorophyll molecules. Their purpose is to enhance the efficiency of absorption of light energy.
- D. This is incorrect as Glucose is the final end product of photosynthesis and as such not a component of photosystems or their reaction centers.
Q35. Acetylcholine and noradrenaline are two types of _ used in our nervous system.
- A. Enzymes
- B. Channel and carrier proteins in the cell membrane of a neuron
- C. Neurotransmitters✓
- D. Hormones
Explanation: Factual recall: Both of these substances are neurotransmitters and not any of the things, mentioned in the other options.
Why the other options are wrong
- A. Enzymes are proteins that act as catalysts in biological reactions. They play a crucial role in facilitating and speeding up chemical reactions in living organisms by lowering the activation energy required for the reactions to occur.
- B. Channel proteins form channels or pores in the cell membrane that allow the selective passage of ions or molecules across the membrane. Carrier proteins, also known as transporters, are involved in the active or passive transport of specific molecules across the cell membrane. Carrier proteins are particularly important for the uptake and release of neurotransmitters in neurons.
- D. Hormones are chemical messengers produced by various glands and cells in the body. They are secreted into the bloodstream and act on specific target cells or organs to regulate and coordinate various physiological processes.
Q36. The type of energy, reduced by the enzymes, for biological reactions to occur is called the:
- A. Light Energy
- B. Heat energy
- C. Active energy
- D. Activation energy✓
Explanation: The type of energy reduced by enzymes to facilitate biological reactions is referred to as "activation energy." Enzymes play a crucial role in biological systems by lowering the activation energy required for a chemical reaction to occur. Activation energy is the energy input needed to initiate a chemical reaction by overcoming the energy barrier associated with the conversion of reactants into products. Enzymes accelerate reactions by providing an alternative pathway with a lower activation energy, making it easier for the reaction to proceed.
Why the other options are wrong
- A. Light energy is a form of energy that is visible to the human eye and is responsible for the sensation of sight. It is a type of electromagnetic radiation, which consists of waves of electric and magnetic fields propagating through space.
- B. Heat energy is a form of energy associated with the movement of atoms and molecules in a substance. It is a manifestation of the internal kinetic energy present in a material due to the random motion of its particles. The faster the particles move, the higher the temperature, and the greater the heat energy.
- C. The correct term is "activation energy," not "active energy." Activation energy is the energy required to initiate a chemical reaction and allow it to proceed. It represents the energy barrier that must be overcome for reactant molecules to transform into products. Enzymes play a significant role in biological systems by lowering the activation energy of reactions, facilitating their occurrence under physiological conditions.
Q37. The prokaryotes possess ribosome with larger subunit of:
- A. 70S
- B. 50S✓
- C. 60S
- D. 40S
Explanation: Prokaryotes contain 70S ribosomes, which themselves comprise of two further subunits; a larger 50S subunit and a smaller 30S subunit. 80S ribosomes are present in eukaryotes.
Why the other options are wrong
- A. Prokaryotes contain 70S ribosomes, which themselves comprise of two further subunits; a larger 50S subunit and a smaller 30S subunit. 80S ribosomes are present in eukaryotes.
- C. Prokaryotes contain 70S ribosomes, which themselves comprise of two further subunits; a larger 50S subunit and a smaller 30S subunit. 80S ribosomes are present in eukaryotes.
- D. Prokaryotes contain 70S ribosomes, which themselves comprise of two further subunits; a larger 50S subunit and a smaller 30S subunit. 80S ribosomes are present in eukaryotes.
Q38. Homozygous means:
- A. Alleles in an organism
- B. Two different alleles of a gene
- C. Having two identical genes
- D. Having two identical alleles of a gene✓
Explanation: Homozygous refers to a genotype where, for a given trait or gene, the organism possesses two alleles of the same type (i.e. both alleles are dominant or both alleles are recessive). Option D fits this description. Option A merely mentions alleles in an organism, whereas homozygous refers to the allelic combination of a particular trait/gene. Option B refers to the heterozygous state, not homozygous. Option C refers to having two identical genes. Homozygous (and even heterozygous) terms refer to the allelic combination the organism possesses of one particular gene. It is important to remember that an allele is a variant of one particular gene so, one gene may have two or more variants or alleles.
Why the other options are wrong
- A. Option A merely mentions alleles in an organism, whereas homozygous refers to the allelic combination of a particular trait/gene.
- B. Option B refers to the heterozygous state, not homozygous.
- C. Option C refers to having two identical genes. Homozygous (and even heterozygous) terms refer to the allelic combination the organism possesses of one particular gene. It is important to remember that an allele is a variant of one particular gene so, one gene may have two or more variants or alleles.
Q39. Most proteins are made up of:
- A. 10 types of amino acids
- B. 20 types of amino acids✓
- C. 170 types Of amino acids
- D. 16 types of amino acids
Explanation: There are a total of 20 naturally-occurring amino acids, which are found in proteins, which consist of long chains of these amino acids. Option B mentions 20 amino acids so, it is the correct answer, while the other options mention numbers aside from 20.
Why the other options are wrong
Q40. The route of urine excretion from kidney to outside of body is:
- A. Kidney → ureter → urinary bladder → urethra✓
- B. Urinary bladder → kidney → ureter → urethra
- C. Kidney → urethra → urinary bladder → ureter
- D. Kidney → ureter → urethra → urinary bladder
Explanation: Option A describes the correct route of urine excretion. The kidney filters blood and forms urine. This urine is to be excreted out of the body, and from the kidney, it drains into the ureter. Each kidney drains into one ureter, which is a long muscular tube, that leads into the urinary bladder, which is a sac-like organ that collects urine from the kidney. When a certain amount of urine has been collected, it is urinated out by a thin tube known as the urethra.All of the remaining options describe jumbled up/incorrect routes of urine excretion.
Why the other options are wrong
- B. All of the remaining options describe jumbled up/incorrect routes of urine excretion.
- C. All of the remaining options describe jumbled up/incorrect routes of urine excretion.
- D. All of the remaining options describe jumbled up/incorrect routes of urine excretion.
Q41. In genetics, the term locus refers to the _ of the gene on the chromosome.
- A. Position✓
- B. Frequency
- C. Copy
- D. Inversion
Explanation: The locus describes the position of the gene on a chromosome.
Why the other options are wrong
- B. Frequency, is generally used to describe frequency of alleles, i.e. how frequently one allele occurs relative to the other or the proportions in which each allele of a particular gene occurs.
- C. Copy, as the name implies, refers to copies or duplications of a portion of the genetic code, found in the genome of an organism.
- D. Inversion, is a mutation, that involves chromosome rearrangement, where one segment of a chromosome is reversed from end to end.
Q42. Glycolysis takes place in the _ of cells.
- A. Nucleus
- B. Mitochondria
- C. Golgi complex
- D. Cytoplasm✓
Explanation: Glycolysis, the first step of aerobic respiration, which results in the formation of two molecules of pyruvate from one molecule of glucose, occurs in the 'cytoplasm' of the cell.
Why the other options are wrong
- A. Option A mentions the 'nucleus', which is not involved in any steps of respiration.
- B. Option B mentions 'mitochondria', which is the site for the remaining steps of aerobic respiration; after pyruvate is made in the cytoplasm via glycolysis, it is shunted into the mitochondria where it is involved in the formation of acetyl CoA via the link reaction after which the Krebs Cycle takes place (link reaction and Krebs cycle occur in the mitochondrial matrix). Finally, the terminal reaction of aerobic respiration occurs across the inner mitochondrial membrane, which is oxidative phosphorylation.
- C. Option C mentions the Golgi complex, which is not involved in any steps of respiration; it merely serves as the site of protein packaging and subsequent transport.
Q43. If a carrier haemophilic female (XHXh) is married to a haemophilic male (XhY). What will be the ratio of the presence of haemophilia in the children? Select the best answer from the given options.
- A. 100% of all females and males will be hemophilic
- B. Females have a 50% chance of getting haemophilia and males will be 100% hemophilic
- C. Carrier female 25%, hemophilic female 25%, normal male 25% and 25% hemophilic male✓
- D. Females and males both have 50% chance of getting hemophilia
Explanation: As per the cross given above, there are four possible genotypes and hence, four possible phenotypes. These are; carrier daughter, hemophiliac daughter, normal son, and hemophiliac son, and all four have an equal probability or likelihood of occurring, which is 25 percent. Option C describes this scenario correctly so, it is the correct option. Option A describes a scenario in which the mother is a hemophiliac (i.e. has a genotype of XhXh) and the father is also a hemophiliac (genotype XhY), which results in all the children being hemophiliacs. Option B describes an impossible scenario, as in order for all the males to be hemophiliac, the mother must have a genotype of XhXh, but in this scenario, the daughters will either be all hemophiliacs or all carriers (father's genotype being either XhY or XHY, respectively). Hence, for all males to be hemophiliacs, it is impossible for the females to have a 50% chance of being hemophiliacs. Option D also describes the given scenario, because if you look at the figure above, males will either be normal or hemophiliac, and females will either be carriers or hemophiliac, as such, each gender has a 50% chance of being hemophiliacs. However, option C better describes this scenario as it specifically lists the probabilities of all four possible phenotypes. (NOTE: The question asks the candidate to select the BEST possible answer from the given options).
Why the other options are wrong
- A. Option A describes a scenario in which the mother is a hemophiliac (i.e. has a genotype of XhXh) and the father is also a hemophiliac (genotype XhY), which results in all the children being hemophiliacs.
- B. Option B describes an impossible scenario, as in order for all the males to be hemophiliac, the mother must have a genotype of XhXh, but in this scenario, the daughters will either be all hemophiliacs or all carriers (father's genotype being either XhY or XHY, respectively). Hence, for all males to be hemophiliacs, it is impossible for the females to have a 50% chance of being hemophiliacs.
- D. Option D also describes the given scenario, because if you look at the figure above, males will either be normal or hemophiliac, and females will either be carriers or hemophiliac, as such, each gender has a 50% chance of being hemophiliacs. However, option C better describes this scenario as it specifically lists the probabilities of all four possible phenotypes.
Q44. A disease caused by gradual breakdown of the thin walls of alveoli is:
- A. Tuberculosis
- B. Asthma
- C. Emphysema✓
- D. Bronchitis
Explanation: Option A, tuberculosis, is a bacterial infection of the lungs, characterized by persistent cough, fever, and weight loss. This involves granuloma formation and cavitation of the lung tissue so, it is not the disease described in the question. Option B, asthma, is the thickening of the bronchioles due to an excessive allergic reaction upon exposure to certain agents and irritants (allergens). Option C, emphysema, is the correct answer, as it involves the breakdown of the alveolar elastic tissue resulting in the breakdown of alveolar walls, leading to the formation of large pockets within the lungs. Option D, bronchitis, is a chronic disease, that involves excessive mucus production in response to prolonged smoking.
Why the other options are wrong
- A. Tuberculosis, is a bacterial infection of the lungs, characterized by persistent cough, fever, and weight loss. This involves granuloma formation and cavitation of the lung tissue so, it is not the disease described in the question.
- B. Asthma, is the thickening of the bronchioles due to an excessive allergic reaction upon exposure to certain agents and irritants (allergens).
- D. Bronchitis, is a chronic disease, that involves excessive mucus production in response to prolonged smoking.
Q45. Substances responsible for increasing the set point of the hypothalamus are called:
- A. Androgens
- B. Pyrogens✓
- C. Pepsin
- D. Prions
Explanation: Substances responsible for increasing the set point of the hypothalamus are called pyrogens. Pyrogens are substances that induce a fever response in the body by raising the set point of the hypothalamus, which is the body's internal temperature-regulating center. When pyrogens are present, they signal the hypothalamus to increase the set point, resulting in the body generating and conserving heat to reach the new higher temperature. Pyrogens can be endogenous (produced within the body) or exogenous (coming from external sources). Examples of endogenous pyrogens include cytokines such as interleukin-1 (IL-1) and interleukin-6 (IL-6), which are released during an immune response. Exogenous pyrogens can include bacterial toxins or certain drugs. By increasing the set point of the hypothalamus, pyrogens contribute to the development of a fever, which is a protective response that helps the body fight off infections and promote immune function.
Why the other options are wrong
- A. Androgens, are a group of hormones that play a role in developing male sexual characteristics and reproductive activity.
- C. Pepsin is an enzyme found in gastric juice, which breaks down proteins.
- D. Prions are pathogenic misfolded proteins that are the agents, responsible for mad cow disease.
Q46. DNA polymerase enzyme for PCR is isolated from bacteria, Thermus aquaticus, because:
- A. It can work at high speed
- B. It can withstand high denaturation temperature✓
- C. It can withstand low denaturation temperature
- D. It can be used again and again
Explanation: 'Thermos aquaticus' is a heat-tolerant bacterium and its enzymes, including DNA polymerase (or Taq polymerase), are resistant to high temperatures. In PCR, a high temperature is used (denaturation temperature) to denature the template DNA or separate its strands. The fact that this DNA polymerase can withstand the high temperatures, used in PCR, enables it to work efficiently without denaturing itself, thereby enabling the reaction to occur, adequately. Hence, option B is the correct answer. Option A is not exclusive to this enzyme, as most enzymes can work at a high speed and increase the rate of reaction. Option C is technically correct as if this DNA polymerase can withstand high temperature, it can obviously withstand low temperature as well, but since PCR involves a high temperature, this trait is not relevant to the scenario. Option D is a feature shared by all enzymes as they are recyclable, not exclusive to this DNA polymerase.
Why the other options are wrong
- A. Option A is not exclusive to this enzyme, as most enzymes can work at a high speed and increase the rate of reaction.
- C. Option C is technically correct as if this DNA polymerase can withstand high temperatures, it can withstand low temperatures as well. Still, since PCR involves a high temperature, this trait is irrelevant to the scenario.
- D. Option D is a feature shared by all enzymes as they are recyclable, not exclusive to this DNA polymerase.
Q47. Which of the following photosystems is involved in cyclic photophosphorylation?
- A. PS II
- B. PS I✓
- C. PS I and PS II
- D. PS III
Explanation: Cyclic photophosphorylation (which is depicted by the yellow arrows below) employs the use of only photosystem I (PS1) and not PSII, which is involved in non cyclic photophosphorylation.
Why the other options are wrong
- A. It is incorrect as cyclic photophosphorylation employs the use of only photosystem I (PS1) and not PSII, which is involved in non cyclic photophosphorylation.
- C. It is incorrect as cyclic photophosphorylation employs the use of only photosystem I (PS1) and not PSII, which is involved in non cyclic photophosphorylation.
- D. It is incorrect as cyclic photophosphorylation employs the use of only photosystem I (PS1) and not PSII, which is involved in non cyclic photophosphorylation.
Q48. Which hormonal pair would maintain the endometrium and make it receptive for implantation of embryo?
- A. Luteinizing Hormone and Progesterone
- B. Estrogen and Progesterone✓
- C. Estrogen and Follicle Stimulating Hormone
- D. Luteinizing Hormone and Follicle Stimulating Hormone
Explanation: The hormonal pair that plays a crucial role in maintaining the endometrium (the lining of the uterus) and making it receptive for the implantation of an embryo consists of progesterone and estrogen. During the menstrual cycle, estrogen is primarily produced by the developing ovarian follicles. In the early phase of the menstrual cycle (follicular phase), rising estrogen levels stimulate the growth and proliferation of the endometrial tissue. Estrogen also promotes the development of blood vessels and glands in the endometrium. Following ovulation, the ruptured follicle transforms into a structure called the corpus luteum, which secretes progesterone. Progesterone acts in conjunction with estrogen to further prepare the endometrium for possible implantation. It causes the glands in the endometrium to become more secretory, increases the thickness of the uterine lining, and helps create a receptive environment for a potential embryo.
Why the other options are wrong
- A. The hormonal pair that plays a crucial role in maintaining the endometrium (the lining of the uterus) and making it receptive for the implantation of an embryo consists of progesterone and estrogen.
- C. The hormonal pair that plays a crucial role in maintaining the endometrium (the lining of the uterus) and making it receptive for the implantation of an embryo consists of progesterone and estrogen.
- D. The hormonal pair that plays a crucial role in maintaining the endometrium (the lining of the uterus) and making it receptive for the implantation of an embryo consists of progesterone and estrogen.
Q49. The thick filaments, in a myofibril of muscles, are made of _.
- A. Myoglobin
- B. Myosin✓
- C. Actin
- D. Haemoglobin
Explanation: Option A, myoglobin, is a heme-containing protein found in muscles, that binds to oxygen, which it supplies to muscle tissue. Option B, myosin, is the correct answer as it forms thick filaments in a myofibril. Option C, actin, forms thin filaments in a myofibril. Option D, haemoglobin, is the heme-containing protein found in red blood cells and serves to carry oxygen within the blood.
Why the other options are wrong
- A. Option A, myoglobin, is a heme-containing protein found in muscles, that binds to oxygen, which it supplies to muscle tissue.
- C. Option C, actin, forms thin filaments in a myofibril.
- D. Option D, haemoglobin, is the heme-containing protein found in red blood cells and serves to carry oxygen within the blood.
Q50. If sequence in DNA is CCCTAGAG, then what would be the sequence in messenger RNA after transcription?
- A. GGGAUCUC✓
- B. GGGATCTC
- C. GGAAUCUC
- D. GGGGTCTC
Explanation: C pairs with G, A pairs with T in DNA while A pairs with U in RNA. The question asks for the corresponding mRNA sequence, after transcription of the DNA sequence. The C bases will correspond to G bases on the mRNA, T will correspond to A, G will correspond to C, whereas A will correspond to U and not T because the transcript is made up of RNA and not DNA, hence U takes the place of T. Option A describes the correct transcript: C C C T A G A G G G G A U C U C
Why the other options are wrong
- B. Only Option A has the correct order of base pairs.
- C. Only Option A has the correct order of base pairs.
- D. Only Option A has the correct order of base pairs.
Q51. In chemiosmosis, the proton (H+) moves from _.
- A. Stroma to Lumen
- B. Cytoplasm to Stroma
- C. Lumen to Stroma✓
- D. Stroma to cytoplasm
Explanation: Chemiosmosis is the process, whereby protons move down their electrochemical gradient i.e. from a region of their higher concentration to lower concentration. During this process, they move through ATP synthase, and their movement results in the coupling of ADP and inorganic phosphate to from ATP. In chloroplasts, the concentration of protons is greater in the thylakoid lumen relative to the stroma, hence protons move across the semi-permeable membrane, from the lumen into the stroma.
Why the other options are wrong
- A. During photosynthesis, the movement of protons (H+) occurs across the thylakoid membrane of the chloroplasts. The thylakoid lumen refers to the interior space within the thylakoid membrane, while the stroma is the semi-fluid region surrounding the thylakoid membrane within the chloroplast.In the light-dependent reactions of photosynthesis, protons are actively pumped from the stroma into the thylakoid lumen. This pumping of protons across the thylakoid membrane establishes a higher concentration of protons in the lumen compared to the stroma.To balance the charge and equalize the concentration, the protons move back across the thylakoid membrane from the lumen to the stroma. This movement of protons occurs through ATP synthase, an enzyme complex embedded in the thylakoid membrane. As the protons move from the lumen to the stroma through ATP synthase, the energy released is used to generate ATP from ADP and inorganic phosphate (Pi).Therefore, in the process of chemiosmosis during photosynthesis, the movement of protons (H+) occurs from the Lumen to the Stroma, not from the Stroma to the Lumen.
- B. The proton (H+) does not move from the cytoplasm to the stroma in chemiosmosis. I apologize for the error and any confusion it may have caused.In photosynthesis, during the light-dependent reactions, the movement of protons (H+) occurs across the thylakoid membrane, which separates the thylakoid lumen and the stroma within the chloroplast. The correct direction of proton movement is from the lumen to the stroma, not from the cytoplasm to the stroma.Protons are actively pumped from the stroma into the thylakoid lumen by protein complexes, such as the cytochrome b6f complex and photosystem II, during the process of electron transport. This active transport of protons creates an electrochemical gradient across the thylakoid membrane, with a higher concentration of protons in the lumen compared to the stroma.To balance the charge and equalize the concentration, protons move back across the thylakoid membrane from the lumen to the stroma. This movement of protons occurs through ATP synthase, an enzyme complex embedded in the thylakoid membrane. As the protons move from the lumen to the stroma through ATP synthase, the energy released is used to generate ATP from ADP and inorganic phosphate (Pi).
- D. During photosynthesis, the movement of protons occurs across the thylakoid membrane of the chloroplasts. The thylakoid lumen refers to the interior space within the thylakoid membrane, and the stroma is the semi-fluid region surrounding the thylakoid membrane within the chloroplast.In the light-dependent reactions of photosynthesis, protons are actively pumped from the stroma into the thylakoid lumen. This pumping of protons across the thylakoid membrane establishes a higher concentration of protons in the lumen compared to the stroma.To balance the charge and equalize the concentration, the protons move back across the thylakoid membrane from the lumen to the stroma. This movement of protons occurs through ATP synthase, an enzyme complex embedded in the thylakoid membrane. As the protons move from the lumen to the stroma through ATP synthase, the energy released is used to generate ATP from ADP and inorganic phosphate (Pi).Therefore, in the process of chemiosmosis during photosynthesis, the movement of protons (H+) occurs from the Lumen to the Stroma, not from the Stroma to the Cytoplasm
Q52. Microtubule subunits (for spindle fibers) are synthesized in _ phase.
- A. G1
- B. M
- C. G2✓
- D. S
Explanation: Microtubule subunits are tubulin proteins, which are formed prior to the initiation of mitosis. They are formed during the G2 phase, hence option C is the correct answer. G1 phase, involves normal growth and protein synthesis of the cell, leading up to the DNA replication phase (S). M is mitosis in which nuclear division occurs and it consists of prophase, metaphase, anaphase, and telophase. Prophase involves the assembly of microtubules into the spindle fibers, but the subunits of the microtubules, which are tubulin proteins, are formed prior to this stage, i.e. G2. S phase involves DNA replication.
Why the other options are wrong
- A. G1 phase, involves normal growth and protein synthesis of the cell, leading up to the DNA replication phase (S).
- B. M is mitosis in which nuclear division occurs and it consists of prophase, metaphase, anaphase, and telophase. Prophase involves the assembly of microtubules into the spindle fibers, but the subunits of the microtubules, which are tubulin proteins, are formed prior to this stage, i.e. G2.
- D. S phase involves DNA replication.
Q53. How many molecules of ATP would be utilized for phosphorylation of one glucose molecule during glycolysis?
- A. Three
- B. Two✓
- C. Four
- D. One
Explanation: Two ATP molecules are used to phosphorylate glucose; the first is used to convert glucose into glucose-6-phosphate, while the second is used to convert fructose-6-phosphate into fructose-1,6-bisphosphate.
Why the other options are wrong
- A. It is incorrect as two ATP molecules are used to phosphorylate glucose; the first is used to convert glucose into glucose-6-phosphate, while the second is used to convert fructose-6-phosphate into fructose-1,6-bisphosphate.
- C. It is incorrect as two ATP molecules are used to phosphorylate glucose; the first is used to convert glucose into glucose-6-phosphate, while the second is used to convert fructose-6-phosphate into fructose-1,6-bisphosphate.
- D. It is incorrect as two ATP molecules are used to phosphorylate glucose; the first is used to convert glucose into glucose-6-phosphate, while the second is used to convert fructose-6-phosphate into fructose-1,6-bisphosphate.
Q54. The function of calcium ions in muscle contraction is to:
- A. Bind to troponin molecule and cause them to move✓
- B. Polarize visible light
- C. Aid in the transmission of nerve impulse
- D. Bind to tropomyosin molecule and cause them to form cross bridges
Explanation: Calcium ions play a critical role in muscle contraction by binding to the troponin molecules present on the thin filaments. When calcium ions bind to troponin, it induces a conformational change in the troponin-tropomyosin complex. This change exposes the myosin-binding sites on the actin filaments, allowing the myosin heads to form cross-bridges and initiate muscle contraction.
Why the other options are wrong
- B. The presence of calcium ions in muscle contraction does not relate to the polarization of visible light. This option is not relevant to the physiological process of muscle contraction.
- C. Calcium ions are not directly involved in transmitting nerve impulses. Nerve impulses are transmitted through the movement of ions (primarily sodium and potassium) across the nerve cell membrane, creating an action potential that travels along the nerve fiber.
- D. This statement is not accurate. Tropomyosin does not form cross-bridges, and calcium ions do not directly bind to tropomyosin to cause them to form cross-bridges. The interaction between calcium ions, troponin, and tropomyosin regulates the exposure of myosin-binding sites on actin, enabling cross-bridge formation between actin and myosin.
Q55. According to the theory of natural selection, organisms produce:
- A. More offspring than supported✓
- B. Less offspring than supported
- C. Offspring according to the resources available
- D. Offspring to create resources
Explanation: According to theory of natural selection, those organisms whose inherited characterstics fit them best to their enviroment are likely to leave more offsprings than the less fit individuals.
Q56. A person was married to his cousin and both are heterozygous for Sickle Cell anemia. Among their four kids, what will be the proportion of homozygotes?
- A. 75%
- B. 50%✓
- C. 100%
- D. 25%
Explanation: As can be seen from the cross below, 50 percent of the offspring are heterozygotes, i.e. 50 percent possess the sickle cell trait. 25 percent are normal i.e. homozygous for HbN, while 25 percent have sickle cell anemia, i.e. homozygous for HbS. In total, 50 percent are homozygous (25 percent plus 25 percent) so, option B is correct.
Why the other options are wrong
- A. As can be seen from the cross below, 50 percent of the offspring are heterozygotes, i.e. 50 percent possess the sickle cell trait. 25 percent are normal i.e. homozygous for HbN, while 25 percent have sickle cell anemia, i.e. homozygous for HbS. In total, 50 percent are homozygous (25 percent plus 25 percent) so, option B is correct.
- C. As can be seen from the cross below, 50 percent of the offspring are heterozygotes, i.e. 50 percent possess the sickle cell trait. 25 percent are normal i.e. homozygous for HbN, while 25 percent have sickle cell anemia, i.e. homozygous for HbS. In total, 50 percent are homozygous (25 percent plus 25 percent) so, option B is correct.
- D. As can be seen from the cross below, 50 percent of the offspring are heterozygotes, i.e. 50 percent possess the sickle cell trait. 25 percent are normal i.e. homozygous for HbN, while 25 percent have sickle cell anemia, i.e. homozygous for HbS. In total, 50 percent are homozygous (25 percent plus 25 percent) so, option B is correct.
Q57. The major function of basophils is to:
- A. Destroy small particles by phagocytosis
- B. Release heparin to prevent blood clotting✓
- C. Transport oxygen
- D. Inactivate inflammation producing substances
Explanation: Basophils have a variety of functions, including mediating inflammatory and allergic responses as they contain histamine, in addition to preventing blood clotting as they contain heparin, which is a blood thinner/anticoagulant.
Why the other options are wrong
- A. Option A describes phagocytosis, which is primarily mediated by neutrophils and macrophages (phagocytes).
- C. Option C describes the process of red blood cells.
- D. Option D may describe the action of certain anti-inflammatory substances, which may include drugs.
Q58. Which enzyme is administered to the patients of Severe Combined Immunodeficiency Disease (SCID)?
- A. Adenosine Deaminase (ADA)✓
- B. Pancreatic Enzyme
- C. ß-galactosidase
- D. ß-lactamase
Explanation: 'SCID' is due to Adenosine Deaminase (ADA) deficiency so, it is administered to overcome the deficiency. Hence, option A is correct. Pancreatic enzymes (B) partake in digestion. Beta-galactosidase (C) breaks down lactose into glucose and galactose in certain organisms. Beta-lactamase (D) is an enzyme produced by bacteria, that confers their resistance against beta-lactam drugs, such as penicillin, as it breaks down the beta-lactam ring present in these drugs.
Why the other options are wrong
- B. Pancreatic enzymes (B) partake in digestion.
- C. Beta-galactosidase breaks down lactose into glucose and galactose in certain organisms.
- D. Beta-lactamase is an enzyme produced by bacteria, that confers their resistance against beta-lactam drugs, such as penicillin, as it breaks down the beta-lactam ring present in these drugs.
Q59. Given below, is the diagram of a nephron without a vascular supply.What is the name of Part C?
- A. Collecting tubule
- B. Proximal tubule
- C. Distal tubule✓
- D. Loop of Henle
Explanation: Part A is the Bowman's capsulePart B is the Descending limb of the loop of henle.Part C is the Distal tubule so, option C is the correct answer.Part D is the Collecting duct.
Why the other options are wrong
- A. The collecting duct system of the kidney consists of a series of tubules and ducts that physically connect nephrons to a minor calyx or directly to the renal pelvis.
- B. Proximal tubules are responsible for reabsorbing approximately 65% of filtered load and most, if not all, of filtered amino acids, glucose, solutes, and low molecular weight proteins. Proximal tubules also play a key role in regulating acid-base balance by reabsorbing approximately 80% of filtered bicarbonate.
- D. Loop of Henle, long U-shaped portion of the tubule that conducts urine within each nephron of the kidney of reptiles, birds, and mammals. The principal function of the loop of Henle is in the recovery of water and sodium chloride from urine.
Q60. Inside ovary, primary oocyte divides through first meiotic division, forming two haploid cells, the secondary oocyte and:
- A. Ovum
- B. Oogonium
- C. Follicle cell
- D. Polar body✓
Explanation: Inside the ovary, during the process of oogenesis, the primary oocyte undergoes the first meiotic division, resulting in the formation of two haploid cells. These cells are the secondary oocyte and a smaller cell called the first polar body. The first polar body is a smaller cell that contains a portion of the genetic material but minimal cytoplasm. The polar bodies typically do not play a direct role in fertilization and are eventually broken down or reabsorbed.
Why the other options are wrong
- A. Option A, the ovum, is the mature haploid female gamete or egg cell formed after the second meiotic division.
- B. Option B, oogonium, is the first stage of oogenesis which gives rise to subsequent oocytes, and as such is not a product of meiotic division.
- C. Option C, follicle cells, are the cells which surround the developing egg cell within the ovary.
Q61. Genetic engineering has been successfully used to produce?
- A. Animals, with inferior traits
- B. Transgenic mice for testing the safety of the polio vaccine before use in humans✓
- C. Animals, that have the same genetic constitution
- D. None of the above
Explanation: Transgenic mice are being formed for use in testing the safety of vaccines before they are used on human beings. Transgenic mice are being used to test the safety of the polio vaccine. Many transgenic animals are developed to increase our understanding of how genes contribute to the development of disease so, that investigation of new treatments for diseases is made possible. Now transgenic models exist for many human diseases such as cancer, cystic fibrosis, rheumatoid arthritis, Alzheimer's disease, hemophilia, thalassemia, etc. Therefore, the correct answer is option B.
Why the other options are wrong
- A. Genetic engineering is typically aimed at improving or modifying traits in organisms rather than producing animals with inferior traits. The goal is often to introduce beneficial characteristics.
- C. This statement is not entirely accurate. While cloning can produce animals with the same genetic constitution as the donor organism, genetic engineering usually involves the introduction of specific genes or genetic modifications, resulting in organisms with altered or enhanced traits.
- D. This is not the correct answer. Genetic engineering has been successfully used for various purposes, including the production of transgenic animals for research and other applications.
Q62. In plants, which sugar is transported from source to sink through sieve tubes?
- A. Glucose
- B. Sucrose✓
- C. Fructose
- D. None of the above
Explanation: Factual recall; Glucose is the monosaccharide, that makes up the disaccharide sucrose along with fructose, whereas sucrose is the form, in which sugar is transported from source to sink. Sucrose is broken down to its constituents and then used by tissue cells.
Why the other options are wrong
- A. Factual recall: Glucose is the monosaccharide, that makes up the disaccharide sucrose along with fructose, whereas sucrose is the form, in which sugar is transported from source to sink. Sucrose is broken down to its constituents and then used by tissue cells.
- C. Fructose is a monosaccharide, or a simple sugar, that is naturally found in fruits, honey, and certain vegetables. It is one of the three main dietary sugars, along with glucose and galactose. Fructose is sweeter than glucose and is often used as a sweetener in processed foods and beverages
Q63. Which of the following hormone stimulates the ovulation from the follicle into oviduct?
- A. Estrogen
- B. Progesterone
- C. Luteinizing hormone✓
- D. Follicle stimulating hormone
Explanation: Option A, estrogen, is the hormone that causes the development and thickening of the endometrial lining.Option B, progesterone, is the hormone, secreted by the corpus luteum, to maintain and thicken the endometrial lining, making it ready for implantation.Option C, LH, is the main trigger of ovulation, as a surge in LH causes the release of the secondary oocyte from the Graafian follicle into the oviduct. Hence, it is the correct option. Option D, FSH, is responsible for the development of follicles in the ovary.
Why the other options are wrong
- A. Option A, estrogen, is the hormone that causes the development and thickening of the endometrial lining.
- B. Option B, progesterone, is the hormone, secreted by the corpus luteum, to maintain and thicken the endometrial lining, making it ready for implantation.
- D. Option D, FSH, is responsible for the development of follicles in the ovary.
Q64. Which one is an example of a Nucleotide?
- A. Adenosine
- B. NAD
- C. ATP✓
- D. Guanine
Explanation: ATP is a nucleotide, as it contains a pentose sugar, an adenine base, and three phosphate groups. A nucleotide may have one or more phosphate groups.
Why the other options are wrong
- A. A nucleotide consists of three components; a pentose sugar, a nitrogenous base, and at least one phosphate group.adenosine is a nucleoside, as it consists of a pentose sugar and an adenine base but does not contain any phosphate group.
- B. It is nicotinamide dinucleotide, which is a dinucleotide, where one nucleotide, containing adenine, is covalently bound to another base containing nicotinamide. It may fit the description of a nucleotide, but a better option would be to select a mononucleotide since NAD itself consists of two nucleotides.
- D. It is simply a nitrogenous base.
Q65. Four plants are present in different environmental conditions. Plant A is present in a warm climate with continuous rainfall, plant B is present in a cool forest, plant C is present in a warm climate with little breeze, while plant D is present in a warm climate with high wind speed. Which one of the above plants will have the highest rate of transpiration?
- A. Plant B
- B. Plant D✓
- C. Plant A
- D. Plant C
Explanation: When it comes to questions like these, do not confuse the option letter with the letter of the plant itself. The factors which affect the rate of transpiration are: temperature, as at a higher temperature, more water vapour is given up by the leaves of the plant; humidity, as more humid conditions decrease the concentration gradient of water vapour between the air spaces of the leaves and the atmosphere so, the rate of transpiration decreases; wind speed, as a greater wind speed moves away more of the water vapour collected around the leaves and stomata, thereby increasing the concentration gradient between the air spaces of the leaves and the atmosphere. Plant A has a warm atmosphere but has continuous rainfall. Rainfall would imply a humid atmosphere so, the rate of transpiration is not very high. Plant B has a cool atmosphere so, the rate is low. Plant C is present in a warm climate but the breeze is slow so, when wind speed is low, more water vapour accumulates around the leaves of the plant thereby reducing the concentration gradient between the air spaces and the atmosphere. Hence, the rate of transpiration is not very high. Plant D is present in a warm climate in addition to having a high wind speed so, both factors contribute to a high rate of transpiration. Hence, the option which mentions plant D is the correct answer, which is option B.
Why the other options are wrong
- A. Plant B has a cool atmosphere so, the rate is low.
- C. Plant A has a warm atmosphere but has continuous rainfall. Rainfall would imply a humid atmosphere so, the rate of transpiration is not very high.
- D. Plant C is present in a warm climate but the breeze is slow so, when wind speed is low, more water vapour accumulates around the leaves of the plant thereby reducing the concentration gradient between the air spaces and the atmosphere. Hence, the rate of transpiration is not very high.
Q66. The protein coat of virus is called:
- A. Capsid✓
- B. Cosmid
- C. Capsomere
- D. Chromophore
Explanation: The outer protein coat of a virus is known as 'the capsid'. It consists of several oligomeric structural subunits made of a protein called protomers, which cover the nucleic acid, present in the virus, and protects it when the virus inserts itself into the host. The capsid proteins also help the virus attach and penetrate the host cells, thereby infecting the host. Hence, option A is correct.
Why the other options are wrong
- B. Cosmids, on the other hand, are not related to viruses. They are a type of hybrid plasmid used in molecular biology for gene cloning.
- C. Capsomeres are subunits of the capsid. They are the proteinaceous building blocks that make up the capsid structure.
- D. Chromophores are molecules or groups within molecules that give rise to color. This term is not specifically related to the protein coat of viruses.
Q67. If stimulation is above _, impulses travel to the brain along the sensory neuron.
- A. Action Potential
- B. Resting Potential
- C. Threshold✓
- D. Recovery Period
Explanation: The threshold is the minimum level of stimulation required for a neuron to generate an action potential. If the stimulation is above the threshold, impulses can travel to the brain along sensory neurons, initiating the transmission of sensory information.
Why the other options are wrong
- A. This option is incorrect because an action potential is a rapid change in the membrane potential of a neuron that occurs once the threshold is reached, allowing the neuron to transmit signals, but it doesn't indicate the level of stimulation required for impulses to travel to the brain along a sensory neuron.
- B. This option is incorrect as resting potential refers to the stable voltage across a neuron's membrane when it's not transmitting signals, and it doesn't specify the threshold needed for impulses to travel to the brain via sensory neurons.
- D. This option is incorrect because the recovery period is a phase after an action potential when a neuron is temporarily less responsive to new stimuli, but it doesn't determine the threshold for impulses to travel to the brain through sensory neurons.
Q68. The covalent bond or bridge between two monosaccharides to form a disaccharide is called a:
- A. Carboxyl bond
- B. Hydrogen bond
- C. Hydroxyl bond
- D. Glycosidic bond✓
Explanation: Hydrogen bond: Hydrogen bonds are weak electrostatic attractions between a hydrogen atom in a polar covalent bond and an electronegative atom (such as oxygen, nitrogen, or fluorine) in another molecule. While hydrogen bonding can play a role in the interactions between monosaccharides or other biomolecules, it is not the bond that joins two monosaccharides to form a disaccharide. Hydroxyl bond: A hydroxyl bond is not a commonly used term in chemistry. The correct term to describe the bond between two monosaccharides to form a disaccharide is a glycosidic bond. Glycosidic bond: The correct option is glycosidic bond. A glycosidic bond is a covalent bond that forms when a hydroxyl group (-OH) on one monosaccharide reacts with the anomeric carbon (the carbon containing the carbonyl group, usually the first carbon) of another monosaccharide. This reaction involves the elimination of a water molecule (H2O), resulting in the formation of a glycosidic linkage between the two monosaccharides. Disaccharides, such as maltose, lactose, and sucrose, are formed by glycosidic bonds between two monosaccharides.In summary, option d) Glycosidic bond is the correct option. A glycosidic bond is the covalent bond between two monosaccharides that forms a disaccharide or other types of oligosaccharides.
Why the other options are wrong
- A. A carboxyl bond is not a term used to describe the bond between two monosaccharides to form a disaccharide. A carboxyl bond typically refers to a covalent bond formed between a carbon atom and an oxygen atom in a carboxyl group (COOH), which is present in organic acids like fatty acids and amino acids.
- B. Hydrogen bonds are weak electrostatic attractions between a hydrogen atom in a polar covalent bond and an electronegative atom (such as oxygen, nitrogen, or fluorine) in another molecule. While hydrogen bonding can play a role in the interactions between monosaccharides or other biomolecules, it is not the bond that joins two monosaccharides to form a disaccharide.
- C. A hydroxyl bond is not a commonly used term in chemistry. The correct term to describe the bond between two monosaccharides to form a disaccharide is a glycosidic bond.
Q69. The structure of a fibrous protein comprises of polypeptide chains in the form of:
- A. Cluster
- B. Spherical or curried up ball
- C. Long strands or fibrils✓
- D. Flat uncoiled chains
Explanation: The options describe different conformations of polypeptide chains. Option A describes a formation, not characteristic of fibrous proteins.Option B describes the conformation of globular proteins.Option C describes that of fibrous proteins.Option D most probably is indicative of beta pleated sheets or another structure, not characteristic of fibrous protein.
Q70. Taxonomy includes the arrangement of organisms into different taxa. Which of the following represents the correct hierarchy of various taxa of classification?
- A. Species, genus, family, order, class, phylum✓
- B. Order, family, class, phylum, kingdom
- C. Species, genus, family, class, order, phylum
- D. Species, genus, order, family, class, phylum
Explanation: The correct hierarchy of various taxa in biological classification is:Species, genus, family, order, class, phylumExplanation:1. Species: The fundamental unit of classification, consisting of organisms that can interbreed and produce fertile offspring.2. Genus: A group of closely related species.3. Family: A group of related genera.4. Order: A group of related families.5. Class: A group of related orders.6. Phylum: A group of related classes.This hierarchical arrangement helps organize and categorize living organisms based on their evolutionary relationships. Mnemonics, that one can use to memorize the taxonomic hierarchy, which is Domain, Kingdom, Phylum, Class, Order, Family, Genus, and Species, in that specific order are as follows:-“Dear King Philip Came Over For Good Soup" (the first letter of each word corresponds to a taxa)- Kingdom Phylum went to a Class and Ordered his Family to look for a Genius(Genus) who is a rare Species. The diagram, given below, illustrates the hierarchy.
Why the other options are wrong
- B. The correct hierarchy of various taxa in biological classification is:Species, genus, family, order, class, phylumExplanation:1. Species: The fundamental unit of classification, consisting of organisms that can interbreed and produce fertile offspring.2. Genus: A group of closely related species.3. Family: A group of related genera.4. Order: A group of related families.5. Class: A group of related orders.6. Phylum: A group of related classes.This hierarchical arrangement helps organize and categorize living organisms based on their evolutionary relationships.
- C. The correct hierarchy of various taxa in biological classification is:Species, genus, family, order, class, phylumExplanation:1. Species: The fundamental unit of classification, consisting of organisms that can interbreed and produce fertile offspring.2. Genus: A group of closely related species.3. Family: A group of related genera.4. Order: A group of related families.5. Class: A group of related orders.6. Phylum: A group of related classes.This hierarchical arrangement helps organize and categorize living organisms based on their evolutionary relationships.
- D. The correct hierarchy of various taxa in biological classification is:Species, genus, family, order, class, phylumExplanation:1. Species: The fundamental unit of classification, consisting of organisms that can interbreed and produce fertile offspring.2. Genus: A group of closely related species.3. Family: A group of related genera.4. Order: A group of related families.5. Class: A group of related orders.6. Phylum: A group of related classes.This hierarchical arrangement helps organize and categorize living organisms based on their evolutionary relationships.
Q71. The Plasmid pBR322 has antibiotic resistance genes for:
- A. Streptomycin
- B. Ampicillin and Tetracycline✓
- C. Tetracycline and doxycycline
- D. Ampicillin
Explanation: Factual recall;pBR322 is base pairs in length and has two antibiotic resistance genes - the gene 'bla', encoding the ampicillin resistance (AmpR) protein, and the gene 'tetA', encoding the tetracycline resistance (TetR) protein.
Why the other options are wrong
- A. Streptomycin resistance is not a feature of the pBR322 plasmid. The resistance genes on pBR322 are specifically for ampicillin and tetracycline.
- C. While pBR322 carries a tetracycline resistance gene, it does not include a gene for doxycycline resistance. The correct combination is ampicillin and tetracycline.
- D. This is partially correct. pBR322 does carry an ampicillin resistance gene, but it also has a tetracycline resistance gene. The plasmid confers resistance to both ampicillin and tetracycline.
Q72. Which of the following blood vessels contain semilunar valves?
- A. Arteries
- B. Capillaries
- C. Veins✓
- D. Arterioles
Explanation: Valves in veins are one-way(semi lunar) flaps that help prevent blood from flowing backward in the circulatory system. They play a crucial role in maintaining blood flow towards the heart and preventing the backflow of blood. This mechanism is particularly important in the legs, where gravity can make it harder for blood to return to the heart, leading to conditions like varicose veins when the valves don't function properly.
Why the other options are wrong
- A. Semilunar valves are present in veins.Its a factual recall present is Sindh Text book.
- B. Semilunar valves are present in veins.Its a factual recall present is Sindh Text book.
- D. Semilunar valves are present in veins.Its a factual recall present is Sindh Text book.
Q73. The main nitrogenous excretory product of humans is:
- A. Ammonia
- B. Urea✓
- C. Ammonium
- D. Uric acid
Explanation: Option A, Ammonia, is the primary excretory product in certain animals such as fishes, aquatic amphibians, aquatic insects, tadpoles, etc. as ammonia is extremely soluble in nature and excreted via simple diffusion in aquatic animals. It is not the main nitrogenous excretory product in humans, as due to its high solubility, it would need a very large amount of water to be excreted, which would be unfavorable for humans.Option B, Urea, is the correct answer. Urea is relatively less toxic and requires less water than ammonia to excrete so, it is the main nitrogenous excretory product in humans as it best suits the organism’s condition and needs.Option C, Ammonium, is a derivative of ammonia or its ionic form so, the same concept, associated with ammonia, applies here.Option D, Uric Acid, is the chief excretory product in organisms such as birds, cockroaches, snakes, lizards, and other terrestrial insects, which excrete it in a solid or semisolid form. Uric Acid is the least soluble of the waste products so, it requires less water. Humans excrete a small portion of this because if a large amount of it were to accumulate, it would precipitate and form uric acid stones, thereby damaging the urinary system.
Why the other options are wrong
- A. Ammonia is very toxic and dissolves quickly in body fluids. Thus, it must be kept in low concentration in the body. To maintain its low concentration below that of body requires large volume of water also to eliminate it in urine as it is produced.
- C. The ammonium cation is a positively charged polyatomic ion with the chemical formula NH+4 or [NH₄]⁺. It is formed by the protonation of ammonia.
- D. Animals inhabiting environment with acute shortage of water supply require an excretory product which can be excreted with minimum amount of water. Only 1ml water is required to eliminate 1g of nitrogen in the form of uric acid.
Q74. Water and Minerals move down their concentration gradient through plasmodesmata to cells of cortex, endodermis, pericycle, and then to sap in the xylem cells. This is also known as the:
- A. Vacuolar pathway
- B. Apoplastic pathway
- C. Symplast Pathway✓
- D. Mineral absorption Pathway
Explanation: The symplast pathway, involves movement of water from one cell to the other by plasmodesmata, hence water moves from cytoplasm of one cell to the cytoplasm of the other cell via the plasmodesmata, connecting them. This scenario is mentioned in the question, hence C is the correct answer.
Why the other options are wrong
- A. The vacuolar pathway, involves movement of water molecules in plant cells via the central vacuoles, located within the plant cells. Vacuolar involvement was not mentioned in the question.
- B. In apoplastic pathway, water moves from cell to cell via the cell walls of the plant cells and does not enter the cytoplasm. Since the question does not mention the involvement of cell wall, and it mentions passage through plasmodesmata (which are strips of cytoplasm that passes through adjacent cells), apoplastic pathway is not used here.
- D. Mineral absorption pathway, describes the way that minerals are taken up by plant cells, typically following the same pathway as water. Minerals may be taken up via simple diffusion or active transport. Water movement, not mineral transport, was mentioned in the question.
Q75. If 15 um size object is observed under light microscope, using 5X eyepiece and 10X objective, its magnified image size will be:
- A. 750 um✓
- B. 50 um
- C. 500 um
- D. 250 um
Explanation: Recall the formula for magnification, where Image Size (I)= Actual Size (A) x Magnification (M), or I=A x M. The magnification is the product of the eyepiece lens and objective lens’ respective magnifications so; M= 5 x 10 = 50. The question asks for the size of the image so; I=A x M = 15 x 50 = 750 um.
Why the other options are wrong
- B. This option is incorrect.
- C. This option is incorrect.
- D. Recall the formula for magnification, where Image Size (I)= Actual Size (A) x Magnification (M), or I=A x M. The magnification is the product of the eyepiece lens and objective lens’ respective magnifications so; M= 5 x 10 = 50. The question asks for the size of the image so; I=A x M = 15 x 50 = 750 um.
Q76. A person got an infection, he became ill but then he survived. What do you think which of immunity he would have developed?
- A. Active immunity
- B. Artificially induced active immunity
- C. Passive immunity
- D. Naturally induced active immunity✓
Explanation: Naturally induced active immunity occurs when the body's immune system responds to an actual infection by pathogens or exposure to antigens in the environment. In this process, the immune system recognizes the invading pathogens, such as bacteria or viruses, and mounts a specific and targeted immune response. During the course of the infection, the immune system produces antibodies and memory cells. Antibodies help in the elimination of the pathogens, while memory cells "remember" the specific antigens, providing the basis for a faster and more robust immune response upon subsequent exposure to the same pathogen. This form of immunity is a natural consequence of the body's encounters with various infectious agents throughout life.
Why the other options are wrong
- A. 'Active immunity' is when the body itself gets exposed to the antigen to generate an immune response, whereby memory cells are produced which confer long lasting or lifelong immunity against the particular agent. This response may take some time to develop.
- B. In 'artificial active immunity', the immunity is produced by intentionally exposing the individual to antigens in a vaccine (hence the term artificial, since exposure did not occur naturally).
- C. Passive immunity occurs when an individual receives antibodies or immune components produced by another organism rather than by their own immune system. There are two main types: Natural Passive Immunity:This occurs when antibodies are transferred from mother to baby during pregnancy or through breast milk. The newborn benefits from the mother's antibodies for a temporary period, providing protection against certain infections. Artificial Passive Immunity:This involves the administration of pre-formed antibodies obtained from another individual or animal. This can provide immediate but temporary protection. For example, injecting someone with antibodies against a specific pathogen can offer rapid defense in situations like exposure to a disease or venom.
Q77. The nitrogen-containing bases in nucleotide are of two types; Purines and Pyrimidines. The purines bases are:
- A. Adenine, Guanine, and Cytosine
- B. Guanine and Cytosine
- C. Adenine and Guanine✓
- D. Adenine and Thymine
Explanation: Purine bases are adenine and guanine, while pyrimidine bases are thymine, cytosine, and uracil. Option C is the only option that mentions only purine bases, while the others mention a combination of purine and pyrimidine bases.
Why the other options are wrong
- A. It is incorrect.
- B. It is incorrect.
- D. It is incorrect.
Q78. The process in which a complementary copy of the code from a gene is produced by RNA Polymerase in the nucleus:
- A. Transcription✓
- B. Translation
- C. Proofreading
- D. DNA Replication
Explanation: Transcription, is when RNA polymerase makes a copy of a gene on a template DNA strand in the nucleus; this copy is messenger RNA.
Why the other options are wrong
- B. Translation, is when ribosomes translate the code on the mRNA and produce a corresponding protein or polypeptide chain in the cytoplasm.
- C. Proofreading, is when the newly-formed DNA or RNA is checked for any errors in replication or production.
- D. DNA replication, is when the DNA of a cell is replicated via complementary base pairing in a semi-coservative manner.
Q79. Among the following, which cellular organelle contains circular DNA, similar to those found in bacteria?
- A. Lysosome
- B. Nucleus
- C. Nucleosome
- D. Mitochondria✓
Explanation: Chloroplasts and mitochondria are the two organelles, that contain circular DNA similar, to those found in prokaryotic cells, along with 70S ribosomes, which are also similar to the ones in prokaryotes, such as in bacteria. This can be traced back to the endosymbiotic theory, where mitochondria and chloroplasts are understood to be ancient prokaryotes.
Why the other options are wrong
- A. It does not contain DNA.
- B. It contains linear DNA.
- C. It does not contain circular DNA similar to prokaryotes.
Q80. The following flowchart depicts the steps of the Calvin Cycle. Which option, according to you, fits in as the correct answer of the missing step?
- A. Pyruvate
- B. Hydrogenase
- C. Ribulose bisphosphate✓
- D. Oxaloacetate
Explanation: The first step involves the fixing of carbon (derived from CO2) into molecules of Ribulose Bisphosphate (RuBP) via the action of the enzyme 'rubisco', resulting in the formation of 3-phosphoglycerate. This is further processed into 1,3-BPG and eventually, G-3-P, before the cycle starts again. The chart above only has RuBP missing.
Why the other options are wrong
- A. Pyruvate, is the product of glycolysis and thus, is not involved in the Calvin cycle.
- B. Hydrogenase, is an enzyme, that catalyzes the reduction of a particular substance by hydrogen. It may be involved in the reduction of 1,3-BPG into G-3-P, but the question does not ask for this step.
- D. Oxaloacetate, is a substrate present within the Krebs Cycle and not the Calvin cycle.
Q81. Given figure shows:
- A. Structure of a Lenticel✓
- B. Hydathode showing gaseous vapour exchange
- C. Fungus reproducing by spore formation
- D. Algae reproducing by spore formation
Explanation: The figure shows the structure of 'Lenticel', which facilitates gaseous exchange and transpiration. These are aerating pores in the bark of woody trees. These are surrounded by loosely arranged thin walled complementary cells, enclosing intercellular spaces for gaseous exchange.
Why the other options are wrong
- B. This option is incorrect, as the following figure shows the structure of a lenticel.
- C. This option is incorrect, as the following figure shows the structure of a lenticel.
- D. This option is incorrect, as the following figure shows the structure of a lenticel.
Q82. Xerophytes have small, thick leaves to:
- A. Help them float on water
- B. Limit water loss, by increasing the surface area
- C. Help them survive in salty environment
- D. Limit water loss, by reducing the surface area✓
Explanation: Xerophytes are plants that are adapted to survive in environments, with very little water. Option A describes a feature of a hydrophyte, that grows on water.Option B describes the correct feature, which is limiting the loss of water, but this is not done by 'increasing the surface area'. Water loss is limited by 'decreasing the surface area of the leaves'.Option C describes a feature of halophytes, which grow in conditions of high salt content in the soil or water.Option D describes the correct feature along with the correct adaptation, i.e. limiting water loss by 'reducing the surface area' of the leaves, as xerophytes need to conserve water and they do this by having small leaves, with a thick waxy coating and sunken stomata.
Why the other options are wrong
- A. This option is incorrect, as xerophytes have small, thick leaves to limit water loss, by reducing the surface area.
- B. This option is incorrect, as xerophytes have small, thick leaves to limit water loss, by reducing the surface area.
- C. This option is incorrect, as xerophytes have small, thick leaves to limit water loss, by reducing the surface area.
Q83. Passive processes for the movement of molecules across cell surface membrane are:
- A. Facilitated diffusion and osmosis✓
- B. Diffusion and exocytosis
- C. Pinocytosis and facilitated diffusion
- D. Osmosis and phagocytosis
Explanation: Osmosis, diffusion and facilitated diffusion are passive processes of passage of molecules across the cell membrane but exocytosis and endocytosis are active processes of molecules across the cell.
Why the other options are wrong
- B. Diffusion is a passive process while exocytosis is an active process.
- C. Pinocytosis is an active process while facilitated diffusion is a passive process.
- D. Osmosis is a passive process and phagocytosis is an active process.
Q84. During the G2 phase:
- A. Chromosome number is duplicated.
- B. The chromosomes are left with only one chromatid.
- C. Energy is stored for chromosome movement and mitotic specific proteins (Tubulin) are produced.✓
- D. Specific enzymes are synthesized and DNA base units are accumulated.
Explanation: Option A occurs during the S phase, where DNA is replicated. Option B occurs after the M phase, when the cell has divided. Option C is 'G2', which occurs right before mitosis. Steps are taken to prepare the cell for cell division, and they include storing energy for chromosome movement and production of tubulin proteins, which are microtubule subunits that will be used in the formation of spindle fibers in the M phase. Option D is G1 phase, where the cell prepares for DNA replication so, enzymes, such as DNA polymerase, are synthesized along with nucleotides that will be used to form new DNA.
Why the other options are wrong
- A. It occur during the S phase, where DNA is replicated.
- B. It occurs after the M phase, when the cell has divided.
- D. It occurs in G1 phase, where the cell prepares for DNA replication so, enzymes, such as DNA polymerase, are synthesized along with nucleotides that will be used to form new DNA.
Q85. During inspiration, the space inside the chest cavity is increased due to:
- A. The relaxation of the muscles of the diaphragm
- B. Relaxation of the external intercostal muscles
- C. Increased pressure
- D. The contraction of the muscles of the diaphragm✓
Explanation: Option A occurs during expiration, as the diaphragm’s muscles relax, causing the chest cavity space to decrease and the air is pushed out.Option B also occurs during expiration, as in inspiration, the external intercostal muscles contract while the inner ones relax, and in expiration, the external intercostal muscles relax and inner ones contract.Option C occurs during expiration, as the volume of the chest cavity decreases, causing an increase in pressure which drives the movement of air back into the atmosphere. The reverse process occurs in inspiration.Option D occurs during inspiration, as the diaphragm muscles contract, causing the diaphragm to flatten. This increases the volume of the chest cavity (along with the external intercostal muscles, contracting, and inner ones, relaxing, resulting in the ribcage, moving upwards and outwards), which causes a decrease in pressure, resulting in the movement of air into the lungs from the atmosphere.
Why the other options are wrong
- A. This option is incorrect, as during inspiration, the space inside the chest cavity is increased due to the contraction of the muscles of the diaphragm.
- B. This option is incorrect, as during inspiration, the space inside the chest cavity is increased due to the contraction of the muscles of the diaphragm.
- C. This option is incorrect, as during inspiration, the space inside the chest cavity is increased due to the contraction of the muscles of the diaphragm.
Q86. A student of chemical engineering mistakenly engulfed the toxic compound "A" which was a potent inhibitor of a certain enzyme. He was immediately brought to a hospital where the doctor injected, intravenously, substrate "B" to minimize the toxic effect of Compound A. His life was saved from serious damage. The treatment method shows that compound A was a _ inhibitor.
- A. Non competitive
- B. Irreversible
- C. Temperature sensitive
- D. Competitive reversible✓
Explanation: 'Compound A' caused a toxic effect by inhibiting the action of a certain enzyme. 'Substrate B' was injected, which minimized the toxic effect of compound A, and this toxic effect was brought about by inhibiting the enzyme. The addition of a larger quantity of substrate allowed the enzyme to work to its normal capacity once again, as the inhibitory or toxic effect of compound A was minimized. Competitive reversible inhibitors compete with the substrate for the active site and if there is a greater amount of the substrate, the active site is more likely to bind to the substrate, rather than the inhibitor so, the activity of the enzyme is restored. This is the exact scenario described in the question, as the inhibitory effect was reversed upon addition of more substrate. Hence, the correct option is D. Option A, non-competitive inhibitors, decrease the Vmax of the enzyme so, addition of more substrate will not change or restore the enzyme's effectiveness. Option B, irreversible inhibitors, would have an effect that cannot be reversed under any circumstances so, addition of substrate would have no effect. Option C, temperature sensitive inhibitor has no relevance to the given scenario as temperature has not been mentioned as a factor in the question.
Q87. Which is an example of a Disaccharide?
- A. Starch
- B. Lactose✓
- C. Fructose
- D. Glycogen
Explanation: Option A is a polysaccharide, consisting of glucose subunits joined together to form a large chain. (starch and glycogen are polysaccharides)Option B is a disaccharide, consisting of two monosaccharides, glucose and galactose, joined together. (sucrose, maltose, and lactose are all disaccharides)Option C is a monosaccharide (fructose, glucose, and galactose are monosaccharides).Option D is a polysaccharide.
Q88. In glycine, R is _.
- A. Ethane
- B. Fatty acid
- C. H atom✓
- D. Competitive reversible
Explanation: Glycine is the simplest amino acid, with its R group (the side chain of an amino acid) consisting of just a single hydrogen atom. Hence, option C is correct.
Q89. Sequence of amino acids, in a polypeptide chain of protein molecule, corresponds to the sequence of nucleotides on mRNA for that protein. If the reading frame of mRNA for a human protein is 993 nucleotides, including a stop codon at the end, how many amino acids would be incorporated in the polypeptide chain?
- A. 93
- B. 330✓
- C. 331
- D. 993
Explanation: Codon consists of three nucleotides, and each codon corresponds to a single amino acid. A stop codon, however, does NOT code for an amino acid; they signal the end or termination of the polypeptide chain. Hence, out of the 993 nucleotides, the last three correspond to a stop codon and hence 990 nucleotides are to be considered. 990 nucleotides correspond to 330 codons (990 divided by 3), and since each codon codes for a single amino acid, 330 codons will code for 330 amino acids, hence, the answer is B.
Why the other options are wrong
- A. It is incorrect.
- C. It is incorrect.
- D. It is incorrect.
Q90. Blood group AB is an example of _ .
- A. Complete dominance
- B. Recessive alleles
- C. Co-dominance✓
- D. Incomplete dominance
Explanation: Option A describes one allele being completely dominant over the other allele i.e. one allele is dominant while the other is recessive so, in a heterozygous condition, only the dominant allele is expressed as a trait. However, in the AB blood group, BOTH A and B antigens are expressed so, that one allele is not completely dominant over the other. Option B describes alleles that are only expressed in the phenotype in homozygous conditions; they will not be expressed if a dominant allele is present in heterozygous conditions. One allele is recessive over the other, but in this case, both traits are expressed. Option C is the correct answer, as it describes the scenario in which both alleles are equally expressed in the phenotype. Since both antigens are expressed individually, this means that both alleles are equally expressed. Option D describes a scenario in which the alleles are expressed in such a way that the phenotype is actually a mixture of intermediate expression of both alleles. The individual alleles are not expressed completely. For example, alleles of black and white fur color are not expressed as black and white spots, they are expressed as grey fur color, i.e. an intermediate or mixture of the two traits.
Why the other options are wrong
- A. Complete dominance is a form of dominance in the heterozygous condition wherein the allele that is regarded as dominant completely masks the effect of the allele that is recessive. For instance, for an individual carrying two alleles that are both dominant (e.g. AA), the trait that they represent will be expressed.
- B. A recessive allele does not produce a trait at all when only one copy is present. This contrasts to a dominant trait, which requires that only one of the two alleles be present to express the trait.
- D. Incomplete dominance is a form of Gene interaction in which both alleles of a gene at a locus are partially expressed, often resulting in an intermediate or different phenotype. It is also known as partial dominance.
Q91. As a result of replication, parental DNA would become completely dispersed and that each strand of all the daughter molecules would be a mixture of old and new DNA. This is called as:
- A. Dispersive idea✓
- B. Conservative idea
- C. Disruptive idea
- D. Semi-conservative idea
Explanation: It is 'dispersive replication', which involves each daughter strand containing both parental and new DNA, as the old DNA is broken up and randomly dispersed into each daughter strand.
Why the other options are wrong
- B. Conservative replication, which involves the entire parental double-stranded DNA molecule being conserved and an exact copy of the duplex being made.
- C. It is not a form of DNA replication.
- D. It is 'semi-conservative replication', where each strand of the parent duplex is conserved in each daughter strand, where a complimentary copy of the parental strand is made, such that each daughter duplex contains one parental strand and one new strand.
Q92. Smooth endoplasmic reticulum is responsible for the metabolism of:
- A. Carbohydrates✓
- B. Nucleic acids
- C. Proteins
- D. Lipids
Explanation: Mitochondria are responsible for the carbohydrate metabolis. To convert carbohydrates into CO2 , H20 and generate ATPs through cellular respiraton. SER also metabolis carbohydrates
Why the other options are wrong
- B. Nucleus, mitochondria and chloroplasts are responsible for nucleic acid metabolism.
- C. Ribosomes and RER are responsible for the protein synthesis.
- D. Smooth Endoplasmic Reticulum is responsible for the synthesis of lipids
Q93. Among followings, _ enzyme is naturally found in human immunodeficiency virus (HIV).
- A. Ligase
- B. Reverse Transcriptase✓
- C. RNA Polymerase
- D. DNA Polymerase
Explanation: HIV is a retrovirus. Its genome consists of RNA molecules, and it possesses a 'reverse transcriptase enzyme', which allows the virus to use its RNA as a template to construct copies of DNA, which it uses to incorporate into the genome of the host cell. The remaining enzymes (ligase, RNA, and DNA polymerase) are present in the host cell, which HIV uses for its own proliferation upon infecting the cell. Hence, the correct option is B.
Why the other options are wrong
- A. Ligase enzymes are present in various cellular compartments, including the cytoplasm, nucleus, and mitochondria. They are involved in the joining or sealing of DNA or RNA strands by catalyzing the formation of phosphodiester bonds. In the nucleus, DNA ligases play a crucial role in DNA replication, repair, and recombination. They are involved in sealing the nicks or gaps that occur during these processes. Ligase enzymes are present in various cellular compartments, including the cytoplasm, nucleus, and mitochondria. They are involved in the joining or sealing of DNA or RNA strands by catalyzing the formation of phosphodiester bonds.In the nucleus, DNA ligases play a crucial role in DNA replication, repair, and recombination. They are involved in sealing the nicks or gaps that occur during these processes.
- C. RNA polymerase is an enzyme responsible for synthesizing RNA molecules from a DNA template during the process of transcription. It plays a vital role in gene expression by converting the genetic information encoded in DNA into functional RNA molecules, such as messenger RNA (mRNA), transfer RNA (tRNA), and ribosomal RNA (rRNA).
- D. DNA polymerase is an enzyme responsible for catalyzing the synthesis of DNA molecules from deoxyribonucleotide triphosphates (dNTPs). It plays a crucial role in DNA replication, repair, and other DNA-related processes. The main function of DNA polymerase is to add nucleotides to the growing DNA strand during DNA synthesis.
Q94. The average atomic mass of Boron is 10.8. It has two isotopes of masses 10 and 11 respectively. What is the percentage of isotope with the average mass of 10?
- A. 20%✓
- B. 60%
- C. 80%
- D. 50%
Explanation: The formula for calculating the average atomic mass is[ (Mass of one isotope x percentage abundance) + (mass of other isotope x percentage abundance) divided by 100]. In this question, aside from using the formula for each option which would be a bit time consuming, you can take clues from the question itself. The average mass of Boron is 10.8, which is closer to 11 than 10. As such, you can conclude that the abundance of 10 isotope is lesser than the abundance of the 11 isotope, as such, its abundance MUST be less than 50%. The only option with an abundance less than 50 percent is option A, 20 percent. If you check this with the formula, the answer comes out to be correct: [(10 x 20) + (11 x 80) divided by 100] is 10.8.
Why the other options are wrong
- B. The only option with an abundance less than 50 percent is option A, 20 percent.
- C. The only option with an abundance less than 50 percent is option A, 20 percent.
- D. The only option with an abundance less than 50 percent is option A, 20 percent.
Q95. Which one of the following compounds is an additional polymer?
- A. Polyvinyl chloride✓
- B. Nylon
- C. Carbohydrate
- D. Polyester
Explanation: An 'addition polymer' is a polymer which consists of monomers, that add on to each other or combine without the formation of a secondary product, whereas in 'condensation polymers', the functional groups of monomers condense, such that a secondary product, such as H2O, is also formed. Out of all these options, only option A is an addition polymer, whereas all three others are condensation polymers.
Why the other options are wrong
- B. Out of all these options, only option A is an addition polymer, whereas all three others are condensation polymers.
- C. Out of all these options, only option A is an addition polymer, whereas all three others are condensation polymers.
- D. Out of all these options, only option A is an addition polymer, whereas all three others are condensation polymers.
Q96. Which of the following compounds will give a secondary alcohol after reaction with NaBH4?
- A. CH3COCH3✓
- B. CH3COOCH3
- C. CH3CH2CHO
- D. CH3CH2COOH
Explanation: Option A is a ketone, and its reduction (NaBH4 is a reducing agent) results in a secondary alcohol. This is because the carbonyl functional group is present in the middle of the chain so, the hydroxyl group is formed in the same place after reduction, giving a secondary alcohol. Option B is an ester, which does not undergo reduction with NaBH4.Option C is an aldehyde, that forms a primary alcohol, upon reduction, as its carbonyl group is towards the terminal end of the chain, thereby forming a terminal hydroxyl group. Option D is a carboxylic acid, which does not undergo reduction with NaBH4.
Why the other options are wrong
- B. Option B is an ester, which does not undergo reduction with NaBH.
- C. Option C is an aldehyde, that forms a primary alcohol, upon reduction, as its carbonyl group is towards the terminal end of the chain, thereby forming a terminal hydroxyl group.
- D. Option D is a carboxylic acid, which does not undergo reduction with NaBH4.
Q97. Select the reagent X from the following choices for this conversion:
- A. Acidified Potassium hydroxide
- B. Acidified Potassium dichromate (VI)✓
- C. Acidified Phosphoric acid
- D. Acidified Oxalic acid
Explanation: The reaction above is oxidation of a secondary alcohol into a ketone. As such, an oxidizing agent must be chosen for reagent X. Among the options, 'Potassium dichromate (VI)' is an oxidizing agent so, the correct option is B. Another answer could be 'potassium manganate (VII)', but it is not mentioned in any of the options. The other options do not oxidize alcohols.
Why the other options are wrong
- A. The other options do not oxidize alcohols. Another answer could be 'potassium manganate (VII)', but it is not mentioned in any of the options. The other options do not oxidize alcohols.
- C. The other options do not oxidize alcohols. Another answer could be 'potassium manganate (VII)', but it is not mentioned in any of the options. The other options do not oxidize alcohols.
- D. The other options do not oxidize alcohols. Another answer could be 'potassium manganate (VII)', but it is not mentioned in any of the options. The other options do not oxidize alcohols.
Q98. The pH of 10-2 M aqueous solution of sodium hydroxide is:
- A. 14
- B. 10
- C. 12✓
- D. 13
Explanation: The concentration of OH- in the 10-2 M solution of NaOH would be [10-2]. The pOH of this solution is -log (10-2) which is 2, and the pH is (14 - pOH), which equals 12.
Why the other options are wrong
Q99. Ketones can be made by oxidation of:
- A. Aldehydes
- B. Primary Alcohols
- C. Secondary Alcohols✓
- D. Tertiary Alcohols
Explanation: Option A; aldehydes oxidize into carboxylic acids. Option B; primary alcohols oxidize into aldehydes and then to carboxylic acids. Option C; secondary alcohols oxidize into ketones. Option D; tertiary alcohols are resistant to oxidation.
Why the other options are wrong
- A. Option A; aldehydes oxidize into carboxylic acids.
- B. Option B; primary alcohols oxidize into aldehydes and then to carboxylic acids.
- D. Option D; tertiary alcohols are resistant to oxidation.
Q100. In the following reaction sequence, product D will be:
- A. 1 - propanol
- B. Propanoic acid
- C. 2 - propanol✓
- D. Mixture of methanol and ethanol
Explanation: The above reaction scheme describes dehydrohalogenation of the alkyl halide into an alkene, followed by hydration of the alkene. The first step involves the reaction of propyl bromide with alcoholic KOH, which will result in elimination or dehydrohalogenation, whereby the halogen atom and adjacent carbon atom's hydrogen atom is removed, resulting in the formation of a double bond between the two carbons, forming propane, which is product C. Propene is acted upon by aqueous H2SO4, which implies hydration or addition of H2O, resulting in the formation of two products; the major product which is 2-propanol and the minor product which is 1-propanol so, the major product is the preferred option, i.e. option C.
Why the other options are wrong
Q101. Copper is a typical transition metal. Its atomic number is 29. In which oxidation state does it have a partially filled orbital in d-subshell?
- A. Cu
- B. Cu+
- C. Cu-
- D. Cu2+✓
Explanation: Electronic configuration of the options are as follows: Option A, Cu: 1s2 2s2 2p6 3s2 3p6 3d10 4s1, so its d subshell is filled Option B, Cu+: 1s2 2s2 2p6 3s2 3p6 3d10, so its d subshell is filled Option C, Cu-: 1s2 2s2 2p6 3s2 3p6 3d10 4s2, so its d subshell is filled. Option D, Cu2+: 1s2 2s2 2p6 3s2 3p6 3d9, so its d subshell is not filled completely, one orbital is partially filled, so it is the correct answer.
Why the other options are wrong
- A. Electronic configuration of Option A is as follows: Option A, Cu: 1s2 2s2 2p6 3s2 3p6 3d10 4s1, so its d subshell is filled.
- B. Electronic configuration of Option B is as follows: Option B, Cu+: 1s2 2s2 2p6 3s2 3p6 3d10, so its d subshell is filled.
- C. Electronic configuration of Option C is as follows:Option C, Cu-: 1s2 2s2 2p6 3s2 3p6 3d10 4s2, so its d subshell is filled.
Q102. The decomposition of phosphorus pentachloride in the presence of moisture takes place by the following mechanism. The rate equation for this reaction will be:
- A. Rate = k [POCl3][H2O]3
- B. Rate = k [PCl5][H2O]✓
- C. Rate = k [PCl5][H2O]4
- D. Rate = [PCl5][H2O]
Explanation: For the rate equation, the reactants of ONLY the rate-determining step, which is the slow step, are taken into account in a multi-step reaction, NOT the overall equation or the fast step. Since the slow step here consists of one mole of PCL5 and one mole of H2O in the reactants, the rate equation will contain these two substances, each raised to the power 1, which is reflected in option B only. Option A takes into account the fast step only. Option C takes into account the overall reaction. Option D does not have the rate constant k mentioned in the question.
Why the other options are wrong
- A. Option A takes into account the fast step only.
- C. Option C takes into account the overall reaction.
- D. Option D does not have the rate constant k mentioned in the question.
Q103. Which type of reaction takes place when a carbonyl compound is treated with a mixture of NaCN and an acid?
- A. Electrophilic addition reaction
- B. Substitution reaction
- C. Nucleophilic addition reaction✓
- D. Displacement reaction
Explanation: The given scenario is an example of a nucleophilic addition reaction, as the reactant, CN- is a nucleophile which adds across the carbonyl bond. Option A describes reactions undergone by alkenes, where an electrophile is added across the carbon-carbon double bond. Option B describes a reaction where one group of atoms is replaced by another group of atoms, but this is not the case here. Option D describes a reaction in which one element is replaced by another element in a compound.
Why the other options are wrong
- A. Option A describes reactions undergone by alkenes, where an electrophile is added across the carbon-carbon double bond.
- B. Option B describes a reaction where one group of atoms is replaced by another group of atoms, but this is not the case here.
- D. Option D describes a reaction in which one element is replaced by another element in a compound.
Q104. An intermolecular force of attraction X is relatively stronger than the other intermolecular forces. It stabilizes alpha-helix and beta-pleated sheets of proteins. The double helical structure of DNA is also stabilized by this force of attraction. Identify X:
- A. Van Der Waals Forces
- B. Hydrogen bonding✓
- C. Ionic interactions
- D. Dipole dipole attraction
Explanation: Option B is correct, as H-bonding stabilizes DNA structure as it is between bases in a complementary base pair as well as it stabilizes the secondary structures, such as alpha-helix and beta-pleated sheet. It is also stronger than the other intermolecular attraction, which is Van der Waals forces.
Why the other options are wrong
- A. Option A, Van der Waals forces are the weakest intermolecular forces and are not found in the examples, mentioned in the question given.
- C. Option C is present between ions and not molecules, and is not found within DNA or in secondary protein structures.
- D. Option D is an example of a Van der Waals force.
Q105. Which of the following molecule shows cis-trans isomers?
- A. C2H4
- B. C2H2Cl4
- C. C2H2Br2✓
- D. C2HCl3
Explanation: For cis-trans isomerism, the rotation must be restricted in the molecule (so, cannot occur in compounds that only have C-C single bonds) and there must be two non-identical groups on each double-bonded carbon atom. Option A does not fulfill this requirement, as each double-bonded carbon atom has two identical groups i.e. each C has two H atoms attached to it. Option B does not fulfill these requirements as it is a halogenoalkane, with no C-C double bonds so, rotation is not restricted in the molecule. Option C fulfills these requirements, as not only is rotation restricted as it has a C-C double bond, each carbon atom has two non-identical atoms, i.e. each C has one Hydrogen atom and one Bromine atom so, this option is correct. Option D does not fulfill the requirements as well as even though one double-bonded carbon atom has two non-identical atoms i.e. one H atom and one Cl atom, the other carbon has two identical Cl atoms.
Why the other options are wrong
- A. For cis-trans isomerism, the rotation must be restricted in the molecule (so, cannot occur in compounds that only have C-C single bonds) and there must be two non-identical groups on each double-bonded carbon atom. Option A does not fulfill this requirement, as each double-bonded carbon atom has two identical groups i.e. each C has two H atoms attached to it.
- B. Option B does not fulfill these requirements as it is a halogenoalkane, with no C-C double bonds so, rotation is not restricted in the molecule.
- D. Option D does not fulfill the requirements as well as even though one double-bonded carbon atom has two non-identical atoms i.e. one H atom and one Cl atom, the other carbon has two identical Cl atoms.
Q106. Modern periodic table is arranged in ascending order of?
- A. Nucleon number
- B. Atomic mass
- C. Proton number✓
- D. Mass number
Explanation: Elements of the periodic table are arranged in ascending order of their atomic number or proton number (which corresponds to the number of protons in the nucleus). Nucleon number, mass number, or atomic mass (all terms used to describe the same thing i.e. relative atomic mass) may have been used in earlier periodic tables.
Why the other options are wrong
- A. Nucleon number, mass number, or atomic mass (all terms used to describe the same thing i.e. relative atomic mass) may have been used in earlier periodic tables.
- B. As per the explanation, this option is incorrect.
- D. As per the explanation, this option is incorrect.
Q107. Disposable cups are made of a polymer 'polystyrene'. Polystyrene is:
- A. A polyamide
- B. A condensation polymer
- C. An addition polymer✓
- D. A polyester
Explanation: As you can see in the above image, polystyrene is an addition polymer, where the monomers (in this, a styrene molecule) are simply linked together to form a long chain, without the formation of a secondary product so, the answer is C. Option A describes polyamide, which is a condensation polymer formed by monomers, linked by amide bonds. Option B describes condensation polymers, where the functional groups of monomers are linked together, forming a secondary product, such as H2O, in the process. Option D describes a polyester, which is a condensation polymer, formed by monomers linked by ester linkages.
Why the other options are wrong
- A. Option A describes polyamide, which is a condensation polymer formed by monomers, linked by amide bonds.
- B. Option B describes condensation polymers, where the functional groups of monomers are linked together, forming a secondary product, such as H2O, in the process.
- D. Option D describes a polyester, which is a condensation polymer, formed by monomers linked by ester linkages.
Q108. Which of the following element is not present in halogens?
- A. I
- B. Cl
- C. Fe✓
- D. F
Explanation: Halogens are elements present in group 7A of the periodic table and include, Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I), and Astatine (At). Among the given options, only option C is NOT a halogen, it is Iron (Fe), a transition element.
Why the other options are wrong
- A. Iodine is a halogen. The halogens are a group of elements in Group 17 of the periodic table, and iodine is a member of this group.
- B. Chlorine is also a halogen. Like iodine, it belongs to Group 17 of the periodic table and is part of the halogen family.
- D. Fluorine is a halogen. It is the first element in Group 17 and is a highly reactive nonmetal.
Q109. Chlorofluorocarbons (CFCs) are important compounds that are used as refrigerants but these are also responsible for Ozone layer depletion. If a Chlorofluorocarbon CFCl3 is present in stratosphere, which of it’s reaction intermediates are actually responsible for the breakdown of the ozone molecule?
- A. CFCl2* and Cl*
- B. Cl* and ClO*✓
- C. CFCl2* and ClO*
- D. CFCl2 and CFCl3
Explanation: Ozone breakdown is mediated by free radicals derived from CFCs. Free radicals have unpaired electrons and are highly unstable, thereby breaking down ozone into oxygen. As per the following reaction mechanism, you can see that chlorine radicals are the chief substance involved in ozone depletion, as it catalyses the breakdown of ozone into oxygen and gets regenerated at the end of the reaction via forming a ClO* intermediate, enabling it to break down more ozone molecules.As such, the option, containing Cl* and ClO*, is correct, which is option B.Option A contains a carbon or alkyl containing radical, which is not as reactive as chloride radical due to the presence of a stabilising carbon/ alkyl group, and does not mention ClO*. Option C does not mention the chloride radical.Option D merely mentions examples of CFCs.
Why the other options are wrong
- A. Option A contains a carbon or alkyl containing radical, which is not as reactive as chloride radical due to the presence of a stabilising carbon/ alkyl group, and does not mention ClO*.
- C. Option C does not mention the chloride radical.
- D. Option D merely mentions examples of CFCs.
Q110. Which of the equations shows ‘twice’ the enthalpy change of neutralization as the following equation: HCl + NaOH → NaCl + H2O
- A. MgCO3 + 2HCl → MgCl2 + CO2 + H2O
- B. KOH + HCl → KCl + H2P
- C. NH4Cl + NaOH → NaCl + H2O + NH3
- D. H2SO4 + Mg(OH)2 → MgSO4 + 2H2O✓
Explanation: The given reaction depicts a neutralization reaction, where one mole of acid is neutralized by one mole of alkali (as indicated by 1 mole of HCl reacting with 1 mole of NaOH). For a reaction to have twice the enthalpy change as this reaction, it should involve neutralization of TWO moles of acid with TWO moles of alkali. Such an option is D, which has two moles of acid (which are present in H2SO4, as one molecule of H2SO4 has two molecules of hydrogen ions) reacting with two moles of alkali (Mg(OH)2 has two moles of hydroxide ions). Option B has the same enthalpy change of neutralisation as the reaction in the question as both involve one mole of H+ reacting with one mole of OH-. Options A and C are not reactions that fit the description of enthalpy change of neutralization, as they form gases in the products aside from a salt and water (for enthalpy change of neutralisation, an acid and a base react to form a salt and water only) so, their enthalpies cannot be compared to the given reaction.
Why the other options are wrong
- A. Options A and C are not reactions that fit the description of enthalpy change of neutralization, as they form gases in the products aside from a salt and water (for enthalpy change of neutralisation, an acid and a base react to form a salt and water only) so, their enthalpies cannot be compared to the given reaction.
- B. Option B has the same enthalpy change of neutralisation as the reaction in the question as both involve one mole of H+ reacting with one mole of OH-.
- C. Options A and C are not reactions that fit the description of enthalpy change of neutralization, as they form gases in the products aside from a salt and water (for enthalpy change of neutralisation, an acid and a base react to form a salt and water only) so, their enthalpies cannot be compared to the given reaction.
Q111. Which two elements are isotopes?
- A. 16X8 and 16Y8
- B. 14X8 and 15Y8✓
- C. 18X9 and 20Y10
- D. 12X6 and 12Y7
Explanation: In option A, both elements are the exact same, as they have same proton number (8) and same mass number (16) so, they are not isotopes (which vary in mass number but have the same proton number). Option B describes isotopes, as they have the same proton number (8), while having differing mass numbers. Option C describes two different elements entirely as they have varying proton numbers. Option D also describes two different elements due to varying proton numbers.
Why the other options are wrong
- A. In option A, both elements are the exact same, as they have same proton number (8) and same mass number (16) so, they are not isotopes (which vary in mass number but have the same proton number).
- C. Option C describes two different elements entirely as they have varying proton numbers.
- D. Option D also describes two different elements due to varying proton numbers.
Q112. Carboxylic acids can be reduced to corresponding alcohols. Which of the following reagent can be used for this purpose?
- A. KMnO4
- B. LiAlH4✓
- C. K2Cr2O4
- D. H2SO4
Explanation: For this reaction to take place, you need the proper reducing agent, which is only LiAlH4 i.e. option B. (NOTE: NaBH4 is not a strong enough reducing agent to reduce carboxylic acids, but LiAlH4 is.)Options A, C, and D; all describe OXIDISING agents.
Why the other options are wrong
- A. Options A, C, and D all describe OXIDISING agents. Oxidizing agents, also known as oxidants, are substances that facilitate oxidation reactions by accepting electrons from other substances. In the context of redox reactions, oxidation refers to the loss of electrons from a species, resulting in an increase in its oxidation state. The oxidizing agent, on the other hand, gains those electrons, leading to a decrease in its own oxidation state.
- C. Options A, C, and D all describe OXIDISING agents. Oxidizing agents, also known as oxidants, are substances that facilitate oxidation reactions by accepting electrons from other substances. In the context of redox reactions, oxidation refers to the loss of electrons from a species, resulting in an increase in its oxidation state. The oxidizing agent, on the other hand, gains those electrons, leading to a decrease in its own oxidation state.
- D. Options A, C, and D; all describe OXIDISING agents. Oxidizing agents, also known as oxidants, are substances that facilitate oxidation reactions by accepting electrons from other substances. In the context of redox reactions, oxidation refers to the loss of electrons from a species, resulting in an increase in its oxidation state. The oxidizing agent, on the other hand, gains those electrons, leading to a decrease in its own oxidation state.
Q113. Which enthalpy change is relevant in the following process Na(s) → Na (g) ΔH = +107
- A. Enthalpy of atomization✓
- B. Enthalpy of fusion
- C. Enthalpy of vaporization
- D. Enthalpy of formation
Explanation: Option A, enthalpy of atomization, is the energy required to completely separate all the atoms in a chemical substance. The separated atoms are in a gaseous state and get separated from the corresponding substance in its standard state. Sodium is solid in its standard state, and after atomization, the atoms are in their gaseous state. Hence, this is the correct answer. Option B is the enthalpy change when a solid substance melts into a liquid. Here, the state change is from a solid to a gas, no liquid state involved. Option C is the enthalpy change when a liquid is vaporized into a gas. Here, a solid is atomized to its gaseous state so, vaporization does not apply here. Option D is the enthalpy change when one mole of a substance is formed from its constituent elements. This does not describe the given reaction.
Why the other options are wrong
- B. Option B is the enthalpy change when a solid substance melts into a liquid. Here, the state change is from a solid to a gas, no liquid state involved.
- C. Option C is the enthalpy change when a liquid is vaporized into a gas. Here, a solid is atomized to its gaseous state so, vaporization does not apply here.
- D. Option D is the enthalpy change when one mole of a substance is formed from its constituent elements. This does not describe the given reaction.
Q114. Ionization energy decreases down the group, from top to bottom, due to:
- A. Increase in atomic mass
- B. Increase in shielding effect of the intervening electrons✓
- C. Increase in proton number
- D. Decrease in atomic size
Explanation: Ionization energy is the energy required to remove an electron from the outermost shell of the atom. The factors that affect activation energy are: An increase in proton number, as more protons cause a greater electrostatic force of attraction between the nucleus and the outermost electrons, requiring more energy to overcome. A decrease in atomic size, as the force of attraction is inversely proportional to distance so, the closer the atoms are to the nucleus, the greater would be the force of attraction, which requires greater energy to overcome. The shielding effect describes the reduction in effective nuclear force of attraction between the nucleus and outer electrons due to the repulsion exerted by the inner shells of the atom. As we go down the group, the proton number increases, which would theoretically cause ionization energy to increase, but as we go down the group, the number of shells of each atom increases, successively, resulting in a greater shielding effect which reduces the effective force of attraction between the nucleus and the valence electrons. Hence, ionization energy decreases due to an increase in shielding effect down the group, i.e. option B. Option A does not have a direct impact on ionization energy, albeit atomic mass is accompanied by atomic number, closely in most atoms. Option C is a correct observation down the group, but the ionization energy still decreases even though the atomic number increases. Option D is an incorrect statement as atomic size increases down the group.
Why the other options are wrong
- A. Option A does not have a direct impact on ionization energy, albeit atomic mass is accompanied by atomic number, closely in most atoms.
- C. Option C is a correct observation down the group, but the ionization energy still decreases even though the atomic number increases.
- D. Option D is an incorrect statement as atomic size increases down the group.
Q115. The Ka values of HCI, CH3COOH, HF, and H2SO4 are 107, 1.85 x 10-5, 6.7 x 10-5 and 102 respectively. The decreasing order of acidic strength is:
- A. CH3COOH > HF > H2SO4 > HCI
- B. HCI > H2SO4 > HF > CH3COOH✓
- C. HCl > CH3COOH > HF > H2SO4
- D. HCl > HF > H2SO4 > CH3COOH
Explanation: Ka is a measure of ionization of the acid, thereby a greater Ka corresponds to greater acidic strength. The question asks for DECREASING order of acidic strength so, the acids are to be listed from strongest to weakest. HCl is the strongest with the greatest Ka (107), followed by H2SO4 (102), followed by HF (6.7 x 10-5), and then CH3COOH which is the weakest having the lowest Ka (1.85 x 10-5). Option B has this correctly laid out so, it is the answer. Option A has the order in reverse, as it lists the acid down in increasing order of acidic strength. Options, C and D, have them listed incorrectly, as C has CH3COOH before the rest while D has HF mentioned before H2SO4.
Why the other options are wrong
- A. Option A has the order in reverse, as it lists the acid down in increasing order of acidic strength.
- C. Options, C and D, have the acids listed incorrectly, as C has CH3COOH before the rest while D has HF mentioned before H2SO4.
- D. Options, C and D, have the acids listed incorrectly, as C has CH3COOH before the rest while D has HF mentioned before H2SO4.
Q116. In contact process, to which substance are adequate quantities of water added to convert it to sulphuric acid?
- A. H2S2O7✓
- B. HSO4-
- C. SO3
- D. S
Explanation: In the contact process, sulfur dioxide (formed by roasting sulfur in oxygen) is reacted with oxygen to form sulfur trioxide, which is mixed with H2SO4 to form oleum or fuming sulfuric acid, with the formula of H2S2O7. This is then mixed with adequate quantities of water to form aqueous sulfuric acid, so the answer is A. Option B is hydrogen sulfate, the species formed when H2SO4 donates one proton. This is not involved in the contact process. Option C is SO3, which can react with water to directly form H2SO4, but the reaction is so violent and inefficient that it can not be a practical source of sulfuric acid so, SO3 is reacted with H2SO4 to form oleum. Option D is elemental sulfur, which is used to make SO2 upon reacting with oxygen in the contact process.
Why the other options are wrong
- B. Option B is hydrogen sulfate, the species formed when H2SO4 donates one proton. This is not involved in the contact process.
- C. Option C is SO3, which can react with water to directly form H2SO4, but the reaction is so violent and inefficient that it can not be a practical source of sulfuric acid so, SO3 is reacted with H2SO4 to form oleum.
- D. Option D is elemental sulfur, which is used to make SO2 upon reacting with oxygen in the contact process.
Q117. For the following equilibrium reaction, when the forward reaction is exothermic; an increase in temperature shifts the equilibrium position towards the left. What will occur in that scenario? 2SO2 + O2 ⇌ 2SO3
- A. The concentrations of SO2 and O2 increases and concentration of SO3 decreases as the temperature increases.✓
- B. The concentrations of SO3, SO2, and O2 increase as the temperature increases.
- C. The concentrations of SO2 and O2 decreases and concentration of SO3 increases as the temperature increases.
- D. The concentrations of SO2 and O2 and SO3 remains the same as the temperature increases.
Explanation: Since the equilibrium of the reaction shifts to the left, this means that the left hand side of the reaction is favoured. Increasing the reactants (LHS) and decreasing the products (RHS). Le Chatelier's principle will be used.
Why the other options are wrong
- B. SO3 is on the right side of the equation, hence the concentration of it will decrease.
- C. This is incorrect as this is the opposite of what will actually entail. Since the reaction is shifting towards the left, the concentration of SO2 and O2 will increase.
- D. Since a change is being applied, the equilibrium must adapt to maintain the equilibrium. Hence, this option is incorrect.
Q118. Which one of the following molecules has sp3 hybridization?
- A. CH4✓
- B. C2H4
- C. CO2
- D. C2H2
Explanation: CH4 has sp3 hybridization which enables all four bonds to be of the same length and strength. Methane molecule is formed by the overlap of sp3 hybrid orbitals of carbon with 1s orbitals of four hydrogen atoms separately to form four sigma bonds.
Why the other options are wrong
- B. Option B, C2H4 has sp2 hybridization as carbon atom contains three single bonds which include sp2 orbitals, whereas the C-C double bond is brought about by a p-p overlap.
- C. Options, C and D, both have sp hybridization. In CO2, carbon has two single bonds which involve sp orbitals, and a double bond with each oxygen so, two free p orbitals are used for the two double bonds. In C2H2, an alkyne, carbon has two single bonds which involve sp orbitals, but a triple bond that uses two p orbitals per carbon atom.
- D. Options, C and D, both have sp hybridization. In CO2, carbon has two single bonds which involve sp orbitals, and a double bond with each oxygen so, two free p orbitals are used for the two double bonds. In C2H2, an alkyne, carbon has two single bonds which involve sp orbitals, but a triple bond that uses two p orbitals per carbon atom.
Q119. During stoichiometric calculations, which of the following laws must be followed?
- A. Dalton's law
- B. Avogadro's law
- C. Law of conservation of mass✓
- D. Law of conservation of energy
Explanation: Option A describes the law of partial pressures, which states that the total pressure by a mix of gases is equal to the sum of partial pressures of each of the constituent gases. Option B describes the law which states that equal volumes of gases, at the same temperature and pressure, contain equal numbers of molecules. (NOTE: Do not confuse this with Avogadro's number and the concept of a mole). Option C describes the law which states that matter can neither be created nor destroyed so, the mass of every element, present in the products of a chemical reaction, must be equal to the mass of each and every element present in the reaction, on the reactant side. This is the basis of balancing a chemical equation, without which stoichiometric calculations cannot be carried out so, it is the correct answer. Option D describes the law which states that energy can neither be created nor destroyed; it can only be transferred from one form to the other. This has more relevance in energy conversion and work or power calculations rather than stoichiometry.
Why the other options are wrong
- A. Option A describes the law of partial pressures, which states that the total pressure by a mix of gases is equal to the sum of partial pressures of each of the constituent gases.
- B. Option B describes the law which states that equal volumes of gases, at the same temperature and pressure, contain equal numbers of molecules. (NOTE: Do not confuse this with Avogadro's number and the concept of a mole).
- D. Option D describes the law which states that energy can neither be created nor destroyed; it can only be transferred from one form to the other. This has more relevance in energy conversion and work or power calculations rather than stoichiometry.
Q120. Nitriles (RCN), on hydrolysis, in the presence of a mineral acid yield:
- A. Ethers
- B. Carboxylic acids✓
- C. Aldehydes
- D. Alcohols
Explanation: As can be seen from the reaction mechanism below, nitrile hydrolysis yields carboxylic acids and the liberation of an ammonium/ammonia molecule.
Why the other options are wrong
- A. False.nitrile hydrolysis yields carboxylic acids and the liberation of an ammonium/ammonia molecule.
- C. False.nitrile hydrolysis yields carboxylic acids and the liberation of an ammonium/ammonia molecule.
- D. False.nitrile hydrolysis yields carboxylic acids and the liberation of an ammonium/ammonia molecule.
Q121. Alkenes undergo:
- A. Electrophilic Addition✓
- B. Electrophilic substitution
- C. Nucleophilic substitution
- D. Nucleophilic addition
Explanation: Alkenes have a pi bond between carbon atoms, which is an area of electron density i.e. a region of great negative charge, which attracts positively charged species, i.e. electrophiles, which add across the double bond without the removal of any atom/group of atoms. Hence, alkenes undergo electrophilic addition, option A. The remaining options describe reactions that are undergone by other organic compounds. Option B, electrophilic substitution is undergone by benzene. Option C, nucleophilic substitution is undergone by alkyl halides. Option D, nucleophilic addition is undergone by aldehydes and ketones.
Why the other options are wrong
- B. Option B, electrophilic substitution is undergone by benzene.
- C. Option C, nucleophilic substitution is undergone by alkyl halides.
- D. Option D, nucleophilic addition is undergone by aldehydes and ketones.
Q122. Treatment of ethene with cold sulphuric acid, followed by reaction with boiling water, yields:
- A. Ethane
- B. Ethanal
- C. Ethanol✓
- D. Ethyne
Explanation: The scenario describes the overall reaction of the addition of OH or hydration of ethene. Upon reacting with sulfuric acid, it forms an intermediate, which is ethyl hydrogen sulfate, and upon boiling with water, it forms ethanol as sulfuric acid is regenerated. The answer is C. Option A, ethane is formed upon hydrogenation of ethene. Option B, ethanal is formed upon oxidation of the ethanol, which is formed. Optio D, ethyne is formed upon treatment of ethene with Bromine, followed by heating in the presence of alcoholic KOH.
Why the other options are wrong
- A. Option A, ethane is formed upon hydrogenation of ethene.
- B. Option B, ethanal is formed upon oxidation of the ethanol, which is formed.
- D. Option D, ethyne is formed upon treatment of ethene with Bromine, followed by heating in the presence of alcoholic KOH.
Q123. How many moles of Calcium Carbonate are present in 1.75 kg of Calcium Carbonate? (Ar of Ca = 40, Ar of C = 12, Ar of O = 16)
- A. 1.75 mol
- B. 1750 mol
- C. 0.0175 mol
- D. 17.5 mol✓
Explanation: The molar mass of CaCO3 (40 + 12 + 16 + 16 + 16) is 100g per mole. If one mole equals 100g, than 1750g (1.75 kg x 1000) equals 1750/100, which is 17.5 mol so, D is the answer.
Why the other options are wrong
Q124. Which balanced chemical equation show the formation of ethanoyl chloride using thionyl chloride?
- A. HCOOH + SOCl2 → HCOCI + SO2 + HCI
- B. CH3CH2COOH + 2SOCl → CH3CH2COCl + SO2 + HCI
- C. CH3CH2COOH + 2SOCl → CH3CH2COC1 + SO3 + HCI
- D. CH3COOH + SOCl2 → CH3COCl + SO2 + HCI✓
Explanation: Thionyl chloride is SOCl2 and it reacts with carboxylic acids to form acyl chlorides.Options B and C do not involve thionyl chloride, it mentions SOCl2 instead of SOCl2 so, they are incorrect.Options A and D are both valid reactions involving thionyl chloride. However, the question asks for the formation of ethanoyl chloride. Option A shows the formation of METHANOYL Chloride, whereby D shows ethanoyl chloride formation so, D is the correct answer.
Why the other options are wrong
- B. Options B and C do not involve thionyl chloride, it mentions SOCl instead of SOCl2 so, they are incorrect.
- C. Options B and C do not involve thionyl chloride, it mentions SOCl instead of SOCl2 so, they are incorrect.
Q125. All the collisions between the particles of gases are elastic in nature. What is meant by "Elastic Collisions"?
- A. No change in the total kinetic energy✓
- B. The velocity of the molecules changes
- C. No change in potential energy during the collisions
- D. No change in mass during the collisions
Explanation: By definition, an 'Elastic collision' describes a collision whereby the total kinetic energy of the molecules is unchanged so, option A is correct. Option B, velocity may or may not change in elastic collisions, and the velocity also changes in inelastic conditions as well. Option C, potential energy is not usually used in the context of elastic collisions. Option D is a correct statement but it holds for all types of collisions and is not exclusive to elastic collisions.
Why the other options are wrong
- B. Velocity may or may not change in elastic collisions, and the velocity also changes in inelastic conditions as well.
- C. Potential energy is not usually used in the context of elastic collisions.
- D. Option D is a correct statement but it holds for all types of collisions and is not exclusive to elastic collisions.
Q126. Which of the following reagent is required for preparation of acyl chloride (CH3COCl) from ethanoic aicd?
- A. PCl5✓
- B. POCl3
- C. CH3Cl
- D. HCl
Explanation: Production of acyl chloride from a carboxylic acid can be used using the following reagents, PCl3, PCl5, SOCl2 (thionyl chloride). Only option A mentions one of the three, which is PCl5 so, it is the correct answer.
Why the other options are wrong
- B. Production of acyl chloride from a carboxylic acid can be used using the following reagents, PCl3, PCl5, SOCl2 (thionyl chloride). Only option A mentions one of the three, which is PCl5 so, it is the correct answer.
- C. Production of acyl chloride from a carboxylic acid can be used using the following reagents, PCl3, PCl5, SOCl2 (thionyl chloride). Only option A mentions one of the three, which is PCl5 so, it is the correct answer.
- D. Production of acyl chloride from a carboxylic acid can be used using the following reagents, PCl3, PCl5, SOCl2 (thionyl chloride). Only option A mentions one of the three, which is PCl5 so, it is the correct answer.
Q127. Identification tests for functional groups of organic compounds are associated with specific observations. Tollen’s reagent is an ammoniacal silver nitrate solution, which is used for the identification of a functional group X with an observation O. Identify X and O.
- A. X = Aldehyde O = Silver mirror✓
- B. X = Ketone, O = Grey precipitate
- C. X = Ketone, O = Silver mirror
- D. X = Aldehyde O = Red precipitate
Explanation: Tollens reagent test is also known as the silver mirror test. It cannot react with ketones but it reacts with aldehydes, thereby identifying the aldehyde functional group. Upon reacting, the silver precipitates as a silver mirror which coats the bottom of the test tube. Hence, option A is the correct answer as it is the only one with both correct functional group and observation.
Why the other options are wrong
- B. The main importance of Tollens' reagent is used to distinguish aldehydes and ketones. The reaction of aldehydes with Tollens' reagent is an oxidation reaction which converts aldehydes to carboxylic acid. Tollens' reagent is a mild oxidizing agent which can oxidize aldehydes but not ketones.
- C. The main importance of Tollens' reagent is used to distinguish aldehydes and ketones. The reaction of aldehydes with Tollens' reagent is an oxidation reaction which converts aldehydes to carboxylic acid. Tollens' reagent is a mild oxidizing agent which can oxidize aldehydes but not ketones.
- D. Tollens reagent test is also known as the silver mirror test. It cannot react with ketones but it reacts with aldehydes, thereby identifying the aldehyde functional group. Upon reacting, the silver precipitates as a silver mirror which coats the bottom of the test tube. Hence, option A is the correct answer as it is the only one with both correct functional group and observation.8
Q128. Free Nitrogen and Oxygen are present in atmosphere but they do not react with each other under normal conditions because:
- A. Nitrogen requires a catalyst
- B. Oxygen is very inactive
- C. Oxygen is found in less concentration
- D. Nitrogen is highly inactive gas✓
Explanation: Option A is a true statement, but it does not, by itself, explain why nitrogen does not react under normal conditions; Nitrogen is highly inactive so, it requires a catalyst because of its inactivity/inertness.Option B is incorrect as oxygen is quite reactive, taking part in numerous reactions such as combustion reactions.Option C is a true statement because it is found in less concentration than nitrogen, but that should not, in itself, prevent a reaction from taking place under normal conditions.Option D is correct. Nitrogen is nonpolar and has a triple bond, which requires an enormous amount of energy to overcome so, under normal conditions, it cannot react with oxygen; it requires a catalyst and heat energy to overcome its natural inertness.
Why the other options are wrong
- A. Option A is a true statement, but it does not, by itself, explain why nitrogen does not react under normal conditions; Nitrogen is highly inactive so, it requires a catalyst because of its inactivity/inertness.
- B. Option B is incorrect as oxygen is quite reactive, taking part in numerous reactions such as combustion reactions.
- C. Option C is a true statement because it is found in less concentration than nitrogen, but that should not, in itself, prevent a reaction from taking place under normal conditions.
Q129. CFCs are organic compounds, that are derivatives of saturated hydrocarbons. They have high bond dissociation values therefore they are inert and non-toxic for living organisms.The word CFCs stands for:
- A. Chlorofluorocarbons✓
- B. Carbonfluorochlorines
- C. Clorofluorocarbonos
- D. Chlorofluoridecarbons
Explanation: Factual recall.
Why the other options are wrong
- B. CFCs stand for chlorofulorocarbons.
- C. CFCs stand for chlorofulorocarbons.
- D. CFCs stand for chlorofulorocarbons.
Q130. According to Watson and Crick’s model of DNA, the DNA molecule consists of a double helix. What type of forces are responsible to keep two strands of DNA together?
- A. Van der Waals forces
- B. Ionic bonding
- C. Hydrogen bonding✓
- D. Dipole-induced dipole forces
Explanation: The bases in each complementary base pair have hydrogen bonds between them, which keeps the two strands together and stable. 'A' and 'T' have 2 hydrogen bonds between them, while 'G' and 'C' have three hydrogen bonds between them. The answer is C, as the other options do not mention hydrogen bonding.
Why the other options are wrong
- A. Van der Waals forces are weak intermolecular forces that occur between atoms or molecules. These forces arise from temporary fluctuations in electron distribution, leading to the creation of temporary dipoles. There are three types of Van der Waals forces: dispersion forces, dipole-dipole interactions, and hydrogen bonding. Dispersion forces are present in all molecules and arise from the momentary imbalances in electron distribution. Dipole-dipole interactions occur between polar molecules with permanent dipoles. Hydrogen bonding is a specific type of dipole-dipole interaction that occurs when a hydrogen atom is bonded to an electronegative atom, such as oxygen, nitrogen, or fluorine.
- B. Ionic bonding is a type of chemical bonding that occurs between atoms with significantly different electronegativities. It involves the transfer of electrons from one atom to another, resulting in the formation of ions. One atom, typically a metal, loses electrons to become a positively charged ion (cation), while the other atom, usually a nonmetal, gains those electrons to become a negatively charged ion (anion).
- D. Dipole-induced dipole forces, also known as induced dipole forces or London dispersion forces, are a type of intermolecular force. They occur between molecules with a permanent dipole and molecules without a permanent dipole.When a polar molecule approaches a nonpolar molecule, the electric field of the polar molecule induces a temporary dipole in the nonpolar molecule. This induced dipole creates an attractive force between the two molecules.
Q131. Nitrogen has an atomic number of 7.Which of the following electronic configurations is of a nitrogen atom in the ground state?
- A. 1s2, 2s2, 2px1, 2py1, 2pz1✓
- B. 1s2, 2s2, 2px2, 2pz1
- C. 1s2, 2s2, 2px2, 2py1
- D. 1s2, 2s2, 2py2, 2pz1
Explanation: The electronic configuration of nitrogen is as follows: 1s2, 2s2, 2p3. The 'Auf-bau principle' states that electrons fill lower-energy atomic orbitals before filling higher-energy ones. Moreover, we have the 'Hund's Rule' stating that when electrons occupy degenerate orbitals (i.e. of the same energy level), they must first occupy the empty orbitals before double occupying them.
Why the other options are wrong
- B. This configuration indicates that nitrogen has two electrons in the 1s orbital, two electrons in the 2s orbital, and three electrons in the 2p orbital. Specifically, there are two electrons in the 2px orbital, no electron in the 2py orbital, and one electron in the 2pz orbital. Thus, this option is incorrect.
- C. This configuration indicates that nitrogen has two electrons in the 1s orbital, two electrons in the 2s orbital, two electrons in the 2px orbital, one electron in the 2py orbital, and no electrons in the 2pz orbital. Thus, this option is incorrect.
- D. This configuration indicates that Nitrogen has two electrons in the 1s orbital, two electrons in the 2s orbital, no electron in the 2px orbital, two electrons in the 2py orbital, and one electron in the 2pz orbital. Thus, this option is incorrect.
Q132. Which of the following substances exhibits strong hydrogen bonding?
- A. H2S
- B. SiH4
- C. NH3✓
- D. HI
Explanation: Hydrogen bonding occurs in those substances in which a highly electronegative atom (such as Fluorine (F), Oxygen (O) or Nitrogen (N)) is directly bonded to Hydrogen. The presence of one of these three atoms is a REQUIREMENT for hydrogen bonding to occur. Only option C mentions a substance which has one of these three atoms, i.e. Nitrogen in NH3, while the other options mention other atoms aside from the three highly electronegative species mentioned previously.
Why the other options are wrong
- A. In H2S, the sulfur atom is less electronegative than oxygen, which means the hydrogen-sulfur bond is not as polar as the hydrogen-oxygen bond in water. As a result, hydrogen bonding in H2S is significantly weaker than in H2O.
- B. Hydrogen bonding does not occur in SiH4 (silane). Hydrogen bonding is a special type of intermolecular force that occurs when a hydrogen atom is bonded to a highly electronegative atom (such as oxygen, nitrogen, or fluorine) and interacts with another electronegative atom nearby.
- D. In HI, the hydrogen atom is bonded to iodine (I), which is less electronegative than oxygen or nitrogen but still significantly more electronegative than hydrogen. This electronegativity difference allows for a partial positive charge on the hydrogen atom and a partial negative charge on the iodine atom. This polarization creates a dipole-dipole interaction between the hydrogen atom of one HI molecule and the iodine atom of another HI molecule.
Q133. Aqueous solutions of Iodine and Sodium hydroxide were mixed in a round bottom flask at 70 C. Following chemical reaction was carried out. 3I2 + 6 NaOH → NaIO3 + NaI + H2OThis reaction is termed as:
- A. Redox reaction✓
- B. Precipitation reaction
- C. Substitution reaction
- D. Free radical reaction
Explanation: To determine whether such a reaction is a redox reaction, the oxidation states of the reactants and products is compared. The oxidation state of Na remains +1 throughout, as does the oxidation states of Hydrogen (+1) and Oxygen (-2). Iodine undergoes a change in oxidation state. Its oxidation state is 0, in its molecular form, on the reactant side. In NaI, iodine's oxidation state is -1 so, Iodine has undergone reduction. In NaIO3, the oxidation states of Na remain +1 and oxygen's also remains -2 so, we can determine that the oxidation state of iodine is +5 in this reaction. (NOTE: For oxidation numbers, the total oxidation state of a compound is zero so, Iodine's oxidation number must be +5 to ensure NaIO3’s oxidation state is zero). Since Iodine underwent oxidation AND reduction, we can conclude that this is a redox reaction (disproportionation to be precise, as the same species has undergone oxidation and reduction) so, option A is correct. Option B is incorrect, as the two salts produced are soluble in water. Option C does not describe this reaction. Option D is incorrect as no free radicals are produced during this reaction.
Why the other options are wrong
- B. Option B is incorrect, as the two salts produced are soluble in water.
- C. Option C does not describe this reaction.
- D. Option D is incorrect as no free radicals are produced during this reaction.
Q134. Which of the following bond is responsible for joining the amino acids in proteins?
- A. Peptide Bond✓
- B. Ionic Bond
- C. Metallic Bond
- D. Disulfide Bond
Explanation: Option A is correct, as within a protein chain, each amino acid is linked to each other by a peptide bond which is a covalent bond.Options B and D describe those bonds that hold proteins in their complex three dimensional structures, but the question asks for the bond that holds individual amino acids within proteins.Option C describes a metallic bond which is only found in metals, and not in proteins as it is molecular in nature.
Why the other options are wrong
- B. Options B and D describe those bonds that hold proteins in their complex three dimensional structures, but the question asks for the bond that holds individual amino acids within proteins.
- C. Option C describes a metallic bond which is only found in metals, and not in proteins as it is molecular in nature.
- D. Options B and D describe those bonds that hold proteins in their complex three dimensional structures, but the question asks for the bond that holds individual amino acids within proteins.
Q135. Which of the following is the electronic configuration of Cr?
- A. [Ar] 3d5 4s2
- B. [Ar] 3d5 4s1✓
- C. [Ar] 3d4 4s2
- D. [Ar] 3d6 4s0
Explanation: Chromium (Cr) has atomic number 24. Theoretically, the electronic configuration of Cr should be 1s2 2s2 2p6 3s2 3p6 3d4 4s2 (NOTE: [Ar] symbol denotes the electronic configuration for 1s2 2s2 2p6 3s3 3p6). However, in reality, one electron from 4s jumps to the 3d subshell so, that the configuration is [Ar] 3d5 4s1. This is because a half-filled d subshell, which is 3d5, is much more stable than 3d4, and atoms favor stability. Hence, option B is the correct answer.
Why the other options are wrong
- A. As per the explanation, this option is incorrect.
- C. As per the explanation, this option is incorrect.
- D. As per the explanation, this option is incorrect.
Q136. The number of moles of water in 1 kg ice are:
- A. 50 moles
- B. 100 moles
- C. 1000 moles
- D. 55.5 moles✓
Explanation: 1 mole of water corresponds to 18g. So, to calculate the number of moles of water in 1kg or 1000g of ice (NOTE: The state of the substance does not have an effect in such stoichiometric calculations), 1000 is divided by 18, which comes out to 55.5 moles.
Why the other options are wrong
- A. Factual recall; please check the explanation for the correct answer.
- B. Factual recall; please check the explanation for the correct answer.
- C. Factual recall; please check the explanation for the correct answer.
Q137. Which of the following set constitutes of all the molecules and ions of non-planar geometry?
- A. PH4+, NH3, SO3, Benzene
- B. CH4, NH4 +, MnO4- , NF3✓
- C. Ethene, H2O, BeCl2, H2S
- D. SO2, C2H4, BF3, NO3-
Explanation: The question asks for species that have NON-PLANAR geometry so, those structures which are planar are to be eliminated. Option A includes benzene and SO3, which are planar molecules as all carbons of benzene have trigonal planar geometry around them, while SO3 is a trigonal planar molecule as well (due to the presence of three bonding pairs of electrons around them). PH4+ and NH3 are not planar however, PH4+ is tetrahedral (its shape corresponds to ammonium ion as P and N are in the same group), while NH3 has a trigonal pyramidal shape (3 bonding pairs and one lone pair around N). Option B is correct, as all four substances have non-planar structures. CH4 and NH4+ have tetrahedral structures due to four pairs of bonding electrons around the central atom, MnO4- also has tetrahedral geometry (see pictures below), while NF3 has a trigonal pyramidal shape (compare it to NH3 structure as both have three single bonds with a lone pair of electrons). Option C is also incorrect, as ethene and BeCl2 are planar molecules. Ethene is trigonal planar, while BeCl2 is linear. H2O and H2S are non planar however, with both having the same bent structure with two bonding pairs of electrons and two lone pairs (the two structures are similar as both O and S belong to group 6). Option D is incorrect due to the presence of planar C2H4 (ethene), NO3-, and BF3, as they both are trigonal planar. SO2 only is the non-planar bent substance in this list.
Why the other options are wrong
- A. Option A includes benzene and SO3, which are planar molecules as all carbons of benzene have trigonal planar geometry around them, while SO3 is a trigonal planar molecule as well (due to the presence of three bonding pairs of electrons around them). PH4+ and NH3 are not planar however, PH4+ is tetrahedral (its shape corresponds to ammonium ion as P and N are in the same group), while NH3 has a trigonal pyramidal shape (3 bonding pairs and one lone pair around N).
- C. Option C is also incorrect, as ethene and BeCl2 are planar molecules. Ethene is trigonal planar, while BeCl2 is linear. H2O and H2S are non planar however, with both having the same bent structure with two bonding pairs of electrons and two lone pairs (the two structures are similar as both O and S belong to group 6).
- D. Option D is incorrect due to the presence of planar C2H4 (ethene), NO3-, and BF3, as they both are trigonal planar. SO2 only is the non-planar bent substance in this list.
Q138. The given diagram shows the enthalpy changes during a chemical reaction. What type of reaction is this?
- A. An endothermic reaction
- B. An exothermic reaction✓
- C. An isothermic process
- D. A non-spontaneous process
Explanation: This diagram shows a reaction in which the reactants are at a greater energy level than the products, indicating that energy is released during the reaction, i.e. change in enthalpy or (H2-H1) would be negative, indicating that it is an exothermic reaction so, option B is correct. Option A describes an endothermic reaction which would have a diagram depicting products, at a higher energy level than the reactants. Option C indicates a process in which the heat energy of the system does not change, but the diagram itself shows a change in enthalpy. Option D cannot be determined from a mere energy diagram as shown.
Why the other options are wrong
- A. Option A describes an endothermic reaction which would have a diagram depicting products, at a higher energy level than the reactants.
- C. Option C indicates a process in which the heat energy of the system does not change, but the diagram itself shows a change in enthalpy.
- D. Option D cannot be determined from a mere energy diagram as shown.
Q139. What is the measure of activation energy in an endothermic reaction?
- A. The energy of activation of backward reaction is less than that of forward reaction✓
- B. The energy of activation of backward reaction is more that that of forward reaction
- C. The energy of activation of forward reaction is less than that of backward reaction
- D. The energy of activation of forward - backward reaction is same
Explanation: In an endothermic reaction, the activation energy of a forward reaction will always be greater than that of the reverse reaction as can be seen in the diagram given above so, the answer is A which is the activation energy of the reverse reaction being less than that of the forward reaction. Options B and C describe the conditions of an exothermic reaction. Option D would describe a reaction in which the products and reactants are at the same energy level.
Why the other options are wrong
- B. Options B and C describe the conditions of an exothermic reaction.
- C. Options B and C describe the conditions of an exothermic reaction.
- D. Option D would describe a reaction in which the products and reactants are at the same energy level.
Q140. Maleic and Fumaric acid, both have chemical C4H4O4. The structure of these acids is shown below. What type of isomers are these?
- A. Cis-trans isomers✓
- B. Structural isomers
- C. Metamers
- D. Position Isomers
Explanation: Option A describes isomers in which one isomer has the same groups of atoms on one side of the double bond (cis), while the other isomer (trans) would have different groups of atoms on each side of the double bond. Maleic acid is the cis-isomer, while fumaric acid is the trans-isomer. Option B does not describe these compounds as these isomers are stereoisomers, having the same arrangements of atoms, structurally. Option C, metamers, describes compounds that have differing alkyl groups on each side of the functional group. As you can see from their structures, both compounds have the same groups on either side of the C=C. Option D also is incorrect as positional isomers have different locations of the functional groups, but both compounds have the double bond located at the exact same location.
Why the other options are wrong
- B. Option B does not describe these compounds as these isomers are stereoisomers, having the same arrangements of atoms, structurally.
- C. Option C, metamers, describes compounds that have differing alkyl groups on each side of the functional group. As you can see from their structures, both compounds have the same groups on either side of the C=C.
- D. Option D also is incorrect as positional isomers have different locations of the functional groups, but both compounds have the double bond located at the exact same location.
Q141. Amino acids are bi-functional compounds, with a general formula NH2CH(R)CO2H. A tripeptide is formed between Alanine (ala), Glycine (gly), and lysine (lys). There is no repetition of amino acid in this tri-peptide; suggest how many tri-peptides are possible?
- A. 9
- B. 6✓
- C. 3
- D. 12
Explanation: For such questions, try to make all possible combinations of amino acids. They include:ala-gly-lys gly-ala-lys lys-ala-glyala-lys-gly gly-lys-ala lys-gly-alaThus, there are six possible amino acids that can be formed without repetition. If repetition was allowed, then the answer would be 27 (3 x 3 x 3).NOTE: Tripeptides which can be written in reverse such as ala-lys-gly and gly-lys-ala are different and distinct from each other so do not eliminate such examples or count them as one instead of two, because in such tripeptides the C-terminal and N-terminals vary.
Why the other options are wrong
- A. 9 This option seems to assume that each position in the tripeptide can be filled with any of the three amino acids (Ala, Gly, or Lys), with repetition allowed. However, since the question specifies that there is no repetition of amino acids in the tripeptide, this answer is not applicable.
- C. 3 This option suggests that there are only three possible tripeptides formed from Alanine, Glycine, and Lysine. However, considering that each position in the tripeptide can be filled with any of the three amino acids without repetition, this answer is too low.
- D. 12 This option overestimates the number of possible tripeptides. It seems to assume that repetition is allowed and does not consider that each position in the tripeptide must be filled with a unique amino acid. Therefore, this answer is not correct in the context of the question.
Q142. If the energy of activation of a chemical reaction is very low, the rate of that chemical reaction is observed to be very high because?
- A. Concentration of the reactants becomes irrelevant
- B. Reaction proceeds without any transition state
- C. Number of efficient or fruitful collisions increase✓
- D. Molecules of the reactants move slowly
Explanation: Option A is incorrect because the concentration of reactants, still, is a factor regardless of other factors such as low activation energy. (Same goes for all other factors that affect the rate of reaction) Option B is incorrect, as the transition state is always present regardless of activation energy. Option C is correct, as low activation energy means that many more reactant particles have the minimum energy required to produce products so, with a greater number of particles possessing energy equal to or greater than the activation energy collide, they produce products. Hence, more fruitful collisions occur. Option D is incorrect, as reactant particles move slowly if there is less heat energy applied, which was not mentioned in the question.
Why the other options are wrong
- A. Option A is incorrect because the concentration of reactants, still, is a factor regardless of other factors such as low activation energy. (Same goes for all other factors that affect the rate of reaction).
- B. Option B is incorrect, as the transition state is always present regardless of activation energy.
- D. Option D is incorrect, as reactant particles move slowly if there is less heat energy applied, which was not mentioned in the question.
Q143. Which of the following compounds is responsible for the depletion of ozone layer?
- A. Chlorofluorocarbons✓
- B. Carbon tetrachlorie
- C. Methane
- D. Hydroflorocarbons
Explanation: Factual recall.
Why the other options are wrong
- B. CCl4 was widely used as a solvent for oils, fats, waxes, and other organic compounds due to its excellent solvent properties. However, its use as an industrial solvent has decreased significantly due to environmental and health concerns.
- C. Methane is the primary component of natural gas, which is a significant source of fuel worldwide. It is used for heating, cooking, and generating electricity. Natural gas is also used as a feedstock for the production of various chemicals, such as methanol and ammonia.
- D. HFCs are widely used as refrigerants in various applications, such as air conditioning systems, refrigerators, and freezers. They provide cooling by absorbing heat from the surroundings and transferring it to another location. HFC refrigerants have been adopted as alternatives to CFCs and HCFCs, which were phased out due to their ozone-depleting potential.
Q144. Which product is obtained by the hydrolysis of 1-chlorobutane with the aqueous sodium hydroxide?
- A. 1-butanal
- B. 1-butanol✓
- C. 1-butene
- D. Butanone
Explanation: The scenario describes nucleophilic substitution of 1-chlorobutane, where -OH serves as the nucleophile, as sodium hydroxide is aqueous instead of alcoholic. As such, alcohol is produced as -OH substitutes the Cl atom so, option B is correct.Option A is incorrect as alkyl halides cannot be directly converted to aldehydes.Option C, an alkene, would be produced if the sodium hydroxide was in an alcohol solvent or if the reactant was alcoholic KOH instead of aqueous. This is because, in these conditions, an elimination reaction occurs instead of a substitution reaction, producing an alkene upon the elimination of the halogen and adjacent carbons hydrogen atom.Option D is incorrect as ketones cannot be formed directly from alkyl halides.
Why the other options are wrong
- A. Option A is incorrect as alkyl halides cannot be directly converted to aldehydes.
- C. Option C, an alkene, would be produced if the sodium hydroxide was in an alcohol solvent or if the reactant was alcoholic KOH instead of aqueous. This is because, in these conditions, an elimination reaction occurs instead of a substitution reaction, producing an alkene upon the elimination of the halogen and adjacent carbons hydrogen atom.
- D. Option D is incorrect as ketones cannot be formed directly from alkyl halides
Q145. Oxidation number of particular element can be directly or indirectly inferred from its:
- A. Group number✓
- B. Atomic size
- C. Atomic mass
- D. Physical state
Explanation: Generally, groups 1, 2, 3, and 4 have oxidation numbers of +1, +2, +3, and +/-4. And groups 7, 6, and 5 have oxidation numbers -1, -2, and -3. This is the general trend among the groups; however, there are many exceptions to this.
Why the other options are wrong
- B. The oxidation number of a particular element can be directly or indirectly inferred from its group number.
- C. The oxidation number of a particular element can be directly or indirectly inferred from its group number.
- D. The oxidation number of a particular element can be directly or indirectly inferred from its group number.
Q146. Which of the following reactions is used for the production of alcohols on industrial scale?
- A. Hydrogenation of alkenes
- B. Hydration of alkenes✓
- C. Hydrohalogenation of alkenes
- D. Hydroxylation of alkenes
Explanation: Option A describes a reaction that produces alkanes from alkenes. Option B describes a reaction that produces alcohol from alkenes so, it is correct. Option C describes a reaction that produces alkyl halides from alkenes. Option D describes a reaction that produces glycol from alkenes, which is a type of alcohol but not the type that is produced on an industrial scale for commercial use.
Why the other options are wrong
- A. Option A describes a reaction that produces alkanes from alkenes.
- C. Option C describes a reaction that produces alkyl halides from alkenes.
- D. Option D describes a reaction that produces glycol from alkenes, which is a type of alcohol but not the type that is produced on an industrial scale for commercial use.
Q147. Solution contains 85.5g of sucrose (C12H22O11) in 250 cm3. What is its molarity?
- A. 1 M✓
- B. 0.5 M
- C. 0.25 M
- D. 2 M
Explanation: Molarity is moles of a substance divided by the volume in liters or cubic decimeters. For moles, divide the given mass with the molar mass of sucrose, which is (12x12+22+11x16) 342 grams per mol. Number of moles is 85.5/342 which comes out to 0.25 mol. To convert 250 cubic cm to liters, divide by 1000, so this comes out to 0.25 liters. Molarity = 0.25/0.25 = 1M so, answer is A.
Why the other options are wrong
- B. 1 M is the correct answer.
- C. 1 M is the correct answer.
- D. 1 M is the correct answer.
Q148. Which derivative of benzene shows maximum reactivity in electrophilic substitution reactions?
- A. Benzoic acid
- B. Methyl benzene✓
- C. Benzaldehyde
- D. Nitrobenzene
Explanation: Activating groups increase the reactivity of electrophilic substitutions, whereas deactivating groups decrease it. Activating groups are (from most activating to least): -NH2, -NR2 > -OH, -OR> -NHCOR> -CH3 and other alkyl groups, where R is an alkyl group. Deactivating groups are (from most deactivating to least): -NO2, -CF3> -COR (COR can be both carboxylic acids or aldehydes), -CN, -CO2R, -SO3H > Halogens. Among the options, only B describes benzene with an activating group so, it is correct. All other options describe deactivating groups as one can see from the lists mentioned.
Why the other options are wrong
- A. Benzoic acid (C6H5COOH) is a crystalline organic compound. Benzoic acid is reactive in electrophilic substitution reactions due to the presence of the benzene ring in its structure. The benzene ring in benzoic acid is electron-rich and can undergo substitution reactions with electrophiles.
- C. Benzaldehyde (C6H5CHO) is an aromatic aldehyde and is also reactive in electrophilic substitution reactions due to the presence of the benzene ring in its structure.
- D. Nitrobenzene (C6H5NO2) is an aromatic compound that is highly reactive in electrophilic substitution reactions due to the presence of the nitro group (-NO2) attached to the benzene ring.
Q149. The names of functional groups in the following compound X are:
- A. Secondary alcohol, nitrile, and phenol ring
- B. Secondary alcohol, amine, and benzene ring
- C. Secondary alcohol, nitrile, and aryl ring✓
- D. Primary alcohol, nitrile, and benzene ring
Explanation: The functional groups are: secondary alcohol, nitrile, and benzene/aryl ring. Option A incorrectly mentions phenol as there is no hydroxyl group directly bonded to the benzene ring. Option B incorrectly mentions amine, as for an amine, the nitrogen atom must be bonded to at least three other species/atoms, but in this case, nitrogen is directly bonded to one carbon atom, indicating a C-N triple bond which is characteristic of nitriles. Option C correctly lists all three functional groups. Option D incorrectly mentions primary alcohol, as for the alcohol group to be primary it must have been terminal/present at the end of the alkyl group, which is not the case here as -OH group is mentioned in the structural formula as being in the middle of the alkyl group.
Why the other options are wrong
- A. Option A incorrectly mentions phenol as there is no hydroxyl group directly bonded to the benzene ring.
- B. Option B incorrectly mentions amine, as for an amine, the nitrogen atom must be bonded to at least three other species/atoms, but in this case, nitrogen is directly bonded to one carbon atom, indicating a C-N triple bond which is characteristic of nitriles.
- D. Option D incorrectly mentions primary alcohol, as for the alcohol group to be primary it must have been terminal/present at the end of the alkyl group, which is not the case here as -OH group is mentioned in the structural formula as being in the middle of the alkyl group.
Q150. In the second period of elements, although oxygen lies next to nitrogen yet its ionization first energy is lower than that of nitrogen because?
- A. Oxygen is paramagnetic in character.
- B. Nuclear charger of oxygen is greater than nitrogen.
- C. Oxygen has higher electron affinity.
- D. In oxygen, there exists repulsion between pair of electrons present in the same orbital of valence shell.✓
Explanation: Option A is factually correct but has no bearing on ionization energy. Option B is factually correct as oxygen has one more proton in its nucleus than nitrogen, however, because of this, the ionization energy must increase, but in reality, the ionization energy of oxygen is lower than that of nitrogen. Option C is factually correct, but has no bearing on activation energy. Option D is correct because oxygen has 6 valence electrons compared to Nitrogen's 5 valence electrons so, the electronic configuration of the last shell of O is 2s2 2p4 compared with nitrogen's 2s2 2p3. In N, the p subshells have all three orbitals, singly filled with electrons whereby in oxygen, one p orbital has a pair of electrons. In this orbital, the two electrons exert repulsion which will lower the ionization energy due to a decrease in the effective nuclear force of attraction between the outermost electron and nucleus in the oxygen atom.
Why the other options are wrong
- A. Option A is factually correct but has no bearing on ionization energy.
- B. Option B is factually correct as oxygen has one more proton in its nucleus than nitrogen, however, because of this, the ionization energy must increase, but in reality, the ionization energy of oxygen is lower than that of nitrogen.
- C. Option C is factually correct, but has no bearing on activation energy.
Q151. The structure of Xenon trioxide is shown below: With reference to the valence shell electron pair repulsion theory (VSEPR), the shape of XeO3 is:
- A. Trigonal planar.
- B. Tetrahedral.
- C. Bent(or angular).
- D. Trigonal pyramidal.✓
Explanation: To determine the shape of the molecule, you must find the number of bonding pairs of electrons and lone pairs of electrons. Pi bonds are to be excluded. The molecule has three single bonds which correspond to three bonding pairs of electrons, and one lone pair of electrons, resulting in a structure similar to that of ammonia, which is trigonal pyramidal so, the answer is D. Option A would occur in a molecule with only three bonding pairs of electrons. Option B would occur in a molecule with four bonding pairs of electrons. Option C would occur in a molecule with either two bonding pairs with one lone pair or with two bonding pairs and two lone pairs of electrons.
Why the other options are wrong
- A. Option A would occur in a molecule with only three bonding pairs of electrons.
- B. Option B would occur in a molecule with four bonding pairs of electrons.
- C. Option C would occur in a molecule with either two bonding pairs with one lone pair or with two bonding pairs and two lone pairs of electrons.
Q152. Which of the following will give a positive test with Tollen’s reagent?
- A. Tertiary alcohols
- B. Carboxylic acids
- C. Aldehydes✓
- D. Ketones
Explanation: Only aldehydes can be easily oxidised by mild oxidising agents such as the Tollen reagent, Fehling solution and Benedict solution.
Why the other options are wrong
- A. Tollen's reagent consists of silver ions (Ag+) in an alkaline solution. In the presence of an aldehyde, the aldehyde is oxidized to a carboxylic acid, while the silver ions are reduced to metallic silver, which appears as a shiny silver mirror or a black precipitates.
- B. Tollen's reagent consists of silver ions (Ag+) in an alkaline solution. In the presence of an aldehyde, the aldehyde is oxidized to a carboxylic acid, while the silver ions are reduced to metallic silver, which appears as a shiny silver mirror or a black precipitates
- D. It is important to note that ketones do not react with Tollen's reagent under normal conditions and, therefore, would not give a positive test. This distinction between aldehydes and ketones is one of the characteristic reactions used to differentiate between the two functional groups.
Q153. Keeping in view the values of standard reduction potential given above, which one of the following would you select as a feasible redox chemical reaction?
- A. Cl- + I2 -> Cl2 + 2I-
- B. Cu + Zn2+ -> Cu2+ + Zn
- C. Mg + 2H + -> Mg2+ + H2✓
- D. 2Au + 6H+ -> 2Au3+ + 3 H2
Explanation: For a redox reaction to be feasible, the emf of it must be positive. (NOTE: When calculating emf, you take the voltage of each half equation according to the scenario, i.e. one will exhibit the same order as those shown above so, the E value is directly taken, but for some, you have to reverse the sign of the E value since the reaction, itself, is reversed). In option A, the emf is = -1.36 + 0.54 = -0.82, so NOT FEASIBLE. In option B, the emf is = -0.34 -0,76 = -1.10, so NOT FEASIBLE. In option C, the emf is = 2.37 + 0.00V = 2.37 so, it IS FEASIBLE; the answer is C. In option D, the emf is = -1.50 + 0 = -1.54 (the coefficient of the reaction is not taken into account) so, it is NOT FEASIBLE.
Why the other options are wrong
- A. In option A, the emf is = -1.36 + 0.54 = -0.82, so NOT FEASIBLE.
- B. In option B, the emf is = -0.34 -0,76 = -1.10, so NOT FEASIBLE.
- D. In option D, the emf is = -1.50 + 0 = -1.54 (the coefficient of the reaction is not taken into account) so, it is NOT FEASIBLE.
Q154. The range of the projectile depends upon the velocity of the projection and the angle of the projection i.e. 45. For a fixed velocity, when the angle of projection is larger than 45. Which of the following is correct?
- A. The height attained by the projectile will be more but the range is less.✓
- B. Both the height and the range attained by the projectile will be more.
- C. The height attained by the projectile will be less but the range is more.
- D. Both the height and the range attained by the projectile will be less.
Explanation: In the formula for range, it is maximum when the value of sin(2θ) is maximum. This value occurs when 2θ is equal to 90 therefore θ = 45. Beyond θ = 45, the Range decreases. The height increases beyond θ = 45 because it is calculated using Sin(θ).
Why the other options are wrong
- B. In the formula for range, it is maximum when the value of sin(2θ) is maximum. This value occurs when 2θ is equal to 90 therefore θ = 45. Beyond θ = 45, the Range decreases. The height increases beyond θ = 45 because it is calculated using Sin(θ).
- C. In the formula for range, it is maximum when the value of sin(2θ) is maximum. This value occurs when 2θ is equal to 90 therefore θ = 45. Beyond θ = 45, the Range decreases. The height increases beyond θ = 45 because it is calculated using Sin(θ).
- D. In the formula for range, it is maximum when the value of sin(2θ) is maximum. This value occurs when 2θ is equal to 90 therefore θ = 45. Beyond θ = 45, the Range decreases. The height increases beyond θ = 45 because it is calculated using Sin(θ).
Q155. The wavelength of the electromagnetic wave having frequency of 3 kHz will be?
- A. 120 km
- B. 100 km✓
- C. 80 km
- D. 140 km
Explanation: λ = v / fInputting speed of light or 3 x 108 m/s as v and 3 x 103 Hz as f gives us 1 x 105 m or 100 km.
Why the other options are wrong
- A. This option is incorrect as per the calculations
- C. This option is incorrect as per the calculations
- D. This option is incorrect as per the calculations
Q156. An automobile is moving forwards with uniform velocity due to the force exerted by its engine. If the force is doubled with the velocity remaining constant, what happens to its total power?
- A. It is squared
- B. It is halved
- C. It is doubled✓
- D. It does not change
Explanation: Power = force * velocityWith velocity kept constant, Power is directly proportional to force. Therefore, doubling force would double power.
Why the other options are wrong
- A. Doubling the force would result in an increase in power, but not by squaring it. Power is defined as the rate at which work is done or energy is transferred, and it depends on both force and velocity. If force is doubled while velocity remains constant, power would increase by a factor of 2, not squared.
- B. Doubling the force while keeping velocity constant would result in an increase in power. If force is doubled, the work done per unit time (power) would also double, assuming no change in velocity. Therefore, the power would increase, not halve.
- D. This option is incorrect. Doubling the force exerted by the engine, while keeping the velocity constant, would result in an increase in power, not a constant value. Power is directly influenced by force, so any change in force would lead to a corresponding change in power.
Q157. Which of the following statement shows that no work is done?
- A. Pushing a car to start it moving
- B. Lifting the weights.
- C. The moon Orbiting the earth.✓
- D. Writing an essay on a page.
Explanation: When the moon revolves around the earth, the displacement is normal to the direction of force on the moon. Therefore no work is done by the moon.Work is the dot product of force and displacement.W=F.dcos theta
Q158. If two objects of equal masses 'm' are moving towards each other with the same speeds 'v' then what will be the total final momentum after elastic head-on collision?
- A. mv kg m/s
- B. - mv kg's
- C. 2 mv kg's
- D. 0 kg m/s✓
Explanation: According to the law of conservation of momentum, total initial momentum of a closed system is equal to total final momentum of a closed system. Since two equal masses are moving in opposite direction, computing vector sum of total initial momentum gives us zero:m * (+v) + m * (-v) = 0Therefore, total final momentum is also equal to 0
Why the other options are wrong
- A. Mathematically, if the initial momentum of each object is given by mv and -mv (opposite in direction), the total initial momentum is: Initial momentum = mv + (-mv) = 0 Therefore, after the elastic head-on collision, the total final momentum of the system will be zero. Hence, this option is incorrect.
- B. Mathematically, if the initial momentum of each object is given by mv and -mv (opposite in direction), the total initial momentum is: Initial momentum = mv + (-mv) = 0 Therefore, after the elastic head-on collision, the total final momentum of the system will be zero. Hence, this option is incorrect.
- C. Mathematically, if the initial momentum of each object is given by mv and -mv (opposite in direction), the total initial momentum is: Initial momentum = mv + (-mv) = 0 Therefore, after the elastic head-on collision, the total final momentum of the system will be zero. Hence, this option is incorrect.
Q159. In double slit experiment, the fringe spacing of the diffracted rays increases when:
- A. The wavelength of the diffracted rays increases✓
- B. The distance between the slits increases
- C. The distance from midpoints of the slits to the central of the fringe on the screen increases
- D. The distance between the screen and the slits decreases
Explanation: Increasing the wavelength of the light source or distance between the slit and the screen would increase the fringe separation. Decreasing slit separation increases the fringe spacing.
Why the other options are wrong
- B. Increasing the wavelength of the light source or distance between the slit and the screen would increase the fringe separation. Decreasing slit separation increases the fringe spacing.
- C. Increasing the wavelength of the light source or distance between the slit and the screen would increase the fringe separation. Decreasing slit separation increases the fringe spacing.
- D. Increasing the wavelength of the light source or distance between the slit and the screen would increase the fringe separation. Decreasing slit separation increases the fringe spacing.
Q160. What is the quark composition of a Proton?
- A. Two up quarks and one down quark✓
- B. Two up quarks and one strange quark
- C. One up quark and two strange quarks
- D. Two down quarks and one up quark
Explanation: The quark composition of a proton consists of two "up" quarks (u) and one "down" quark (d).
Why the other options are wrong
- B. Since the quark composition of a proton consists of two "up" quarks (u) and one "down" quark (d), hence this option is incorrect.
- C. Since the quark composition of a proton consists of two "up" quarks (u) and one "down" quark (d), hence this option is incorrect.
- D. Since the quark composition of a proton consists of two "up" quarks (u) and one "down" quark (d), hence this option is incorrect.
Q161. The sum of all forms of molecular energies (kinetic and potential) of a substance is termed as:
- A. Elastic energy
- B. Absolute energy
- C. Internal energy✓
- D. Heat energy
Explanation: Elastic energy is a form of potential energy. Absolute energy does not exist. By definition, Internal energy is the sum of total kinetic and potential energy as defined in 1st law of thermodynamics.
Why the other options are wrong
- A. Elastic energy refers to the potential energy stored in an object when it is deformed under stress but then returns to its original shape once the stress is removed. This type of energy is associated with materials that exhibit elastic properties, such as springs or rubber bands. It is not directly related to molecular energies or the sum of kinetic and potential energies in a substance.
- B. There isn't a widely recognised concept of "absolute energy" in physics. Energy measurements typically refer to specific forms of energy or total energy within a system. Therefore, this option doesn't accurately describe the concept referred to in the question.
- D. Heat energy refers specifically to the transfer of thermal energy between two bodies due to a temperature difference. It is a form of energy transfer, not a property of a substance itself. While heat energy can contribute to changes in a substance's internal energy, it does not encompass the total internal energy of the substance, which includes both kinetic and potential molecular energies.
Q162. Molecules of a gas at constant pressure for a fixed amount of gas have average kinetic energy X. Increasing temperature from 27 oC to 327 oC, the average K.E. of molecules will become:
- A. 20X
- B. 300X
- C. 200X
- D. 2X✓
Explanation: Total Kinetic Energy = 3/2 * Boltzmann's Constant (k) * temperature in Kelvins27C + 273 = 300K327 + 273 = 600KAs rest of quantities are kept constant increasing temperature from 300K to 600K will double the average kinetic energy of the system.
Why the other options are wrong
- A. This option suggests that the average kinetic energy of the gas molecules increases by a factor of 20 when the temperature increases from 27°C to 327°C. However, this does not accurately represent the relationship between temperature and average kinetic energy. According to the kinetic theory of gases, the average kinetic energy of gas molecules is directly proportional to the temperature in Kelvin. Therefore, the increase in temperature from 27°C to 327°C (which corresponds to an increase from 300K to 600K) results in a doubling of the average kinetic energy, not an increase by a factor of 20. Thus, option A) is incorrect.
- B. This option suggests that the average kinetic energy of the gas molecules increases by a factor of 300 when the temperature increases from 27°C to 327°C. However, as explained above, this does not accurately represent the relationship between temperature and average kinetic energy. According to the kinetic theory of gases, the increase in temperature results in a proportional increase in the average kinetic energy, not by a factor of 300. Thus, option B) is incorrect.
- C. This option suggests that the average kinetic energy of the gas molecules increases by a factor of 200 when the temperature increases from 27°C to 327°C. Similar to options A) and B), this does not accurately represent the relationship between temperature and average kinetic energy. According to the kinetic theory of gases, the increase in temperature results in a proportional increase in the average kinetic energy. Thus, option C) is incorrect.
Q163. Kirchhoff's first law/rule corresponds to:
- A. Law of conservation of energy
- B. Law Of conservation Of momentum
- C. Law of conservation of charge✓
- D. Law of conservation of mass
Explanation: Kirchhoff's first law states that the algebraic sum of current flowing into a junction is zero. This rule corresponds to conservation of charge which states that total charge in a closed system remains constant because current is the rate of flow of charge.
Why the other options are wrong
- A. This law states that energy cannot be created or destroyed, only converted from one form to another. Kirchhoff's first law is not directly related to the conservation of energy; instead, it deals with the conservation of charge.
- B. This law states that the total linear momentum of an isolated system remains constant if no external forces act on it. Kirchhoff's first law is not related to the conservation of momentum; it primarily deals with the conservation of electric charge in a circuit.
- D. This law states that the mass of a closed system remains constant over time. Kirchhoff's first law is not related to the conservation of mass; it specifically addresses the conservation of electric charge in electrical circuits.
Q164. Minimum energy required to eject an electron from metal surface is called:
- A. Stopping potential
- B. Electromotive force
- C. Work function✓
- D. Threshold frequency
Explanation: The work function is the minimum energy needed to remove an electron from a solid to a point in the vacuum immediately outside the solid surface. Stopping potential is defined as the potential required to stop ejection of electrons from a metal surface when an incident beam of energy greater than the work potential of metal is directed on it. Threshold frequency is the minimum frequency of incident light that can cause emission of electrons from the metal surface.
Why the other options are wrong
- A. Stopping potential refers to the voltage that must be applied to stop the emission of photoelectrons in a photoelectric experiment. It's not specifically related to the minimum energy required to eject an electron from a metal surface.
- B. Electromotive force is the energy per unit charge provided by a source, such as a battery or generator, to move electric charge through a circuit. It's not directly related to the minimum energy required to eject an electron from a metal surface.
- D. The threshold frequency is the minimum frequency of incident electromagnetic radiation required to induce the photoelectric effect in a particular material.
Q165. If we change the magnetic flux linking a coil by rotating the coil in a constant magnetic field, the rate of change of this flux is:
- A. Proportional to the emf produced in it✓
- B. Proportional to the material Of the coil
- C. Proportional to the resistance of the coil
- D. Proportional to the change in magnetic field
Explanation: Explanation is given below.
Q166. The area under the extension-load graph Of an elastic material whose elastic limit has not been exceeded gives its:
- A. Stress
- B. Strain energy✓
- C. Strain
- D. Young modulus
Explanation: Strain energy is the energy stored by an object undergoing deformation. Area under the extension-load graph represents work done to cause the deformation. An object which has not reached its elastic limit, the work done during stretching is recovered when it is unloaded.
Q167. What will be the expression for the observed frequency f0 , if the source is moving towards the stationary observer?
- A. Option A
- B. Option B
- C. Option C
- D. Option D✓
Explanation: The following is the solution:
Why the other options are wrong
- A. Incorrect as per formula
- B. Incorrect as per formula
- C. Incorrect as per formula
Q168. The direction of current through the load resistance of a full-wave rectification circuit:
- A. remains constant✓
- B. inverts for positive cycle
- C. changes for every cycle
- D. inverts for negative cycle
Explanation: Rectification changes alternate current to direct current where current remains positive throughout the cycle.
Q169. A negligible small current between input terminals of the operational amplifier is because of:
- A. High output resistance
- B. Low output resistance
- C. High input resistance✓
- D. Low input resistance
Explanation: Ideal op-amps have zero input current. A small input current passes because of very high input impedence.
Why the other options are wrong
- A. Output resistance refers to the resistance offered by the output terminals of the operational amplifier.It does not directly influence the current flowing between the input terminals of the op-amp.High output resistance might affect the behavior of the output signal but does not explain the negligible current between the input terminals.Therefore, option A) High output resistance is incorrect in explaining the negligible small current between the input terminals.
- B. Similarly to option A, output resistance does not directly affect the current flowing between the input terminals of the operational amplifier.While low output resistance can improve the ability of the op-amp to drive loads, it does not explain why there is a negligible current between the input terminals.Therefore, option B) Low output resistance is also incorrect.
- D. Low input resistance would imply that the input terminals of the op-amp draw significant current from the input source.However, operational amplifiers are designed with high input resistance precisely to minimize the current drawn from the input source.Therefore, option D) Low input resistance is incorrect in explaining the negligible current between the input terminals.
Q170. Heavy nucleus of atoms go through fission so that they can:
- A. absorb low amount of energy
- B. absorb high amount of energy
- C. reduce their binding energy nucleon
- D. increase their binding energy per nucleon✓
Explanation: Maximum binding energy is achieved around Z = 50 (Iron is close to peak at Z = 56). Heavy nuclei undergo fission to decrease nuclear size and increase binding energy per nucleon.
Q171. A wire has a spring constant of 5 x 104 N m-1. It is stretched by a force to the extension of 1.4 mm. Calculate the strain energy stored in the wire.
- A. 4.9 x 10-5 J
- B. 4.9 x 10-2 J✓
- C. 4.9 J
- D. 4.9 x 10-3 J
Explanation: E=0.5kx^2E=0.5(50000)(0.0014)2 =0.049 J
Why the other options are wrong
- A. This option suggests that the strain energy stored in the wire is 4.9×10−5J. However, this is not correct. To calculate the strain energy stored in the wire, we use the formula U=1/2 kx2, where k is the spring constant and x is the extension of the wire. Substituting the given values into the formula yields a strain energy of 2.45×10−2J, not 4.9×10−5J.
- C. This option suggests that the strain energy stored in the wire is 4.9 J. However, this is not correct. The strain energy calculated using the given values is 2.45×10−2J, not 4.9 J.
- D. This option suggests that the strain energy stored in the wire is 4.9×10−3J. However, this is not correct. The strain energy calculated using the given values is 2.45×10−2J, not 4.9×10−3J.
Q172. An object is moving along a circular path of radius 4m. What will be its angular displacement if it moves 14 m on this circular path?
- A. 5.0 radians
- B. 3.5 radians✓
- C. 4.5 radians
- D. 5.5 radians
Explanation: Arc length = Radius x Angular displacementS = rθKeeping Arc length as 14m and radius as 4m, we get angular displacement as 3.5 radians.
Why the other options are wrong
- A. It is incorrect as per the given formula.
- C. It is incorrect as per the given formula.
- D. It is incorrect as per the given formula.
Q173. A copper wire has length L and cross-sectional area A. Its resistance is R. If we halved the length and halved the diameter of wire, then what will be the resistance of this wire?
- A. 4R
- B. 3R
- C. 2R✓
- D. R
Explanation: When length is halved, resistance is halved.When diameter is halved, area is divided by 4 (square relationship) hence, resistance is quadrupled. Therefore, (4/2) x R = 2R
Why the other options are wrong
- A. This option is incorrect as per the calculations
- B. This option is incorrect as per the calculations
- D. This option is incorrect as per the calculations
Q174. If a conductor of length 7m is placed in a magnetic field of strength 0.3 T carrying current 1 A, parallel to the field. What will be the force, acting on it, due to this magnetic field?
- A. 7 N
- B. 0 N✓
- C. 3.1 N
- D. 2.1 N
Explanation: When the conductor is placed parallel to magnetic field, no force will act on it.
Why the other options are wrong
- A. When the conductor is placed parallel to magnetic field, no force will act on it. Hence this answer is incorrect.
- C. When the conductor is placed parallel to magnetic field, no force will act on it. Hence this answer is incorrect.
- D. When the conductor is placed parallel to magnetic field, no force will act on it. Hence this answer is incorrect.
Q175. In relation, which quantity is represented by λ?
- A. Decay constant✓
- B. Half life
- C. Activity
- D. Wavelength
Explanation: Explanation is given below.T1/2 represents the 'half-life' with 'T', implying the quantity has something to do with time, and '1/2' representing 'half'.
Q176. Work done, due to centripetal force, for circular motion will be:
- A. Reduced
- B. Zero✓
- C. Maximum
- D. Half
Explanation: The displacement of an object after one complete revolution is 0 as the object returns to its original position. The beginning and final locations of a body that travels a distance and returns to its original place are the same. The displacement is zero in this situation, but the distance traveled is not.As work done = force x displacement, given the displacement is 0, work done is also 0.
Why the other options are wrong
- A. As explained in Option B, this option cannot be correct.
- C. As explained in Option B, this option cannot be correct.
- D. As explained in Option B, this option cannot be correct.
Q177. Electric field strength of a point charge is E and electric potential is V, at a distance 'r' from the point charge. What is the electric potential at a point for the same point charge where electric field strength is E/4?
- A. 4V
- B. 2V✓
- C. V/2
- D. V/4
Why the other options are wrong
- A. Incorrect as per formula
- C. The following is the solution:
- D. Incorrect as per formula
Q178. Light, emitted by a single source, passes through 2 narrow slits 1.00 mm apart. The interference pattern is observed on a screen 200 cm away and the separation between the centers of adjacent bright fringes is 2.00 mm. What would be the wavelength of the light?(u= micro)
- A. 2 pm
- B. 1 um✓
- C. 2 um
- D. 1 nm
Explanation: The explanation is given below:Wavelength = slit separation x firing separation/Distance between slits and screenAll the values, of distance, would be converted to meters (m).Slit separation = 1 x 10-3mFringe separation = 2 x 10-3mDistance between slit and screen = 200 x 10-2m
Why the other options are wrong
- A. This option is incorrect as per the formula.
- C. This option is incorrect as per the formula.
- D. This option is incorrect as per the formula.
Q179. Calculate the energy of a photon, with a frequency of 3.0 x 1018 Hz.(h = 6.63 x 10-34)
- A. 19.89 x 10-16 J✓
- B. 11.89 x 10-16 J
- C. 1.89 x 10-16 J
- D. 19.89 x 10-18 J
Explanation: The correct option is A. E=hf = 6.63×10-34 × 3×10¹⁸ = 19.89×10-16 J
Why the other options are wrong
- B. Based on the numerical solution through an equation, this option is incorrect.
- C. Based on the numerical solution through an equation, this option is incorrect.
- D. Based on the numerical solution through an equation, this option is incorrect.
Q180. The path difference for the destructive interference can be written as:
- A. Δs = n λ
- B. Δs = (n+ 1/3) λ/2
- C. Δs = (2n+ 1) λ/2✓
- D. Δs = (2n) λ
Explanation: Explanation is given below.
Why the other options are wrong
- A. Incorrect as per formula
- B. Incorrect as per formula
- D. Incorrect as per formula
Q181. Calculate the rate at which energy is transferred by a 220 V mains supply, which provides a current of 0.1 A to an LED?
- A. 2.2 W
- B. 2.2 kW
- C. 22 kW
- D. 22 W✓
Explanation: Power = Voltage x Current; 220 x 0.1 = 22W
Why the other options are wrong
- A. Power = Voltage x Current Putting in the values gives us an incorrect answer.
- B. Power = Voltage x Current Putting in the values gives us an incorrect answer.
- C. Power = Voltage x Current Putting in the values gives us an incorrect answer.
Q182. An alternating voltage V (in volts) is represented by the equation:V = 300 sin(100πt) What is the value of “f” for this voltage?
- A. 100 Hz
- B. 50 Hz✓
- C. 25 H
- D. 200 Hz
Explanation: Voltage = Maximum Voltage x sin (2πft) Therefore, 2f = 100 and frequency = 50 Hz
Why the other options are wrong
- A. Voltage = Maximum Voltage x sin (2πft) Use this equation, to decipher the value for f
- C. Voltage = Maximum Voltage x sin (2πft) Use this equation, to decipher the value for f
- D. Voltage = Maximum Voltage x sin (2πft)Use this equation, to decipher the value for f
Q183. A particle, carrying a charge of 5e, falls through a potential difference of 25 V. What would be energy acquired by the particle in ‘J’.
- A. 1.6 x 10-19 J
- B. 125 J
- C. 125 x 10-19 J
- D. 125 x 1.6 x 10-19 J✓
Explanation: Electric Potential Energy = Electric Potential x Charge Charge = 5 x 1.6 x 10-19 C Electric Potential Energy = 25V x (5 x 1.6 x 10-19) C This could be manipulated to give us (125 x 1.6 x 10-19) J, which is Option D.
Why the other options are wrong
- A. Electric Potential Energy = Electric Potential x Charge Plug in the value and you will realise this option is incorrect.
- B. Electric Potential Energy = Electric Potential x Charge Plug in the value and you will realise this option is incorrect.
- C. Electric Potential Energy = Electric Potential x Charge Plug in the value and you will realise this option is incorrect.
Q184. The unit of magnetic flux density is the tesla, ‘T’. It can also be expressed as:
- A. 1 N A-1 m
- B. 1 N-1 A-1 m
- C. 1 N-1 A-1 m-1
- D. 1 N A-1 m-1✓
Explanation: Explanation is given below.
Why the other options are wrong
- A. F = BIL sin (θ) Consider the units and you will realise this option is incorrect.
- B. F = BIL sin (θ) Consider the units and you will realise this option is incorrect.
- C. F = BIL sin (θ) Consider the units and you will realise this option is incorrect.
Q185. If we give a direct current to the transformer’s primary coil, then there will be:
- A. No emf produced in the secondary coil✓
- B. More emf in the secondary coil
- C. Equal emf produced in the secondary coil
- D. Less emf produced in the secondary coil
Explanation: A direct current will produce no varying magnetic field and therefore, no emf will be generated in the secondary coil.
Why the other options are wrong
- B. A varying or alternating current (AC) produces a time-varying magnetic field. In an AC circuit, the direction and magnitude of the current continuously change over time, which results in a magnetic field that alternates in direction. This time-varying magnetic field is one of the essential factors in the operation of devices like transformers and induction motors.
- C. No emf is produced at all as this is not Alternating Current.
- D. No emf is produced at all as this is not Alternating Current.
Q186. Percentage uncertainty in length and width of a rectangle is 2% and 3%. The total uncertainty in the area of that rectangle is:
- A. 1.5%
- B. 5%✓
- C. 1%
- D. 6%
Explanation: The following is the solution:Area = length x widthRelative uncertainties are added, when two quantities are multiplied.For addition or subtraction: The uncertainties add up directly.For multiplication or division: The relative uncertainties (expressed as a fraction or percentage) add up directly. To obtain the absolute uncertainty, multiply the combined relative uncertainty by the result of the multiplication or division.For powers or roots: Multiply the absolute uncertainty by the power or root exponent.
Why the other options are wrong
- A. Incorrect as per the formula
- C. Incorrect as per the formula
- D. Incorrect as per the formula
Q187. Electric field strength at a point between oppositely charged plates is 'E'. If the distance between plates is reduced to half, what will be the new value of electric intensity?
- A. 4E
- B. E/2
- C. E/4
- D. 2E✓
Explanation: Between two parallel plates, the electric field strength is given by: E = V/d If the distance is halved, electric field strength is doubled since both are inversely related.
Why the other options are wrong
- A. Incorrect as per formula
- B. Incorrect as per formula
- C. Incorrect as per formula
Q188. The horizontal component of Earth magnetic flux density is 1.8 x 10-6 T. The current in a horizontal cable is 160 A. Calculate the maximum force per unit length?
- A. 2.88 x 10-6 N/m
- B. 2.88 x 10-4 N/m✓
- C. 2.88 x 10-2 N/m
- D. 2.88 x 10-8 N/m
Explanation: Force/Length = Magnetic Flux density x Current x sin(θ) For maximum force, sin(θ) = 1. Putting in the values gives us the answer.
Why the other options are wrong
- A. Based on the numerical solution, this option is incorrect.
- C. Based on the numerical solution, this option is incorrect.
- D. Based on the numerical solution, this option is incorrect.
Q189. The value and units of the Planck constant ‘h’ can be expressed as:
- A. 3.63 x 10-34 Js
- B. 6.63 x 10-34 Js-1
- C. 6.63 x 10-34 Js✓
- D. 6.63 x 10-43 Js
Explanation: Planck's Constant tells us the relationship between energy and frequency of light.
Why the other options are wrong
- A. This value is incorrect
- B. This value is incorrect
- D. This value is incorrect
Q190. The diameter of a wire is measured by using a micrometer screw gauge with least count of 0.01 mm. Which of the following readings will be correct?
- A. 0.20 cm
- B. 0.002 m
- C. 2.00 mm✓
- D. 0.2 cm
Explanation: The following is the solution:Since least count is 0.01 mm, therefore, diameter must be expressed in multiples of 0.01.2.00 mm is 200 times 0.01 mm therefore, (C).
Why the other options are wrong
- A. Incorrect as per the formula
- B. Incorrect as per the formula
- D. Incorrect as per the formula
Q191. When the length of a simple pendulum is doubled, the ratio of its new time period to old time period is:
- A. 3√2
- B. 1√2
- C. 2√2
- D. √2✓
Explanation: The formula for time period is: T = 2π x √L/gUsing this formula, we see that doubling length results in multiplying time period with √2.
Why the other options are wrong
- A. This option suggests that the ratio of the new time period to the old time period when the length of a simple pendulum is doubled is 3√2. However, this is not correct. When the length of a simple pendulum is doubled, the ratio of the new time period to the old time period is √2, not 3√2.
- B. This option suggests that the ratio of the new time period to the old time period when the length of a simple pendulum is doubled is 1√2. This is incorrect because 1√2 is simply √2. When the length of a simple pendulum is doubled, the ratio of the new time period to the old time period is indeed √2.
- C. This option suggests that the ratio of the new time period to the old time period when the length of a simple pendulum is doubled is 2√2. However, this is not correct. When the length of a simple pendulum is doubled, the ratio of the new time period to the old time period is √2, not 2√2.
Q192. For projectile motion, in the absence of air resistance:
- A. Horizontal acceleration is zero✓
- B. Vertical acceleration is zero
- C. Horizontal force is constant
- D. Vertical speed is constant
Explanation: Air resistance acts on horizontal component, mainly. In the absence of air resistance, there will be no horizontal acceleration. Vertical acceleration is due to gravity, hence options B and D are wrong. In the absence of air resistance, no horizontal force will be applied and thus, option C is wrong.
Why the other options are wrong
- B. Vertical acceleration is due to gravity, hence options B and D are wrong.
- C. In the absence of air resistance, no horizontal force will be applied and thus, option C is wrong.
- D. Vertical acceleration is due to gravity, hence options B and D are wrong.
Q193. In simple harmonic motion, acceleration will be maximum, when the object is at:
- A. Maximum displacement from the mean position✓
- B. Centre position
- C. Half of the maximum displacement from mean position
- D. Mean position
Explanation: When displacement is maximum, acceleration will be maximum. The displacement and acceleration are related by the equation, a= -w2x, where 'a' (acceleration) and 'x' (displacement) are proportional.
Why the other options are wrong
- B. This option suggests that the acceleration will be maximum when the object is at the center position in simple harmonic motion (SHM). However, this is not correct.At the center position, the displacement is zero, so the restoring force acting on the object is also zero. Consequently, the acceleration is also zero at the center position.
- C. This option refers to a point halfway between the mean position and the maximum displacement. However, the acceleration is not maximum at this point.The restoring force and acceleration increase with increasing displacement from the mean position. Therefore, the acceleration is greater at points closer to the maximum displacement.
- D. This option refers to the mean position, where the displacement is zero in simple harmonic motion (SHM).Since the restoring force acting on the object is directly proportional to the displacement, and there is no displacement at the mean position, the restoring force and acceleration are both zero at this point.
Q194. Choose the correct option
- A. The teacher made all the students rewrite their papers, because the first drafts were not acceptable.✓
- B. The teacher made all the students to rewrite their papers, because the first drafts were not acceptable.
- C. The teacher made all the students rewrite their papers, because the first drafts was not acceptable.
- D. The teacher made all the students rewrite their papers, because first drafts were not acceptable.
Explanation: This sentence is correct. "Made" is correctly followed by the base form of the verb "rewrite." "Were" is the correct verb to agree with the plural subject "drafts."
Why the other options are wrong
- B. This sentence is incorrect because "made" is followed by the base form of the verb without "to." It should be "made all the students rewrite."
- C. This sentence is incorrect because "was" does not agree with the plural subject "drafts." It should be "were."
- D. This sentence is almost correct but is missing the article "the" before "first drafts." It should be "the first drafts."
Q195. When I was young, I — run very fast.
- A. Can
- B. Could✓
- C. Could have
- D. Must
Explanation: This is the correct choice because it indicates past ability or capability. It fits well with the past tense "was" in the sentence, indicating that in the past (when the speaker was young), they had the ability to run very fast.
Why the other options are wrong
- A. While "can" indicates present ability, it doesn't fit the past tense context of the sentence.
- C. This implies a possibility in the past that did not happen, but it doesn't fit the structure needed for a simple statement of past ability.
- D. Indicates necessity or certainty, which doesn't make sense in the context of running fast.
Q196. She has a driving license. She — drive the car on the motorway.
- A. Might
- B. May
- C. Can✓
- D. Could have
Explanation: This is the correct answer because it indicates present ability or capability. Since she has a driving license, she is able to drive the car on the motorway.
Why the other options are wrong
- A. Suggests a possibility or uncertainty, which is not appropriate for stating a definite ability.
- B. Indicates permission or possibility, but it doesn't specifically denote ability.
- D. Refers to a past possibility that did not occur, which is not relevant to the present situation of driving on the motorway.
Q197. — you turn down the music a bit, please?
- A. Might
- B. Can✓
- C. Could
- D. Would
Explanation: This is the correct answer because it is used to ask for permission or to make a polite request. In this context, it is asking if it's possible for someone to lower the music volume.
Why the other options are wrong
- A. Suggests a possibility or uncertainty, which is not appropriate for making a polite request.
- C. Could also be used in requests, but "can" is more straightforward and commonly used.
- D. Typically used for polite requests, but it doesn't fit grammatically in the question structure provided.
Q198. You — reduce the speed. There is a speed limit.
- A. Need to
- B. Ought to
- C. Must✓
- D. will
Explanation: This is the correct answer because it expresses a strong necessity or obligation. It indicates that reducing the speed is mandatory because there is a speed limit in place.
Why the other options are wrong
- A. Indicates necessity or obligation, but it is not as strong as "must."
- B. Suggests a recommendation or advice, which is less direct than "must."
- D. Indicates future intention or prediction, which doesn't fit the context of immediate necessity.
Q199. The old garage suddenly collapsed one day. Luckily, the owner wasn’t there or he — received serious injuries.
- A. Might as well
- B. Could have✓
- C. Have to
- D. Would
Explanation: This is the correct answer because it expresses a past possibility or hypothetical situation. It suggests that if the owner had been there, it was possible (but did not actually happen) that he could have received serious injuries due to the collapsing garage.
Why the other options are wrong
- A. This phrase means something is likely to happen or there is no harm in doing something. It doesn't fit the context of the sentence, which discusses a past hypothetical situation.
- C. Indicates necessity or obligation, which doesn't fit the context of a hypothetical situation in the past.
- D. Typically used for conditional statements or future intentions, which doesn't fit the context here.
Q200. You — drive fast. We have plenty of time.
- A. Will not
- B. Shall not
- C. Must not
- D. Need not✓
Explanation: This is the correct answer because it means it is not necessary to drive fast. The sentence implies that driving fast is optional because there is plenty of time available.
Why the other options are wrong
- A. Indicates future tense and negation, which doesn't fit the context of the sentence asking about necessity in the present.
- B. Similar to "will not," it indicates future tense and negation, not present necessity.
- C. Indicates prohibition or necessity not to do something, which is the opposite of what the sentence is asking.
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